MAGNETIC AND MICROWAVE ABSORPTION PROPERTIES OF NEODYMIUM DOPED NICKEL FERRITE USING MILLING TECHNIQUE
DOI:
https://doi.org/10.11113/jt.v81.11045Keywords:
Nickel ferrite, neodymium, milling technique, microwave absorption, magnetic propertiesAbstract
Nickel ferrite doped by neodymium in the form of (Ni(1-x)NdxFe2O4) with (x = 0.0 ; 0.2 and 0.4) have been synthesized using solid state reaction method with milling technique from NiO, Nd2O3 and Fe2O3 powder. The mixture of those compound materials was milled using High Energy Milling (HEM) machine for 10 hours and then sintered at 1000 °C for 5 h. X-ray diffraction patterns showed that a single phase of spinel ferrite has been formed in all of the compositions. The result of morphological observation using Scanning Electron Microscope (SEM) exhibited a homogeneous structure has been formed with particle size about 200 nm. The magnetic measurement using vibrating sample magnetometer (VSM) showed that the sample exhibited a ferromagnetic behavior, where the Ms value decrease (around of 58.4 to 39.40 emu/g) and value of Hc increased (around of 116-170 Oe) along with the addition of the Nd3+ ion (x values) content. While the ability of microwaves absorption measured by using Vector Network Analyzer (VNA) indicates that the maximum value of Reflection Loss (RL) obtained at the composition of x = 0.4 up to -29 dB at a frequency of 10.81 GHz. It means the Ni0,6Nd0,4Fe2O4 sample can absorb microwave up to ~ 96.5% at a frequency of 10.81 GHz.
References
Ensafi, A. A., Allafchian, A. R. 2013. Multiwall Carbon Nanotubes Decorated with NiFe2O4 Magnetic Nanoparticles, A New Catalyst for Voltammetric Determination of Cefixime. Colloids and Surfaces B: Biointerfaces. 102: 687-693.
Hernández-Gómez, P., Muñoz, J. M., Valente, M. A., Torres, C. and de Francisco C. 2013. Magnetoabsorption and Magnetic Hysteresis in Ni Ferrite Nanoparticles. EPJ Web of Conferences. 40: 17003(1-4).
Lenin, N., Sakthipandi, K., Kanna, R. R., Rajesh, J. 2018. Effect of Neodymium Ion on the Structural, Electrical and Magnetic Properties of Nanocrystalline Nickel Ferrites. Ceramics International. 44: 1562-11569
Mahalakshmi, S. and Manja, K. S. 2015. Spectroscopic and Structural Studies of Nickel Ferrite Doped with Rare Earth Ions. International Journal of ChemTech Research. 7(3): 1460-1464.
Moradmard, H., Shayesteh, S. F. 2015. The Variation of Magnetic Poperties of Nickel Ferrite by Annealing. Manufacturing Science and Technology. 3(4): 141-145.
Shinde, T. J., Gadkari, A. B., Vasambekar, P. N. 2012. Influence of Nd3+ Substitution on Structural, Electrical and Magnetic Properties of Nanocrystalline Nickel Ferrites. Journal of Alloys and Compounds. 513: 80-85.
Farid, M. T., Ahmad, I., Aman, S., Kanwal, M., Murtaza, G., Ali, I., Ahmad, I., Ishfaq, M. 2015. Structural, Electrical and Dielectric Behavior of NixCo1-xNdyFe2-yO4 Nano-ferrites Synthesized by Sol-gel Method. Digest Journal of Nanomaterials and Biostructures. 10(1): 265-275.
PervaizȦ, E. and Gul, I. H. 2013. Magneto-dielectric and Electromagnetic Absorbing Studies of Antimony Doped Nickel Ferrites. International Journal of Current Engineering and Technology. 3(5): 1784-1788.
Tripathi, K. C., Abbas, S. M., Alegaonkar, P. S., Sharma, R. B. 2015. Microwave Absorption Properties of Ni-Zn Ferrite Nano-Particle based Nano Composite. International Journal of Advanced Research in Science, Engineering and Technology. 2(2): 463-468.
Nelson, A. T., White, J. T., Andersson, D. A., Aguiar, J. A., McClellan, K. J., Byler, D. D., Short, M. P., and Stanek, C. R. 2014. Thermal Expansion, Heat Capacity, and Thermal Conductivity of Nickel Ferrite (NiFe2O4). J. Am. Ceram. Soc. 1-7.
Reddy, M. P., Madhuri, W., Sadhana, K., Kim, I. G., Hui, K. N., Hui, K. S., Siva Kumar, K. V., and Reddy, R. R. 2014. Microwave Sintering of Nickel Ferrite Nanoparticles Processed Via Sol-gel Method. J. Sol-Gel Sci. Technol. 70(3): 400-404.
Yousefi, M. and Alimard, P. 2012. Synthesis of M–Nd Doped Fe3O4 Nanoparticles (M = Co, Ce, Cr, Ni) with Tunable Magnetic Properties. Bull. Chem. Soc. Ethiop. 27: 49-56.
Manojit De, Bera, G., Tewar, H. S. 2015. Characterization of Magnesium Substituted Nickel Ferrites Nano-Particles Synthesized Using Combustion Technique. International Journal of Mathematics and Physical Sciences Research. 3(1): 71-76.
Jiao, Q., Wang, Y., Hao, L., Li, H. and Zhao, Y. 2016. Synthesis of Magnetic Nickel Ferrite Microspheres and Their Microwave Absorbing Properties. Chem. Res. Chin. Univ. 32(4): 678-681.
Yunasfi, Wisnu Ari Adi, Mashadi and Putri Astari Rahmy. 2017. Magnetic and Microwave Absortion Properties 0f Nickel Ferrite (NixFe3-xO4) by HEM Technique. Malaysian Journal of Fundamental and Applied Science (MJFAS). 13(3): 203-206.
Ade Mulyawan, Yunasfi dan Wisnu Ari Adi. 2017. The Effect of Milling Time to Microstructure and Magnetic Properties of NiFe2O4-NdFeO3 Composite. Metalurgi. 32(3): 105-114.
Joshi, S., Kumar, M., Chhoker, S., Srivastava, G., Jewariya, M., Singh, V. N. 2014, Structural, Magnetic, Dielectric and Optical Properties of Nickel Ferrite Nanoparticles Synthesized by Co-Precipitation Method. Journal of Molecular Structure. 1076: 55-62.
Sabikoglu, I., Paral, L., Malina, O., Novak, P., Kaslik, J., Tucek, J., Pechousek, J., Navarik, J., Schneeweiss, O. 2015. The Effect of Neodymium Substitution on the Structural and Magnetic Properties of Nickel Ferrite. Progress in Natural Science: Materials International. 25: 215-221.
Rathod, S. M., Bhosale, S. S., Zagade, P. K., Pawar, D. B., Shinde, A. B. 2015. Synthesis and Characterization of La3+ Doped Ni NanoFerriteby Sol-Gel Method 1. Bionano Frontier. 8: 104-106.
Olsson, J. R. T., Savage S. J., Gedde U. W. and Klement U. 2017. Microwave Absorbing Properties of Ferrite-based Nanocomposites. Proc. of SPIE. 6526: (65261P-1).
Li Guo-Min, Wang Lian-Cheng, and Xu Yao. 2014. Templated Synthesis of Highly Ordered Mesoporous Cobalt Ferrite and Its Microwave Absorption Properties Chin. Phys. B. 23(8): 088105(1-7).
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.