HYDROGENATION OF CITRONELLA OIL DERIVATIVES TO 3,7-DIMETHYL-1-OCTANOL AS POTENTIAL BIO-BASED ADDITIVES OVER MODIFIED NATURAL ZEOLITE CATALYSTS

Authors

  • Silvester Tursiloadi Research Centre for Chemistry, Indonesian Institute of Sciences Kawasan PUSPIPTEK Serpong, Tangerang, 15314, Indonesia
  • Ralentri Pertiwi Research Centre for Chemistry, Indonesian Institute of Sciences Kawasan PUSPIPTEK Serpong, Tangerang, 15314, Indonesia
  • Akbar Litiaz Faculty of Sains and Technology, Islamic Syarif Hidayatullah State Islamic University, Jakarta, Indonesia
  • Indri Badria Adilina Research Centre for Chemistry, Indonesian Institute of Sciences Kawasan PUSPIPTEK Serpong, Tangerang, 15314, Indonesia

DOI:

https://doi.org/10.11113/jt.v79.11869

Keywords:

Citronella oil derivatives, 3, 7-dimethyl-1-octanol, natural zeolite, nickel zeolite, bio-based additives

Abstract

An alternative way for saving energy and reduce emission in fuel consumption is using oxygenate compounds as fuel additives that can reduce carbon monoxide and soot that is created during the burning of the fuel. One derivatives of citronella oil fraction, 3,7-dimethyl-1-octanol, is a potential alcohol compound for fragrance and fuel additives producing efficiency energy and environmentally friendly. In this research, the conversion of citronella oil fraction (containing> 60% citronellal) into 3,7-dimethyl-1-octanol was investigated using Ni based natural zeolite-Bogor (ZAB) catalysts through hydrogenation process. The structure and properties of the Ni/ZAB catalysts have been investigated extensively using some of characterization techniques for solid materials i.e. XRF and TEM. Variations of weight catalysts and temperature reaction were conducted to determine the optimum conditions for this reaction. The products were analyzed using GC-MS instrumentation. The optimum conditions for the hydrogenation of citronella oil fractions using catalysts Ni / ZAB-20wt% -HT were obtained at 300oC with 10% weight of catalysts produced 12% of the 3,7-dimethyl-1-octanol compound.

References

Sudarsanam, P., Mallesham, B., Prasad, A. N., Reddy, P. S., Benjaram and Reddy, M. 2013. Synthesis of Bio–additive Fuels from Acetalization of Glycerol with Benzaldehyde over Molybdenum Promoted Green Solid Acid Catalysts. Fuel Processing Technology. 06: 539-545.

Yao, C., Zhang, Z., Xu, Y. and Huang, Y. 2008. Experimental Investigation of Effects of Bio-Additives on Fuel Economy of the Gasoline Engine. Science in China Series E: Technological Sciences. 51(8): 1177-1185.

Chauhan, B. S., Singh, R. K., Cho, H. M., Lim, H. C. 2016. Practice of Diesel Fuel Blends Using Alternative Fuels: A Review. Renewable and Sustainable Energy Reviews. 59: 1358-1368

Yang W. M., An, H., Chou, S. K., Vedharaji, S., Vallinagam, R., Balaji, M., Mohammad, F. E. A., Chua, K. J. E. 2013. Emulsion Fuel With Novel Nano-Organic Additives for Diesel Engine Application. Fuel. 104: 726-731.

Kadarohman, A., Hernani, Rohman, I., Kusrini, R., Astuti, R. M. 2012. Combustion Characteristics of Diesel Fuel on One Cylinder Diesel Engine Using Clove Oil, Eugenol, and Eugenyl Acetate as Fuel Bio-Additives. Fuel. 98: 73-79.

Sutrisno. 2015. Effect of Using Cloves Oil as Bio-Additive Fuels on the Performance of A4-Strokes Petrol Motorcycle, Lampung: Fakultas Teknik, Universitas Lampung.

Tursiloadi, S., Litiaz, A. A., Pertiwi, R., Adilina, I. B., Sembiring, K. C. 2015. Development of Green-Nickel Based Catalysts for Citronella Oil Conversion to Isopulegol. Procedia Chemistry.16: 563-569.

Adilina, I. B., Agustian, E. 2014. Green Synthesis of Isopulegol from Citronellal Catalysed by Zeolite Based Solid Acid Catalyst. Jurnal Chimica Et Natura Acta. 2(1): 58-60.

Pertiwi, R., Tursiloadi, S., Adilina, I. B., Sembiring, K., Oaki, Y. 2016. Nickel Supported Natural Zeolite as a Bifunctional Catalysts for Conversion of Citronella Oil Crude to Menthol. Indonesian Journal of Applied Chemistry. 18(2): 132-137.

Budiyanto, R. 2012. Aktivitas dan Selektivitas Katalis Ni/H5NZA terhadap Hidrorengkah Metil Oleat menjadi Senyawa Hidrokarbon Fraksi Pendek, Jember: Universitas Jember.

Mahardiani, L., Trisunaryanti, W. and Triyono. 2010. Preparation and Characterization of Natural Zeolite Catalyst for Hydrocracking of Process. The 2th International Conference on Chemical Sciences (ICCS-2010). Yogyakarta, Indonesia. 14-16 October 2010.

Chuah, G. K., Liu, S., Jaenicke, S. and Harrison, L. 2001. Cyclisation of Citronellal to Isopulegol Catalyzed by Hydrous Zirconia and Other Solid Acids. Journal of Catalysis. 200: 352-359.

Milone, C., Gangemi, C., Ingoglia, R., Neri, G., Galvagno, S.. 1999. Role of the Support in the Hydrogenation of Citronellal on Ruthenium Catalysts. Applied Catalysis A: General. 184: 89-94.

Adilina, I. B., Pertiwi, R. and Sulaswatty, A. 2014. Conversion of Citronella Oil and Its Derivatives to Menthol over Bifunctional Nickel Zeolite Catalysts. Biopropal Industri. 6(1): 1-6.

Fessenden, R. and Fessenden, J. 1986. Kimia Organik Jilid 2. 3 Edisi Ke-2. Jakarta: Erlangga.

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Published

2017-11-02

How to Cite

HYDROGENATION OF CITRONELLA OIL DERIVATIVES TO 3,7-DIMETHYL-1-OCTANOL AS POTENTIAL BIO-BASED ADDITIVES OVER MODIFIED NATURAL ZEOLITE CATALYSTS. (2017). Jurnal Teknologi, 79(7-2). https://doi.org/10.11113/jt.v79.11869