CHARACTERIZATION OF PCL/ZEOLITE ELECTROSPUN MEMBRANE FOR THE REMOVAL OF SILVER IN DRINKING WATER
DOI:
https://doi.org/10.11113/jt.v79.10442Keywords:
Polycaprolactone, zeolite, electrospinning, membrane, adsorptionAbstract
The presence of heavy metals in drinking water leads to several health problems. In this study, polycaprolactone (PCL)/zeolite nano or microfiber electrospun composite membranes, diameter range of the fibers was 2 µm- 6 µm, were fabricated by using electrospinning technique. The membranes separation processes have played very crucial roles in water purification industry. Apart from that, the membranes are prepared with biocompatible, non-toxic materials which will be eco-friendly. In order to produce electrospun membrane, 15% (w/v) of PCL polymer solution was dissolved in acetone and 20% (w/w) zeolite was incorporated into the PCL polymer solution. Electricity charged jet of polymer solution from the syringe formed an electrostatics field when the high voltage of 20kV was applied. Scanning electron micrograph (SEM) and energy dispersive spectroscopy (EDX) implemented to indicate the characterization of membranes. The water contact angle of PCL/zeolite membrane was 119.53±5.24 which was almost same as pure PCL membrane (107.73±8.54). The inducible results obtained in this study suggested that electrospun pcl and polycaprolactone/zeolite layer by layer nanofibrous membranes can be a favored verdict for the removal of heavy metal ions.
References
Homaeigohar, S., and Elbahri, M. 2014. Nanocomposite Electrospun Nanofiber Membranes For Environmental Remediation. Material. 7(2): 1017-1045.
Nalbandian, M. J., Zhang, M., Sanchez, J., Choa, Y. H., Nam, J., Cwiertny, D. M., & Myung, N. V. 2016. Synthesis And Optimization Of Fe2O3 Nanofibers For Chromate Adsorption From Contaminated Water Sources. Chemosphere. 144: 975-981.
Ferreira, V., Koricheva, J., Duarte, S., Niyogi, D. K. and Guérold, F. 2016. Effects Of Anthropogenic Heavy Metal Contamination On Litter Decomposition In Streams–A Meta-Analysis. Environmental Pollution. 210: 261-270.
Wu, Q., Zhou, H., Tam, N. F., Tian, Y., Tan, Y., Zhou, S., Li, Q., Chen, Y. and Leung, J. Y. 2016. Contamination, Toxicity And Speciation Of Heavy Metals In An Industrialized Urban River: Implications For The Dispersal Of Heavy Metals. Marine Pollution Bulletin. 104(1): 153-161.
Li, M., Yang, W., Sun, T. and Jin, Y. 2016. Potential Ecological Risk Of Heavy Metal Contamination In Sediments And Macrobenthos In Coastal Wetlands Induced By Freshwater Releases: A Case Study In The Yellow River Delta, China. Marine Pollution Bulletin. 103(1): 227-239.
Jin, R. M., Sultana, N., Baba, S., Hamdan, S. and Ismail, A. F. 2015. Porous PCL/Chitosan and nHA/PCL/Chitosan Scaffolds For Tissue Engineering Applications: Fabrication And Evaluation. Journal of Nanomaterials. 1-8.
Lim, M. M., Sun, T. and Sultana, N. 2015 In Vitro Biological Evaluation of Electrospun Polycaprolactone/Gelatine Nanofibrous Scaffold for Tissue Engineering. Journal of Nanomaterials. doi:10.1155/2015/303426.
Sultana, N. and Kadir, M. R. A. 2011. Study Of In Vitro Degradation Of Biodegradable Polymer Based Thin Films And Tissue Engineering Scaffolds. African Journal of Biotechnology. 10(81):18709-18715.
Sultana, N. and Wang, M. 2007. Fabrication And Characterisation Of Polymer And Composite Scaffolds Based On Polyhydroxybutyrate And Polyhydroxybutyrate-Co-Hydroxyvalerate. Key Engineering Materials. 334: 1229-1232.
Mallapur, V. P., Oubagaranadin, J. U. K. and Lature, S. S. 2013. Synthesis Of Zeolite From Inorganic Wastes. International Journal of Research in Engineering and Technology. 431-434.
Balamurugan, R., Sundarrajan, S. and Ramakrishna, S. 2011. Recent Trends In Nanofibrous Membranes And Their Suitability For Air And Water Filtrations. Membranes. 1(3): 232-248.
Peter, A., Mihaly-Cozmuta, L., Mihaly-Cozmuta, A., Nicula, C., Indrea, E. and Tutu, H. 2012. Calcium-And Ammonium Ion-Modification Of Zeolite Amendments Affects The Metal-Uptake Of Hieracium Piloselloides In A Dose-Dependent Way. Journal of Environmental Monitoring. 14(10): 2807-2814.
P. Maiti, A. Rai, S. Senapati, and S. Saraf. 2016. Biodegradable Poly(?-caprolactone) As Controlled Drug Delivery Vehicle Of Vancomycin For The Treatment Of MRSA Infection. Journal of Materials Chemistry B. 4(30): 5151-5160.
Ramakrishna, S., Fujihara, K., Teo, W.E., Lim, T. C. and Ma, Z. 2005. An Introduction To Electrospinning And Nanofibers. Singapore: World Scientific.
Sterling, J. P. 2014. Silver-Resistance, Allergy, And Blue Skin: Truth Or Urban Legend? Burns. 40: S19-S23.
Spacciapoli, P., Buxton, D., Rothstein, D. and Friden, P. 2001. Antimicrobial Activity Of Silver Nitrate Against Periodontal Pathogens. Journal of Periodontal Research. 36(2): 108-113.
Boucher, W., Stern, J. M., Kotsinyan, V., Kempuraj, D., Papaliodis, D., Cohen, M. S. and Theoharides, T. C. 2008. Intravesical Nanocrystalline Silver Decreases Experimental Bladder Inflammation. The Journal of Urology. 179(4): 1598-1602.
Wasiak, J., Cleland, H., Campbell, F. and Spinks, A. 2013. Dressings For Superficial And Partial Thickness Burns. The Cochrane Library.
Chang, H. C., Sun, T., Sultana, N., Lim, M. M., Khan, T. H., Ismail, A. F. 2016. Conductive PEDOT:PSS Coated Polylactide (PLA) and Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) Electrospun Membranes: Fabrication and Characterization. Materials Science and Engineering C. 61: 396-410.
Lim, M. M. & Sultana, N. 2016. In Vitro Cytotoxicity And Antibacterial Activity Of Silver-Coated Electrospun Polycaprolactone/gelatine Nanofibrous Scaffolds. 3 Biotech. 6: 211. doi:10.1007/s13205-016-0531-6.
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.