INFLUENCE OF SONICATION ASSISTED DISPERSION METHOD ON THE MECHANICAL AND ELECTRICAL PROPERTIES OF NYLON 66/NANO-COPPER NANOCOMPOSITE

Authors

  • Mohammed Iqbal Shueb Radiation Processing Technology Division, Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor, Malaysia
  • Mohd Edeerozey Abd Manaf Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia
  • Chantara Thevy Ratnam Radiation Processing Technology Division, Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor, Malaysia
  • Noraiham Mohamad Faculty of Manufacturing Engineering, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, MalaysiabRadiation Processing Technology Division, Malaysian Nuclear Agency, Bangi, 43000 Kajang, Selangor, Malaysia

DOI:

https://doi.org/10.11113/jt.v79.11287

Keywords:

Nylon 66, nano-copper, nanocomposite, sonication, EMI shielding

Abstract

Nylon 66 is a well known engineering polymer with excellent mechanical and thermal properties. However, its poor electrical conductivity restricts its application for conductive material. In this study, nano-copper particles are added into nylon 66 polymer matrix to enhance the electrical conductivity value of the nanocomposite. Sonication assisted dispersion method was used to achieve well dispersed nanomaterials through reasonable exfoliation of the nano-copper particles in the nylon 66 polymer. The impact of sonication on the mechanical performance and the electrical conductivity of nanocomposite were evaluated. The sonication was found to effectively reduce agglomeration of nano-coppers in nylon 66, and improved both mechanical performance and electrical conductivity of the nanocomposite. Irrespective of the nano-copper amount, nanocomposite with sonication-treated nano-copper consistently showed higher hardness and impact strength than nanocomposite without sonication. The electrical conductivity increased by two orders of magnitude from 10-15 to 10-13 for the nanocomposite added with sonication-treated nano-copper compared to that without sonication treatment.

References

Sudha, J. D., Sivakala, S., Patel, K. and Nair, P. R. 2010. Development of Electromagnetic Shielding Materials from the Conductive Blends of Polystyrene Polyaniline-Clay Nanocomposite. Composites Part A: Applied Science and Manufacturing. 41(11): 1647-1652.

Chung, D. D. L. 2001. Electromagnetic Interference Shielding Effectiveness of Carbon Materials. Carbon. 39(2): 279-285.

Park, K. Y., Lee, S. E., Kim, C. G. and Han, J. H. 2007. Application of MWNT-Added Glass Fabric/Epoxy Composites to Electromagnetic Wave Shielding Enclosures. Composite Structures. 81(3): 401-406.

Im, J. S., Kim, J. G., Lee, S. H. and Lee, Y. S. 2010. Enhanced Adhesion and Dispersion of Carbon Nanotube in PANI/PEO Electrospun Fibers for Shielding Effectiveness of Electromagnetic Interference. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 364(1): 151-157.

Geetha, S., Satheesh Kumar, K. K., Rao, C. R., Vijayan, M. and Trivedi, D. C. 2009. EMI Shielding: Methods and Materials—A Review. Journal of Applied Polymer Science. 112(4): 2073-2086.

Fox, R. T., Wani, V., Howard, K. E., Bogle, A. and Kempel, L. 2008. Conductive Polymer Composite Materials and Their Utility in Electromagnetic Shielding Applications. Journal of Applied Polymer Science. 107(4): 2558-2566.

Soto-Oviedo, M. A., Araújo, O. A., Faez, R., Rezende, M. C. and De Paoli, M. A. 2006. Antistatic Coating and Electromagnetic Shielding Properties of a Hybrid Material Based on Polyaniline/Organoclay Nanocomposite and EPDM Rubber. Synthetic Metals. 156(18): 1249-1255.

Menchaca, C., Manoun, B., Martínez-Barrera, G., Castaño, V. M. and López-Valdivia, H. 2006. In Situ High-Temperature Raman Study of Crystalline Nylon 6,12 Fibers Gamma-Irradiated in Argon Atmosphere. Journal of Physics and Chemistry of Solids. 67(9): 2111-2118.

Biçer, M. and Şişman, İ. 2010. Controlled Synthesis of Copper Nano/Microstructures using Ascorbic Acid in Aqueous CTAB Solution. Powder Technology. 198(2): 279-284.

Hielscher, T. 2005. Ultrasonic Production of Nano-Size Dispersions and Emulsions. Ens’05. December. 14-16.

Liu, Y. and Kumar, S. 2014. Polymer/Carbon Nanotube Nano Composite Fibers – A Review. ACS Applied Materials & Interfaces. 6(9): 6069-6087.

Kim, K. T. and Jo, W. H. 2009. Synthesis of Poly (3-Hexylthiophene)-Graft-Poly (t-Butyl Acrylate-Co-Acrylic Acid) and its Role of Compatibilizer for Enhancement of Mechanical and Electrical Properties of Nylon 66/Multi-Walled Carbon Nanotube Composites. Composites Science and Technology. 69(13): 2205-2211.

Arranz-Andrés, J., Pérez, E. and Cerrada, M. L. 2012. Hybrids Based on Poly(Vinylidene Fluoride) and Cu Nanoparticles: Characterization and EMI Shielding. European Polymer Journal. 48(7): 1160-1168.

Al-Ghamdi, A. A. and El-Tantawy, F. 2010. New Electromagnetic Wave Shielding Effectiveness at Microwave Frequency of Polyvinyl Chloride Reinforced Graphite/Copper Nanoparticles. Composites Part A: Applied Science and Manufacturing. 41(11): 1693-1701.

Yao, S. H., Dang, Z. M., Jiang, M. J., Xu, H. P. and Bai, J. 2007. Influence of Aspect Ratio of Carbon Nanotube on Percolation Threshold in Ferroelectric Polymer Nanocomposite. Applied Physics Letters. 91(21): 212901.

Arranz-Andres, J. and Cerrada, M. L. 2013. Conductive Poly (Vinylidene Fluoride)/Copper Hybrids: Mechanical Response and Percolation Threshold. Science of Advanced Materials. 5(3): 233-241.

Downloads

Published

2017-07-19

How to Cite

INFLUENCE OF SONICATION ASSISTED DISPERSION METHOD ON THE MECHANICAL AND ELECTRICAL PROPERTIES OF NYLON 66/NANO-COPPER NANOCOMPOSITE. (2017). Jurnal Teknologi (Sciences & Engineering), 79(5-2). https://doi.org/10.11113/jt.v79.11287