PVDF-CLOISITE HOLLOW FIBER MEMBRANE FOR CO2 ABSORPTION VIA MEMBRANE CONTACTOR
DOI:
https://doi.org/10.11113/jt.v79.10431Keywords:
PVDF-Cloisite hollow fiber membrane, CO2 absorption, Hollow fiber membrane contactor, clayAbstract
The effect of cloisite concentrations on CO2 absorption via polyvinylidene fluoride-cloisite hollow fiber in membrane contactor system was investigated. PVDF polymer was modified by introducing different compositions of cloisite clay (S1: 0%, S2:1 wt%, S3: 3 wt% and S4: 5 wt%) into the polymer solution. The hollow fiber membranes were examined via liquid entry pressure (LEPw), contact angle and scanning electron microscope (SEM). CO2 absorption test was conducted at different liquid absorbent flow rates of 1M MEA. S4 gives highest Liquid entry pressure value and S3 obtained highest contact angle value at around 87.21º. Different concentrations of cloisite exhibited various finger-like structure with sponge-like morphology on the membrane lumen side. Meanwhile, the highest CO2 absorption flux of 3.41×10-2 mol/m2.s at flowrate of 200 ml/min was obtained for membrane S4. Long term performance for membrane S4 up to 55 hours of CO2 absorption showed increasing absorption trend up to 6.78 ×10-2 mol/m2.s of CO2 fluxes.Â
References
Criscuoli, A., and Drioli, E. 2009. Streams Treatments. Handbook of Membrane Separation. 1041-1055.
Lin, Y., Chen, C., Tung, K., Wei, T., and Lu, S. 2013. Mesoporous Fluorocarbon-Modified Silica Aerogel Membranes Enabling Long-Term Continuous CO2 Capture with Large Absorption Flux Enhancements. Chemistry & Sustainability, Energy & Materials. 6 (3): 437-442.
Ghasem, N., Al-Marzouqi, M., and Duidar, A. 2012. Effect Of PVDF Concentration On The Morphology And Performance Of Hollow Fiber Membrane Employed As Gas-Liquid Membrane Contactor For CO2 Absorption. Separation and Purification Technology. 98: 174-185.
Rahbari-Sisakht, M., Ismail, A. F., Rana, D., and Matsuura, T. 2012. Effect Of Different Additives On The Physical And Chemical CO2 Absorption In Polyetherimide Hollow Fiber Membrane Contactor System. Separation and Purification Technology. 98: 472-480.
Klaassen, R., Feron, P. H. M., van der Vaart, R., and Jansen, A. E. 2003. Chapter 6 Industrial Applications And Opportunities For Membrane Contactors. Membrane Science and Technology. 8: 125-145.
Wang, Z., Fang, M., Ma, Q., Yu, H., Wei, C. C., and Luo, Z. 2014. Investigation Of Membrane Wetting In Different Absorbents At Elevated Temperature For Carbon Dioxide Capture. Journal of Membrane Science. 455: 219-228.
Bougie, F., Iliuta, I., and Iliuta, M. C. 2014. Absorption Of CO2 By AHPD-Pz Aqueous Blend In PTFE Hollow Fiber Membrane Contactors. Separation and Purification Technology. 138: 84-91.
Rezaei, M., Ismail, A. F., Hashemifard, S. A., and Matsuura, T. 2014. Preparation And Characterization Of PVDF-Montmorillonite Mixed Matrix Hollow Fiber Membrane For Gas-Liquid Contacting Process. Chemical Engineering Research and Design. 92(11): 2449-2460.
Mansourizadeh A., and Ismail, A. F. 2010. Effect Of Additives On The Structure And Performance Of Polysulfone Hollow Fiber Membranes For CO2 Absorption. Journal of Membrane Science. 348: 260-267.
Mansourizadeh A., and Ismail, A. F. 2011. Preparation And Characterization Of Porous PVDF Hollow Fiber Membranes For CO2 Absorption: Effect Of Different Non-Solvent Additives In The Polymer Dope. International Journal of Greenhouse Gas Control. 5(4): 640-648.
Mansourizadeh A., and Ismail, A. F. 2010. Effect Of LiCl Concentration In The Polymer Dope On The Structure And Performance Of Hydrophobic PVDF Hollow Fiber Membranes For CO2 Absorption. Chemical Engineering Journal. 165(3): 980-988.
Fosi-Kofal, M., Mustafa, A., Ismail, A. F., Rezaei-DashtArzhandi, M., and Matsuura, T. 2016. PVDF/CaCO3 Composite Hollow Fiber Membrane For CO2 Absorption In Gas–Liquid Membrane Contactor. Journal of Natural Gas Science and Engineering. 3: 428-436.
Hou, D., Wang, J., Sun, X., Ji, Z., and Luan, Z. 2012. Preparation And Properties Of PVDF Composite Hollow Fiber Membranes For Desalination Through Direct Contact Membrane Distillation. Journal of Membrane Science. 405: 185-200.
Ismail, A. F., Rahim, R. A., and Rahman, W. A. W. A. 2008. Characterization Of Polyethersulfone/Matrimid® 5218 Miscible Blend Mixed Matrix Membranes For O2/N2 Gas Separation. Separation and Purification Technology. 63(1): 200-206.
Rezaei, M., Ismail, A. F., Bakeri, G., Hashemifard, S. A., and Matsuura, T. 2015. Effect Of General Montmorillonite And Cloisite 15A On Structural Parameters And Performance Of Mixed Matrix Membranes Contactor For CO2 Absorption. Chemical Engineering Journal. 260: 875-885.
Hou, D., Wang, J., Qu, D., Luan, Z., and Ren, X. 2009. Fabrication And Characterization Of Hydrophobic PVDF Hollow Fiber Membranes For Desalination Through Direct Contact Membrane Distillation. Separation and Purification Technology. 69(1): 78-86.
Khayet, M., Feng, C. Y., Khulbe, K. C., and Matsuura, T. 2002. Preparation And Characterization Of Polyvinylidenefluoride Hollow Fiber Membranes For Ultrafiltration. Polymer. 43(13): 3879-3890.
Mokhtar, N. M., Lau, W. J., Ismail, A. F., and Ng, B. C. 2014. Physicochemical Study Of Polyvinylidene fluoride–Cloisite15A® Composite Membranes For Membrane Distillation Application. RSC Advances. 4(108): 63367-63379.
Bakeri, G., Matsuura, T., and Ismail, A. F. 2011. The Effect Of Phase Inversion Promoters On The Structure And Performance Of Polyetherimide Hollow Fiber Membrane Using In Gas-Liquid Contacting Process. Journal of Membrane Science. 383(1-2): 159-169.
Bakeri, G., Ismail, A. F., Rahimnejad, M., and Matsuura, T. 2014. Porous Polyethersulfone Hollow Fiber Membrane In Gas–Liquid Contacting Processes. Chemical Engineering Research And Design. 92(7): 1381-1390.
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.
