DEVELOPMENT AND CHARACTERIZATION OF HYBRID POLYPROPYLENE COMPOSITES REINFORCED WITH CALOTROPIS GIGANTEA FIBER AND FLY ASH FOR ENHANCED MECHANICAL PROPERTIES
DOI:
https://doi.org/10.11113/aej.v16.23614Keywords:
Calotropis gigantea fiber, Fly Ash, Polypropylene, Tensile Strength, Flexural strength, Impact strength, Scanning Electron MicroscopyAbstract
Calotropis gigantea is a common weed found in several Asian countries, currently lacks industrial application and economic support to the region despite its excellent mechanical properties. This research focuses on the development and characterization of a novel hybrid composite material, incorporating Calotropis gigantea stem (CGS) fiber and fly ash (FA) as reinforcement materials within a polypropylene (PP) matrix at varying the weight percent of CGS fiber powder content at 5 weight percent, 10 weight percent, 15 weight percent, and 20 weight percent while maintaining a constant 10 weight percent fly ash content. The physical properties, including density, void content and water absorption and mechanical properties, including tensile strength, flexural strength, and impact resistance, were evaluated, demonstrating that the introduction of CGS fiber and fly ash significantly enhances the mechanical properties of the composites. The stress-strain curves and load-deflection behaviours were recorded. The maximum tensile strength, flexural strength and impact resistance was observed at 10 weight percent of CGS fiber and 10 weight percent of fly ash content. Furthermore, morphological studies using scanning electron microscopy (SEM) offered insights into the microstructural features, illustrating a well-integrated fiber-matrix interface and confirmed uniform distribution of reinforcements. This study introduces a sustainable approach to composite development by leveraging the mechanical benefits of CGS fiber and the cost-effectiveness of fly ash, offering a promising alternative for high-performance, environmentally friendly and to produce lighter weight composite materials.
References
Rajmohan, T., K. Palanikumar, J. P. Davim. 2021. Advances in Materials and Manufacturing Engineering: Select Proceedings of ICMME 2019.. Springer Singapore 1 XXII. 689:2662-3161. DOI: https://doiorg/101007/978-981-15-6267-9.
Palanikumar, K., M. Ramesh, K. H. Reddy. 2016. Experimental investigation on the mechanical properties of green hybrid sisal and glass fiber reinforced polymer composites. Journal of Natural Fibers. 13: 321–31. DOI: https://doiorg/101080/1544047820151029192.
Hanan, F., M. Jawaid, P. M. Tahir. 2018. Mechanical performance of oil palm/kenaf fiber-reinforced epoxy-based bilayer hybrid composites. Journal of Natural Fibers. 17(2): 155-67 DOI: https://doi:101080/1544047820181477083.
Vinod, A., R. Vijay, and D. L. Singaravelu. 2017. ThermoMechanical Characterization of Calotropis gigantea Stem Powder-Filled Jute Fiber-Reinforced Epoxy Composites. Journal of Natural Fibers. 15(5): 648–657. DOI: https://doi.org/10.1080/15440478.2017.1354740.
Ashori, A., and Z. Bahreini. 2009. Evaluation of calotropis gigantea as a promising raw material for fiber-reinforced composite. Journal of Composite Materials. 43(11): 1297–304. DOI: https://doiorg/10.1177/0021998308104526.
Huang, L., B. Mu, X. Yi, S. Li, and Q. Wang. 2016. Sustainable use of coffee husks for reinforcing polyethylene composites. Journal of Polymers and the Environment. 1–11.
Singh, M., and K. Javed. 2015. Comparative study of chemical composition of calotropis gigantea flower, leaf and fruit essential oil. European Chemical Bulletin. 4(10): 477–80.
Ramesh, G., K. Subramanian, S. Sathiyamurthy, & M. Prakash. 2020. Calotropis Gigantea Fiber-epoxy Composites: Influence of Fiber Orientation on Mechanical Properties and Thermal Behavior. Journal of Natural Fibers. 19(10): 3668–3680. DOI: https://doi.org/10.1080/15440478.2020.1848718.
Raja, Thandavamoorthy, D. Yuvarajan, and T. Subash. 2023. Studies on the mechanical and thermal stability of Calotropis gigantea fibre-reinforced bran nano particulates epoxy composite. Scientific Reports. 13(1): 16291.
K. Tamil Mannan, V. Sivaprakash, S. Raja, M. Kulandasamy, P. P. Patil, S. Kaliappan. 2022. Significance of Si3N4/Lime powder addition on the mechanical properties of natural calotropis gigantea composites. Materials Today: Proceedings. 69(3): 1355-1360. ISSN 2214-7853.
DOI: https://doi.org/10.1016/j.matpr.2022.09.002.
Sahu, S. B., S. Nayak, S. Sahu, and M. K.Roul. 2023. Calotropis gigantea bast fiber based epoxy composites for automotive application: An experimental study. Polymer Composites. 44(1): 252-260. DOI: https://doi.org/10.1002/pc.27042.
Sharma, V., M. L. Meena, M. Kumar, A. Patnaik. 2021. Waste fly ash powder filled glass fiber reinforced epoxy composite: physical, mechanical, thermo-mechanical and three-body abrasive wear analysis. Fibers and Polymers. 22: 1120–1136. DOI: https://doi.org/101007/s12221-021-0145-4
Ou, Y., D. Zhu, H. Li. 2016. Strain rate and temperature effects on the dynamic tensile behaviors of basalt fiber bundles and reinforced polymer composite. Journal of Materials in Civil Engineering. 28: 10.
DOI: https://doi.org/101061/(ASCE)MT1943-55330001615.
R. Satheesh, K. Manisekar, V. Manikandan. 2014. Study on mechanical properties of fly ash impregnated glass fiber reinforced polymer composites using mixture design analysis. Materials & Design. 55: 499-508. DOI: https://doi.org/101016/jmatdes201310026.
Raghavendra, Dr. Gujjala, S. Ojha, Acharya, S. K. Pal. 2014. A comparative analysis of woven jute/glass hybrid polymer composite with and without reinforcing of fly ash particles. Polymer Composites. 37(3): 658–65. DOI: https://doi.org/101002/pc23222.
Tambrallimath, V., R. Keshavamurthy, P. Davim, K. Pradeep, G. S. Pignatta, G. Badari, K. A. Yunus, T. M. Badruddin. 2022. Synthesis and characterization of flyash reinforced polymer composites developed by Fused Filament Fabrication. Journal of Materials Research and Technology. 21: 810–26 DOI: https://doi.org/101016/JJMRT202209059.
Sim, J., Y. Kang, B. J. Kim, Y. H. Park, Y. C. Lee. 2020. Preparation of fly ash/epoxy composites and its effects on mechanical properties. Polymers. 12: 79. DOI: https://doi.org/103390/polym12010079.
Raghunandan, A. B., D. S. Chiniwar, S. Hiremath, P. Sondar, H. M. Vishwanatha. 2022. Modelling and comparative analysis of epoxy-fly-ash composite with alloys for bracket application. Journal of Composites Science. 6: 358. DOI: https://doi.org/103390/jcs6120358.
Khan, M., S. Rahamathbaba, M. Mateen, D. Ravi Shankar, H. M. Manzoor. 2019. Effect of NaOH treatment on mechanical strength of banana/epoxy laminates. Polymers from Renewable Resources. 10: 19–26. DOI: https://doi.org/101177/2041247919863626.
Chow, C. P. L., X. S. Xing, R. K. Y. Li. 2007. Moisture absorption studies of sisal fibre reinforced polypropylene composites. Composites Science and Technology. 67: 306-313. DOI: https://doi.org/101016/jcompscitech200608005.
Saleem, A., L. Medina, M. Skrifvars, L. Berglin. 2020. Hybrid Polymer Composites of Bio-Based Bast Fibers with Glass, Carbon and Basalt Fibers for Automotive Applications—A Review. Molecules. 25:4933.
DOI: https://doi.org/103390/molecules25214933
Sajith, S. 2019. Investigation on effect of chemical composition of bio-fillers on filler/ matrix interaction and properties of particle reinforced composites using FTIR. Composites Part B Engineering.166: 21–30. https://doi.org/101016/J COMPOSITESB201811141.
Wickramaarachchi, W. V., S. Walpalage, S. M. Egodage. 2021. Effect of particulate fillers on natural rubber/high-density polyethylene blends for roofing application. . Polymers and Polymer Composites. 29: 763–769. DOI: https://doi.org/101177/0967391120934615/ASSET/IMAGES/LARGE/101177_0967391120934615-FIG3JPEG.
Saw, S. K., K. Akhtar, N. Yadav, A. K. Singh. 2014. Hybrid composites made from jute/coir fibers: Water absorption, thickness swelling, density, morphology and mechanical properties. Journal of Natural Fibers. 11: 39–53. DOI: https://doi.org/doi:101080/154404782013825067.
Cazan, C., A. Enesca, L. Andronic. 2021. Synergic effect of TiO2 filler on the mechanical properties of polymer nanocomposites. Polymers 13: 2017. DOI: https://doi.org/103390/polym13122017.
Shirkavad, S., E. Moslehifard. 2014. Effect of TiO2 nanoparticles on tensile strength of dental acrylic resins. Journal of Dental Research Dental Clinics Dental Prospects. 8: 197. DOI: https://doi.org/105681/JODDD2014036.
Ramesh, M., L. Rajeshkumar, N. Srinivasan, D. Kumar, & D. Balaji. 2022. Influence of filler material on properties of fiber-reinforced polymer composites: A review. e-Polymers. 22(1): 898–916. DOI: https://doi.org/10.1515/epoly-2022-0080
Faruk, O., A. K. Bledzki, H. P. Fink, M. Sain. 2012. Biocomposites reinforced with natural fibers: 2000-2010. Progress in Polymer Science. 37: 1552–1596. DOI: https://doi.org/101016/jprogpolymsci201204003.
Kalauni, K., S. J. Pawar. 2023. Physicochemical mechanical morphological and thermal characterization of Grewia Optiva fiber reinforced epoxy and hybrid (epoxy-Lannea Coromandelica gum) resins composite. Journal of polymer research. 30: 1–19.
DOI: https://doi.org/101007/S10965-023-03583-Z/METRICS.
Thomason, J. L., J. L. Rudeiros-Fern´andez. 2018. A review of the impact performance of natural fiber thermoplastic composites. Frontiers in Materials. 5: 413836. DOI: https://doi.org/103389/FMATS201800060/BIBTEX.
Wypych, G. 2016. The effect of fillers on the mechanical properties of filled materials. In: Handbook of Fillers Elsevier. 467–531. DOI: https://doi.org/101016/B978-1-895198-91-150010-5.
Kumar, K. M. Gupta. 2009. Fabrication and Characterization of Dual Green Fibre Hybrid Composite. M Tech Thesis Department of Applied Mechanics Motilal Nehru National Institute of Technology. INDIA.
Brahma, Y. and K. M. Gupta. 2009. Development and Characterization of Starch and Latex Based Bio-Hybrid Composites. M Tech Thesis Department of Applied Mechanics, Motilal Nehru National Institute of Technology India.













