ELAEIS GUINEENSIS LEAVES EXTRACTS AS ECO-FRIENDLY CORROSION INHIBITOR FOR MILD STEEL IN HYDROCHLORIC ACID
DOI:
https://doi.org/10.11113/jt.v80.11191Keywords:
Mild steel, Elaeis guineensis, corrosion inhibition, weight loss, SEMAbstract
This manuscript presents a study on a green corrosion inhibitor extracted from Elaeis guineensis (EG) leaves for mild steel (MS) exposed to acidic condition. Weight loss measurement was conducted at various temperatures to investigate the corrosion inhibitive behaviour of the aqueous extract in 1 M HCl solution. Results demonstrated that both inhibition efficiency (η%) and surface coverage (θ) had increased with increasing inhibitor concentration, but decreased with increasing temperature. After immersion for 72 h, the inhibition efficiency were between 60.48% at 319 K and 73.81% at 298 K. Adsorption of extract onto the MS surface was shown to obey Langmuir’s adsorption isotherm while the free energy value (ð™Gads) indicated that the adsorption was characteristic of physisorption. Formation of a protective film onto the metal surface was substantiated by SEM and EDX analyses. The study demonstrated that EG leaves is a potential metal corrosion inhibitor in acidic condition.
References
Helen L., Rahim A., Saad B., Saleh M. and Raja P. B. 2014. Aquilaria Crassna Leaves Extracts – A Green Corrosion Inhibitor for Mild Steel in 1 M HCl Medium. International Journal of Electrochemical Science. 9: 830-846.
De Baere K., Verstraelen H., Rigo P., Van Passel S., Lenaerts S. and Potters G. 2013. Reducing the Cost of Ballast Tank Corrosion: An Economic Modeling Approach. Marine Structures. 32: 136-152.
Jiang G., Keller J., Bond P. L. and Yuan Z. 2016. Predicting Concrete Corrosion of Sewers Using Artificial Neural Network. Water Research. 92: 52-60.
Amin, M. A. and Ibrahim, M. M. 2011. Corrosion and Corrosion Control of Mild Steel in Concentrated H2SO4 Solutions by a Newly Synthesized Glycine Derivative. Corrosion Science. 53: 873-885.
Garai, S., Garai, S., Jaisankar, P., Singh, J. K. and Elango, A. 2012. A Comprehensive Study on Crude Methanolic Extract of Artemisia Pallensb (Asteraceae) and Its Active Component as Effective Corrosion Inhibitors of Mild Steel in Acid Solution. Corrosion Science. 60: 193-204.
Banerjee, S., Srivastava, V. and Singh, M. M. 2012. Chemically Modified Natural Polysaccharide as Green Corrosion Inhibitor for Mild Steel in Acidic Medium. Corrosion Science. 59: 35-41.
Raja P. B., Qureshi A. K., Rahim A. A., Osman H. and Awang K. 2013. Neolamarckia Cadamba Alkaloids as Eco-Friendly Corrosion Inhibitors for Mild Steel In 1 M HCl Media. Corrosion Science. 69: 292-301.
Benali, O., Benmehdi, H., Hasnaoui, O., Selles, C. and Salghi, R. 2013. Green Corrosion Inhibitor: Inhibitive Action of Tannin Extract of Chamaerops Humilis Plant for the Corrosion of Mild Steel in 0.5M H2SO4. Journal of Materials and Environmental Science. 4 (1): 127-138.
Abdulrahman A., Ismail M., Hussain M. S. 2011. Inhibition of Corrosion of Mild Steel in Hydrochloric Acid by Bambusa Arundinacea. International Review of Mechanical Engineering. 5(1): 59-63.
Asaad, M. A., Ismail, M., Raja P. B. and Khalid, N. H. A. 2018. Rhizophora Apiculata as Eco-Friendly Inhibitor against Mild Steel Corrosion in 1 M HCl. Surface Review and Letters. 24(8): 1-11.
Mehdipour, M., Ramezanzadeh, B. and Arman, S. Y. 2015. Electrochemical Noise Investigation of Aloe Plant Extract as Green Inhibitor on the Corrosion of Stainless Steel in 1 M H2SO4. Journal of Industrial and Engineering Chemistry. 21: 318-327.
Asaad, M. A., Sarbini, N. N., Sulaiman. A., Ismail, M., Huseien. G. F., Majid. Z. A. and Raja P. B. 2018. Improved Corrosion Resistance of Mild Steel Against Acid Activation: Impact of Novel Elaeis Guineensis and Silver Nanoparticles. Journal of Industrial and Engineering Chemistry. 63: 139-148.
Zulkiflia, F., Alia, N., Sukeri, M., Yusof, M., Isa, M. I. N., Yabuki, A. and W.B. Wan Nika, W. B. W. 2017. Henna Leaves Extract as a Corrosion Inhibitor in Acrylic Resin Coating. Progress in Organic Coatings. 105: 310-319.
Ituen, E., Akaranta, O., James, A. and Sun, S. 2017. Green and Sustainable Local Biomaterials for Oilfield Chemicals: Griffonia Simplicifolia Extract as Steel Corrosion Inhibitor in Hydrochloric Acid. Sustainable Materials and Technologies. 11: 12-18.
El-Etre, A. Y., Ali, A. I. 2017. A Novel Green Inhibitor for C-Steel Corrosion in 2.0 Mol•L−1 Hydrochloric Acid Solution. Chinese Journal of Chemical Engineering. 25: 373-380.
Szymona, K., Borysiuk, P., San H’ng, P., Chin, K. L. and Mamiński, M. 2014. Valorization of Waste Oil Palm (Elaeis Guineensis Jacq.) Biomass through Furfurylation. Materials & Design. 53: 425-429.
Chang, S. K., Ismail, A., Yanagita, T., Esa, N. M. and Baharuldin, M. T. H. 2015. Antioxidant Peptides Purified and Identified from the Oil Palm (Elaeis Guineensis Jacq.) Kernel Protein Hydrolysate. Journal of Functional Foods. 14: 63-75.
Kok, S., Ong-Abdullah, M., Ee, G. C. and Namasivayam, P. 2011. Comparison of Nutrient Composition in Kernel of Tenera and Clonal Materials of Oil Palm (Elaeis Guineensis Jacq.) Food Chemistry. 12: 91343-1347.
Soundararajan, V. and Sreenivasan, S. 2012. Antioxidant Activity of Elaeis Guineensis Leaf Extract: An Alternative Nutraceutical Approach in Impeding Aging. APCBEE Procedia. 2: 153-159.
Bhawsar, J., Jain, P. K. and Jain, P. 2015. Experimental and Computational Studies of Nicotiana Tabacum Leaves Extract as Green Corrosion Inhibitor for Mild Steel in Acidic Medium. Alexandria Engineering Journal. 54: 769-775.
Abiola, O. K. and Tobun Y. 2010. Cocos Nucifera L. Water as Green Corrosion Inhibitor for Acid Corrosion of Aluminium in HCl Solution. Chinese Chemical Letters. 21: 1449-1452.
Eyu, D. G., Esah, H., Chukwuekezie, C., Idris, J. and Ismail, M. 2013. Effect of Green Inhibitor on the Corrosion Behaviour of Reinforced Carbon Steel in Concrete. ARPN Journal of Engineering and Applied Sciences. 8(5): 326-332.
Solomon, M. M., Umoren, S. A., Udosoro, I. I. and Udoh, A. P. 2010. Inhibitive and Adsorption Behaviour of Carboxymethyl Cellulose on Mild Steel Corrosion in Sulphuric Acid Solution. Corrosion Science. 52: 1317-1325.
Alaneme K. K., Olusegun, S. J. and Adelowo, O. T. 2016. Corrosion Inhibition and Adsorption Mechanism Studies of Hunteria Umbellata Seed Husk Extracts on Mild Steel Immersed in Acidic Solutions. Alexandria Engineering Journal. 55: 673-681.
ALI, S. M. and Al LEHAIBI, H. A. 2016. Control of Zinc Corrosion in Acidic Media: Green Fenugreek Inhibitor. Transactions of Nonferrous Metals Society of China. 26: 3034-3045.
Odewunmi, N., Umoren, S. and Gasem, Z. 2015. Utilization of Watermelon Rind Extract as a Green Corrosion Inhibitor for Mild Steel in Acidic Media, Journal of Industrial and Engineering Chemistry. 21: 239-247.
Abu-Dalo, M. A., Al-Rawashdeh, N. A. and Mutlaq. A. A. 2016. Green Approach to Corrosion Inhibition of Mild Steel by Lignin Sulfonate in Acidic Media. Journal of Iron and Steel Research, International. 23: 722-732.
Kowsari, E., Payami, M., Amini, R., Ramezanzadeh, B. and Javanbakht, M. Task-Specific Ionic Liquid as A New Green Inhibitor of Mild Steel Corrosion. Applied Surface Science. 289: 478-486.
Verma, C., Singh, P. and Quraishi, M. A. 2016. A Thermodynamical, Electrochemical and Surface Investigation of Bis (Indolyl) Methanes as Green Corrosion Inhibitors for Mild Steel in 1 M Hydrochloric Acid Solution. Journal of the Association of Arab Universities for Basic and Applied Sciences. 21: 24-30.
Hussin, M. H. and Kassim, M. J. 2011. The Corrosion Inhibition and Adsorption Behavior of Uncaria Gambir Extract on Mild Steel in 1M HCl. Materials Chemistry and Physics. 125: 461-468.
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.