ANTICORROSION PERFORMANCE OF SELF-HEALING POLYMERIC COATINGS ON LOW CARBON STEEL SUBSTRATES

Authors

  • Muhammad Ashraff Ahmad Seri Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Esah Hamzah Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Abdelsalam Ahdash Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mohd Fauzi Mamat Faculty of Engineering Technology, Universiti Teknikal Malaysia Melaka, Hang Tuah Jaya, 76100 Durian Tunggal, Melaka, Malaysia

DOI:

https://doi.org/10.11113/jt.v79.12268

Keywords:

Self-healing coating, Zeolite, Microcapsule, Low carbon steel, Corrosion resistance

Abstract

Recently, self-healing coating is classified as one of the smart coatings which has the ability to heal or repair damage of the coating to prevent further corrosion. The aim of this study is to synthesize the self-healing coatings from polymeric material and evaluate the performance and their corrosion behavior when coated on steel substrates. The corrosion tests were performed using immersion test and salt spray test method at room temperature. The immersion test shows that self-healing coating gives lower corrosion rate compared to pure epoxy paint, with a value of 0.02 and 0.05 mm/year respectively. Also, salt spray test shows similar trend as the immersion test, which is 0.11 and 0.19 mm/year for self-healing coating and pure epoxy paint respectively. While uncoated samples without any protection corroded at 0.89 mm/year. It was also found that the damage on self-healing coating was covered with zeolite from the microcapsules indicating that the self-healing agent was successfully synthesized and could function well. In other words, self-healing coating shows better corrosion resistance compared to the pure epoxy coating on steel substrate.

References

Szczepanowicz, K., Mordarski, G., Podgórna, K., Socha, R., Nowak P., Warsynski P., and Hack T. 2015. Self-healing Epoxy Coatings Loaded with Inhibitor-containing Polyelectrolyte Nanocapsules. Prog. in Org. Coatings. 84: 97-106.

Kumar, A., Stephenson, L. D., and Murray, J. N. 2006. Self-Healing Coatings for Steel. Prog. in Org. Coatings. 55: 244-253.

Siva, T., Sathiyanarayanan, S. 2015, Self-healing Coatings Containing Dual Active Agent Loaded Urea Formaldehyde (UF) Microcapsules. Prog. in Org. Coatings. 82: 57-67.

Yu, D., Zhi, M. and Qiu, M., 2015, Self-healing Polymeric Materials Based on Microencapsulated Healing Agents : From Design to Preparation. Prog. in Polym. Sci. 49-50: 175-220.

Lang, S. and Zhou, Q. 2017. Synthesis and Characterization of Poly(Urea-Formaldehyde) Microcapsules Containing Linseed Oil for Self-healing Coating Development. Prog. in Org. Coatings. 105: 99-110.

Leping, L., Wei, Z., Yi, X. I. N., Hongmei, W., Yang Z. and Wu J. L. 2011. Preparation and Characterization of Microcapsule Containing Epoxy Resin and Its Self-healing Performance of Anticorrosion Covering Material. Chinese Science Bulletin. 56: 439-443.

Blaiszik, B. J., Caruso, M. M., Mcilroy, D. A., Moore, J. S., White S. R., and Sottos, N. R. 2009. Microcapsules Filled with Reactive Solutions for Self-healing Materials. Polymer. 50: 990-997.

Bollinger, J., Britton, J., Gisin, N., Knight, P., Brown E. N. and Viswanathan, S. 2001, Autonomic Healing of Polymer Composites. Letters to Nature. 409: 1804-1807.

García, S. J., Fischer, H. R., Zwaag and S. Van Der. 2011. A Critical Appraisal of the Potential of Self-healing Polymeric Coatings. Prog. in Org. Coatings. 72: 211-221.

Samadzadeh, M., Boura, S. H., Peikari, M., Kasiriha and S. M., Ashrafi, A. 2010. A Review on Self-Healing Coatings Based on Micro/Nanocapsules. Prog. in Org. Coatings. 68: 159-164.

Gonzalez, S. and Kittel, J. 2008. Self-healing Coatings : An Alternative Route for Anticorrosion Protection. Prog. in Org. Coatings. 63: 307-315.

Nesterova, T., Dam-johansen, K. and Kiil, S. 2011. Synthesis of Durable Microcapsules for Self-healing Anticorrosive Coatings : A Comparison Of Selected Methods. Prog. in Org. Coatings. 70: 342-352.

Nesterova, T., Dam-johansen, K., Thorslund, L. and Kiil, S. 2012. Microcapsule-based Self-healing Anticorrosive Coatings : Capsule Size, Coating Formulation, and Exposure Testing. Prog. in Org. Coatings. 75: 309-318.

Islam, N., Halder, S. and Goyat, M. S. 2016. Effect of Epoxy Resin and Hardener Containing Microcapsules on Healing Efficiency of Epoxy Adhesive Based Metal Joints. Mater. Chem. Phys. 171: 267-275.

Paliwoda-porebska, G., Stratmann, M. and Rohwerder, M. 2005. On the Development of Polypyrrole Coatings with Self-healing Properties for Iron Corrosion Protection. Corrosion Science. 47: 3216-3233.

Yang, Z., Wei, Z., Le-Ping W., Mei, W. H., and Jun, L. W. 2011. The Self-healing Composite Anticorrosion Coating. Physics Proceedia. 18: 216-221.

Suryanarayana, C., Rao, K.C. and Kumar, D. 2008. Preparation and Characterization of Microcapsules Containing Linseed Oil and Its Use in Self-healing Coatings. Prog. in Org. Coatings. 63: 72-78.

Boura, S. H., Peikari, M., Ashrafi, A. and Samadzadeh, M. 2012. Self-healing Ability and Adhesion Strength of Capsule Embedded Coatings-Micro and Nano Sized Capsules Containing Linseed Oil. Prog. in Org. Coatings. 75: 292-300.

Aishah, S., Hanim, M., Ahmad, N., Nik and N., Ibrahim, Z., 2017. Analyses of surface Area, Porosity, Silver Release and Antibacterial Activity of Amine-functionalized, Silver-Exchanged Zeolite NaY. Vaccum. 143: 344-347.

Sánchez, M. J., Mauricio, J. E., Paredes, A. R., Gamero and P., Cortés, D. 2017. Antimicrobial Properties of ZSM-5 Type Zeolite Functionalized with Silver. Material letters. 191: 65-68.

ASTM G31-24. 2004. Standard Practice for Laboratory Immersion Corrosion Testing of Metals. ASTM International, West Conshohocken, PA.

ASTM B117-11. Standard Practice for Operating Salt Spray (Fog) Apparatus. ASTM International, West Conshohocken, PA.

Liu, X., Zhang, H., Wang, J., Wang, Z. and Wang, S. 2012. Preparation of Epoxy Microcapsule Based Self-healing Coatings And Their Behavior. Surf. & Coat. Technol. 206: 4976-4980.

Yang, Z., Wei, Z., Le-ping, L., Si-jie, W. and Wu-jun, L., 2012. Self-healing Coatings Containing Microcapsule. Appl. Surf. Sci. 258: 1915-1918.

Thanawala, K., Mutneja, N., Khanna, A. S. and Raman, R. K. S. 2014. Development of Self-healing Coatings based on Linseed Oil as Autonomous Repairing Agent for Corrosion Resistance. Materials. 7: 7324-7338.

Manasa, S., Jyothirmayi, A., Siva, T., Sathiyanarayanan, S., Gobi, K. V. and Subasri R. 2017. Effect of Inhibitor Loading into Nanocontainer Additives of Self-healing Corrosion Protection Coatings on Aluminum Alloy A356. J. Alloys Compd. 726: 969-977.

Sun, D., Zhang, H., Tang, X. and Yang, J. 2016. Water Resistant Reactive Microcapsules for Self-healing Coatings in Harsh Environments. Polymer. 91: 33-40.

Huang, M., Zhang, H. and Yang, J. 2012. Synthesis of Organic Silane Microcapsules for Self-healing Corrosion Resistant Polymer Coatings. Corros. Sci. 65: 561-566.

Kouhi, M., Mohebbi, A., Mirzaei, M. and Peikari, M. 2013. Optimization of Smart Self-healing Coatings Based on Micro/Nanocapsules in Heavy Metals Emission Inhibition. Prog. in Org. Coatings.

Plawecka, M., Snihirova, D., Martins, B., Szczepanowicz, K., Warszynski, P. and Montemor, M. F. 2014. Self Healing Ability of Inhibitor-containing Nanocapsules Loaded in Epoxy Coatings Applied on Aluminium 5083 and Galvanneal Substrates. Electrochimica Acta. 140: 282-293.

Salehi, E., Naderi, R. and Ramezanzadeh, B. 2017. Improvement in the Protective Performance of Epoxy Ester Coating Through Inclusion of an Effective Hybrid Green Corrosion Inhibitive Pigment. J. Taiwan Inst. Chem. Eng. 000: 1-15.

Kongparakul, S., Kornprasert, S., Suriya, P. and Le, D. 2017. Self-healing Hybrid Nanocomposite Anticorrosive Coating From Epoxy/Modified Nanosilica/Perfluorooctyl Triethoxysilane. Prog. in Org. Coatings. 104: 173-179.

Huang, M. and Yang, J. 2014. Salt Spray and EIS Studies on HDI Microcapsule-based Self-healing Anticorrosive Coatings. Prog. in Org. Coatings. 77: 168-175.

Hao, Y., Liu, F. and Han, E., 2013. Protection of Epoxy Coatings Containing Polyaniline Modified Ultra-short Glass Fibers. Prog. in Org. Coatings. 76: 571-580.

Jadhav, A. J., Holkar, C. R. and Pinjari, D. V. 2018. Anticorrosive Performance of Super-hydrophobic Imidazole Encapsulated Hollow Zinc Phosphate Nanoparticles on Mild Steel. Prog. in Org. Coatings. 114: 33-39

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Published

2017-12-07

How to Cite

ANTICORROSION PERFORMANCE OF SELF-HEALING POLYMERIC COATINGS ON LOW CARBON STEEL SUBSTRATES. (2017). Jurnal Teknologi, 79(7-4). https://doi.org/10.11113/jt.v79.12268