Polyion Complex Chitosan Membrane Consisting of Sodium Alginate/Chitosan for the Pervaporation Separation of Methanol/Methyl tert-butyl Ether Mixtures

Authors

  • M. G. Mohd Nawawi Centre of Lipid Engineering and Applied Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Zafifah Zamrud Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v66.1301

Keywords:

Chitosan, sodium alginate, membrane, pervaporation

Abstract

The polyion complex (PIC) composite membranes consisting of chitosan (CS) and sodium alginate (SA) were prepared for the separation of methanol/methyl tert-butyl ether (MTBE) mixtures via pervaporation process. Membrane morphologies showed that CS and SA were homogenously intermixed for all blended ratio tested. Swelling characteristics observed all membranes were readily swelled in the solution mixtures containing more methanols. Separation performance of the membranes via pervaporation was performed on the effect of SA composition in the membrane blend, effect of MTBE concentration in the feed and effect of feed temperature. Overall separation performances showed that the membranes were highly permselective towards methanol due to the affinity and polarity for all the studied parameters.

 

References

Devi, D. A., Smitha, B., Sridhar, S., & Aminabhavi, T. M. 2005. Pervaporation Separation of Isopropanol/Water Mixtures through Crosslinked Chitosan Membranes. Journal of Membrane Science. 262: 91–99.

Wang, X. P., Shen, Z. Q., Zhang, F. Y., & Zhang, Y. F. 1996. A Novel Composite Chitosan Membrane for the Separation of Alcohol-Water Mixtures. Journal of Membrane Science. 119: 191–198.

Xiao, Q., Tong, Q., and Lim, L.-T. 2012. Pullulan-Sodium Alginate Based Edible Films: Rheological Properties of Film Forming Solutions. Carbohydrate Polymers. 87: 1689–1695.

Kim, S. G., Lim, G. T., Jegal, J., & Lee, K. H. 2000. Pervaporation Separation of MTBE (methyl tert-butyl ether) and Methanol Mixtures through Polyion Complex Composite Membranes Consisting of Sodium Alginate/Chitosan. Journal of Membrane Science. 174: 1–15.

Kanti, P., Srigowri, K., Madhuri, J., Smitha, B., & Sridhar, S. 2004. Dehydration of Ethanol through Blend Membranes of Chitosan and Sodium Alginate by Pervaporation. Separation and Purification Technology. 40: 259–266.

Thiyagarajan, R., Ravi, S., & Bhattacharya, P.K. 2011. Pervaporation of Methyl-ethyl Ketone and Water Mixture: Determination of Concentration Profile. Desalination. 277: 178–186.

Yeom, C. K., and Lee, K. H. 1998. Characterization of Sodium Alginate and Poly(vinyl alcohol) Blend Membranes in Pervaporation Separation. Journal of Applied Polymer Science. 67: 949–959.

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Published

2013-12-19

Issue

Section

Science and Engineering

How to Cite

Polyion Complex Chitosan Membrane Consisting of Sodium Alginate/Chitosan for the Pervaporation Separation of Methanol/Methyl tert-butyl Ether Mixtures. (2013). Jurnal Teknologi (Sciences & Engineering), 66(1). https://doi.org/10.11113/jt.v66.1301