Treatment of Textile Wastewater using Chitosan and Chitosan Grafted Acrylamide by Microwave Synthesis

Authors

  • Norzita Ngadi FKK, UTM JB
  • Nurul Jannah Arsad Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Noor Azuin Roslan Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v63.1171

Keywords:

Chitosan, PAM, flocculation, grafted flocculant

Abstract

Polymeric flocculants based on single chitosan and polyacrylamide grafted chitosan (Ch-g-PAM) have been successfully synthesized via microwave initiated method. Under optimal grafting conditions, 30.4% grafting has been observed in case of the microwave irradiation with exposed time, 76s and power, 640MW (80% from full power). The synthesized graft copolymers have been characterized by FTIR spectroscopy. Acidic medium was the best condition for flocculation with optimum pH of 3 and 4 using Ch-g-PAM and Chitosan, respectively. The longer the settling time, the better the flocculation performance as long as the flocs did not break. 60-90 minutes was the best settling time with optimum dosage of 0.1 g for both flocculants. Grafted chitosan with PAM showed the best result in removing the contaminants compared to single chitosan.

 

References

Riera-Torres, M., Gutiérrez-Bouzán, C., & Crespi, M. 2010. Combination of Coagulation-Flocculation and Nanofiltration Techniques for Dye Removal and Water Reuse in Textile Effluents. Desalination. 252(1–3): 53–59.

Menezes, F. M., Amal, R., & Luketina, D. 1996. Removal of Particles Using Coagulation and Flocculation in a Dynamic Separator. Powder Technology. 88(1): 27–31.

Sinha, S., Yoon, Y., Amy, G., & Yoon, J. 2004. Determining the Effectiveness of Conventional and Alternative Coagulants Through Effective Characterization Schemes. Chemosphere. 57(9): 1115–1122.

Chatterjee, T., Chatterjee, S., Lee, D. S., Lee, M. W., & Woo, S. H. 2009. Coagulation of Soil Suspensions Containing Nonionic or Anionic Surfactants Using Chitosan, Polyacrylamide, and Polyaluminium Chloride. Chemosphere. 75(10): 1307–1314.

Zhou, Y., Liang, Z., & Wang, Y. 2008. Decolorization and COD Removal of Secondary Yeast Wastewater Effluents by Coagulation Using Aluminum Sulfate. Desalination. 225(1–3): 301–311.

Wong, S. S., Teng, T. T., Ahmad, A. L., Zuhairi, A., & Najafpour, G. 2006. Treatment of Pulp and Paper Mill Wastewater by Polyacrylamide (PAM) in Polymer Induced Flocculation. Journal of Hazardous Materials. 135(1–3): 378–388.

Singh, V., Sharma, A. K., & Sanghi, R. 2009. Poly(acrylamide) Functionalized Chitosan: An Efficient Adsorbent for Azo Dyes from Aqueous Solutions. Journal of Hazardous Materials. 166(1): 327–335.

Singh, V., Tiwari, A., Tripathi, D. N., & Sanghi, R. 2006. Microwave Enhanced Synthesis of Chitosan-graft-polyacrylamide. Polymer. 47(1): 254–260.

Downloads

Published

2013-07-11

Issue

Section

Science and Engineering

How to Cite

Treatment of Textile Wastewater using Chitosan and Chitosan Grafted Acrylamide by Microwave Synthesis. (2013). Jurnal Teknologi, 63(1). https://doi.org/10.11113/jt.v63.1171