EVALUATION OF IRON OXIDE DECORATED ON GRAPHENE OXIDE (FE3O4/GO) NANOHYBRID INCORPORATED IN PSF MEMBRANE AT DIFFERENT MOLAR RATIOS FOR CONGO RED REJECTION

Authors

  • Chai Pui Vun Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia
  • Abdul Wahab Mohammad Research Centre for Sustainable Process Technology (CESPRO), Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia
  • Teow Yeit Haan Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia
  • Ebrahim Mahmoudi Department of Chemical and Process Engineering, Faculty of Engineering and Built Environment, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor Darul Ehsan, Malaysia

DOI:

https://doi.org/10.11113/jt.v79.10440

Keywords:

Mixed-Matrix Membrane, Graphene Oxide, Iron Oxide, Polysulfone, Nanohybrid

Abstract

In this study, iron oxide decorated graphene oxide (Fe3O4/GO) with three different molar ratio of Fe decorated on GO nanoplates (Fe percentage: 5 wt%, 10wt%, 20 wt%) were synthesized. First, GO nanoplates were synthesized using natural graphite powder according to the Hummers method. Fe3O4/GO nanohybrid was then prepared by co-precipitation of FeCl3.6H2O and FeSO4.7H2O with GO in the presence of ammonia hydroxide (NH4OH). The nanohybrid was characterized using X-ray diffraction (XRD) and Transmission Electron Microscopy (TEM). The polysulfone (PSf) mixed matrix membranes containing 0.4 wt% of the nanohybrid were prepared by phase inversion method. The effect of different molar ratio of Fe3O4/GO nanohybrid on the membrane morphology was examined by several approaches such as porosity & pore size analysis, contact angle, and Field Emission Scanning Electron Microscopy (FESEM) & Energy Dispersive X-Ray (EDX). The mixed-matrix membranes performance were evaluated by measuring the membrane permeate flux and Congo Red (CR) rejection. All the PSf-Fe3O4/GO mixed-matrix membrane showed enhanced hydrophilicity, permeate flux and CR rejection compared to the neat PSf membrane. Experiment showed that the PSf-Fe3O4/GO mixed-matrix membrane with 5 wt% of Fe decorated onto GO nanoplates was having the best performance with the highest permeate flux of 112.47 L/m2.h and the CR rejection of 97±2%. 

References

Aditya Kiran, S., Y. Lukka Thuyavan, G. Arthanareeswaran, T. Matsuura, and A. F. Ismail. 2016. Impact of Graphene Oxide Embedded Polyethersulfone Membranes for the Effective Treatment of Distillery Effluent. Chemical Engineering Journal. 286: 528-537.

Yin, J., and B. Deng. 2015. Polymer-Matrix Nanocomposite Membranes for Water Treatment. Journal of Membrane Science. 479: 256-275.

Lee, J., H.-R. Chae, Y.J. Won, K. Lee, C.-H. Lee, H.H. Lee, I.-C. Kim, and J.-m. Lee. 2013. Graphene Oxide Nanoplatelets Composite Membrane with Hydrophilic and Antifouling Properties for Wastewater Treatment. Journal of Membrane Science. 448: 223-230.

Ganesh, B. M., A. M. Isloor, and A. F. Ismail. 2013. Enhanced Hydrophilicity and Salt Rejection Study of Graphene Oxide-Polysulfone Mixed Matrix Membrane. Desalination. 313: 199-207.

Ionita, M., A. M. Pandele, L. Crica, and L. Pilan. 2014. Improving the Thermal and Mechanical Properties of Polysulfone by Incorporation of Graphene Oxide. Composites Part B: Engineering. 59: 133-139.

Vatanpour, V., S. S. Madaeni, R. Moradian, S. Zinadini, and B. Astinchap. 2012. Novel Antibifouling Nanofiltration Polyethersulfone Membrane Fabricated from Embedding TiO2 Coated Multiwalled Carbon Nanotubes. Separation and Purification Technology. 90: 69-82.

Ng, L. Y., A. W. Mohammad, C. P. Leo, and N. Hilal. 2013. Polymeric Membranes Incorporated with Metal/Metal Oxide Nanoparticles: A Comprehensive Review. Desalination. 308: 15-33.

Huang, Z.-Q., F. Zheng, Z. Zhang, H.-T. Xu, and K.-M. Zhou. 2012. The Performance of the PVDF-Fe3O4 Ultrafiltration Membrane and the Effect of a Parallel Magnetic Field used during the Membrane Formation. Desalination. 292: 64-72.

Ghaemi, N., S.S. Madaeni, P. Daraei, H. Rajabi, S. Zinadini, A. Alizadeh, R. Heydari, M. Beygzadeh, and S. Ghouzivand. 2015. Polyethersulfone Membrane Enhanced with Iron Oxide Nanoparticles for Copper Removal from Water: Application of New Functionalized Fe3O4 Nanoparticles. Chemical Engineering Journal. 263: 101-112.

Daraei, P., S. S. Madaeni, N. Ghaemi, E. Salehi, M. A. Khadivi, R. Moradian, and B. Astinchap. 2012. Novel Polyethersulfone Nanocomposite Membrane Prepared by PANI/Fe3O4 Nanoparticles with Enhanced Performance for Cu(II) Removal from Water. Journal of Membrane Science. 415-416: 250-259.

Safarpour, M., V. Vatanpour, and A. Khataee. 2015. Preparation and Characterization of Graphene Oxide/TiO2 Blended PES Nanofiltration Membrane with Improved Antifouling and Separation Performance. Desalination. 393: 65-78.

Wu, H., B. Tang, and P. Wu. 2014. Development of Novel SiO2–GO Nanohybrid/Polysulfone Membrane with Enhanced Performance. Journal of Membrane Science. 451: 94-102.

Cao, K., Z. Jiang, J. Zhao, C. Zhao, C. Gao, F. Pan, B. Wang, X. Cao, and J. Yang. 2014. Enhanced Water Permeation through Sodium Alginate Membranes by Incorporating Graphene Oxides. Journal of Membrane Science. 469: 272-283.

Zhao, C., X. Xu, J. Chen, and F. Yang. 2013. Effect of Graphene Oxide Concentration on the Morphologies and Antifouling Properties of PVDF Ultrafiltration Membranes. Journal of Environmental Chemical Engineering. 1(3): 349-354.

Zhao, C., X. Xu, J. Chen, G. Wang, and F. Yang. 2014. Highly Effective Antifouling Performance of PVDF/Graphene Oxide Composite Membrane in Membrane Bioreactor (MBR) System. Desalination. 340: 59-66.

Vatanpour, V., A. Shockravi, H. Zarrabi, Z. Nikjavan, and A. Javadi. 2015. Fabrication and Characterization of Anti-Fouling and Anti-Bacterial Ag-Loaded Graphene Oxide/Polyethersulfone Mixed Matrix Membrane. Journal of Industrial and Engineering Chemistry. 30: 342-352.

Koushkbaghi, S., P. Jafari, J. Rabiei, M. Irani, and M. Aliabadi. 2016. Fabrication of PET/PAN/GO/Fe3O4 Nanofibrous Membrane for the Removal of Pb(II) and Cr(VI) Ions. Chemical Engineering Journal. 301: 42-50.

Chai, P. V., E. Mahmoudi, Y. H. Teow, and A. W. Mohammad. 2016. Preparation of Novel Polysulfone-Fe3O4/GO Mixed-Matrix Membrane for Humic Acid Rejection. Journal of Water Process Engineering.

Mahmoudi, E., L. Y. Ng, M. M. Ba-Abbad, and A. W. Mohammad. 2015. Novel Nanohybrid Polysulfone Membrane Embedded with Silver Nanoparticles on Graphene Oxide Nanoplates. Chemical Engineering Journal. 277: 1-10.

Deng, J.-H., X.-R. Zhang, G.-M. Zeng, J.-L. Gong, Q.-Y. Niu, and J. Liang. 2013. Simultaneous Removal of Cd(II) And Ionic Dyes from Aqueous Solution using Magnetic Graphene Oxide Nanocomposite as an Adsorbent. Chemical Engineering Journal. 226: 189-200.

Basri, H., A.F. Ismail, and M. Aziz. 2012. Microstructure and Anti-Adhesion Properties Of PES/TAP/Ag Hybrid Ultrafiltration Membrane. Desalination. 287: 71-77.

Li, J.-F., Z.-L. Xu, H. Yang, L.-Y. Yu, and M. Liu. 2009. Effect of TiO2 Nanoparticles on the Surface Morphology and Performance of Microporous PES Membrane. Applied Surface Science. 255 (9): 4725-4732.

Yu, L., Y. Zhang, B. Zhang, J. Liu, H. Zhang, and C. Song. 2013. Preparation and Characterization of HPEI-GO/PES Ultrafiltration Membrane with Antifouling and Antibacterial Properties. Journal of Membrane Science. 447: 452-462.

Zhang, M., M. Jia, and Y. Jin. 2012. Fe3O4/Reduced Graphene Oxide Nanocomposite as High Performance Anode for Lithium Ion Batteries. Applied Surface Science. 261: 298-305.

Shen, X., J. Wu, S. Bai, and H. Zhou. 2010. One-Pot Solvothermal Syntheses and Magnetic Properties of Graphene-Based Magnetic Nanocomposites. Journal of Alloys and Compounds. 506(1): 136-140.

Qi, T., J. Jiang, H. Chen, H. Wan, L. Miao, and L. Zhang. 2013. Synergistic Effect of Fe3O4/Reduced Graphene Oxide Nanocomposites for Supercapacitors with Good Cycling Life. Electrochimica Acta. 114: 674-680.

Kassaee, M. Z., E. Motamedi, and M. Majdi. 2011. Magnetic Fe3O4-Graphene Oxide/Polystyrene: Fabrication and Characterization of a Promising Nanocomposite. Chemical Engineering Journal. 172 (1): 540-549.

Safarpour, M., A. Khataee, and V. Vatanpour. 2015. Effect of Reduced Graphene Oxide/TiO2 Nanocomposite with Different Molar Ratios on the Performance of PVDF Ultrafiltration Membranes. Separation and Purification Technology. 140: 32-42.

Wang, Z., H. Yu, J. Xia, F. Zhang, F. Li, Y. Xia, and Y. Li. 2012. Novel GO-Blended PVDF uUtrafiltration Membranes. Desalination. 299: 50-54.

Vatanpour, V., S.S. Madaeni, R. Moradian, S. Zinadini, and B. Astinchap. 2011. Fabrication and Characterization of Novel Antifouling Nanofiltration Membrane Prepared from Oxidized Multiwalled Carbon Nanotube/Polyethersulfone Nanocomposite. Journal of Membrane Science. 375(1-2): 284-294.

Rahimpour, A., M. Jahanshahi, S. Khalili, A. Mollahosseini, A. Zirepour, and B. Rajaeian. 2012. Novel Functionalized Carbon Nanotubes for Improving the Surface Properties and Performance of Polyethersulfone (PES) Membrane. Desalination. 286: 99-107.

Esfahani, M. R., J. L. Tyler, H. A. Stretz, and M. J. M. Wells. 2015. Effects of a Dual Nanofiller, Nano-TiO2 and MWCNT, for Polysulfone-Based Nanocomposite Membranes for Water Purification. Desalination. 372: 47-56.

Downloads

Published

2017-01-31

Issue

Vol. 79 No. 1-2: Membranes Technology for Efficient Separation and Energy Generation

Section

Science and Engineering

License

Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.

How to Cite

EVALUATION OF IRON OXIDE DECORATED ON GRAPHENE OXIDE (FE3O4/GO) NANOHYBRID INCORPORATED IN PSF MEMBRANE AT DIFFERENT MOLAR RATIOS FOR CONGO RED REJECTION. (2017). Jurnal Teknologi, 79(1-2). https://doi.org/10.11113/jt.v79.10440