SOLUTION PARAMETER EFFECT ON POLYSULFONE FIBERS VIA ELECTROSPINNING: FABRICATION, CHARACTERIZATION AND WATER FLUX PROPERTY

Authors

  • Tan Yong Chee Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Abdull Rahim Mohd Yusoff Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Nur Atika Rahmat Department of Chemistry, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Nik Ahmad Nizam Nik Malek Department of Biosciences, Faculty of Science, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v81.13439

Keywords:

Electrospinning, polysulfone, manganese(IV) oxide nanoparticles

Abstract

This research investigates the solution parameters, i.e., polymer concentration and addition of manganese (IV) oxide (MnO2) nanoparticles, for the fabrication of polysulfone (PSF) fibers via electrospinning. Initially, PSF was dissolved in N,N-dimethylformamide (DMF) solvent and electrospun fibers with different morphologies were obtained using the range of PSF concentration of 10% (w/v) to 25% (w/v). Subsequently, PSF with the concentration of 20% (w/v) (denoted as PSF(20%)) was chosen to blend with 0.2% (w/v) of MnO2 as it gave the most stable electrospinnability and uniform fiber diameter. The fabricated electrospun PSF(20%) and PSF(20%)-MnO2 fibrous membranes were characterized to determine the morphology, wettability property, zeta potential, and tensile strength. The presence of MnO2 improved tensile strength as it reduced the fiber diameter that eventually made a more compact fiber mat membrane. The results of contact angle confirmed that the fabricated fiber exhibited more hydrophobic property in the presence of MnO2 nanoparticles. Thus, it reduced the pure water flux of PSF fiber membrane. The more hydrophobic nature of the proposed nanofiber might be useful in enhancing the application of PSF fiber in oil-water separation process.

References

KureÄiÄ, M. and Smole, M. S. 2013. Electrospinning: Nanofibre Production Method. Tekstilec. 56(1).

Haider, A., Haider, S. and Kang, I. K. 2018. A Comprehensive Review Summarizing the Effect of Electrospinning Parameters and Potential Applications of Nanofibers in Biomedical and Biotechnology. Arabian Journal of Chemistry. 11(8): 1165-1188.

Fong, H., Chun, I. and Reneker, D. H. 1999. Beaded Nanofibers Formed during Electrospinning. Polymer. 40(16): 4585-4592.

Haider, S., Al-Zeghayer, Y., Ali, F. A. A., Haider, A., Mahmood, A., Al-Masry, W. A., Imran, M. and Aijaz, M. O., 2013. Highly Aligned Narrow Diameter Chitosan Electrospun Nanofibers. Journal of Polymer Research. 20(4): 105.

Sun, B., Long, Y. Z., Zhang, H. D., Li, M. M., Duvail, J. L., Jiang, X. Y. and Yin, H. L. 2014. Advances in Three-Dimensional Nanofibrous Macrostructures via Electrospinning. Progress in Polymer Science. 39(5): 862-890.

Angammana, C. J. and Jayaram, S. H. 2011. Analysis of the Effects of Solution Conductivity on Electrospinning Process and Fiber Morphology. IEEE Transactions on Industry Applications. 47(3): 1109-1117.

Post, J. E. 1999. Manganese Oxide Minerals: Crystal Structures and Economic and Environmental Significance. Proceedings of the National Academy of Sciences. 96(7): 3447-3454.

Tonkin, J. W., Balistrieri, L. S. and Murray, J. W. 2004. Modeling Sorption of Divalent Metal Cations on Hydrous Manganese Oxide Using the Diffuse Double Layer Model. Applied Geochemistry. 19(1): 29-53.

Wang, H. Q., Yang, G. F., Li, Q. Y., Zhong, X. X., Wang, F. P., Li, Z. S. and Li, Y. H. 2011. Porous Nano-MnO 2: Large Scale Synthesis via a Facile Quick-Redox Procedure and Application in a Supercapacitor. New Journal of Chemistry. 35(2): 469-475.

Tian, Y., Liu, Y., Sun, Z., Li, H., Cui, G. and Yan, S. 2015. Fibrous Porous Silica Microspheres Decorated with Mn 3 O 4 for Effective Removal of Methyl Orange from Aqueous Solution. RSC Advances. 5(128): 106068-106076.

Alemu, S., Mulugeta, E., Zewge, F. and Chandravanshi, B. S. 2014. Water Defluoridation by Aluminium Oxide–Manganese Oxide Composite Material. Environmental Technology. 35(15): 1893-1903.

Islam, M. A., Morton, D. W., Johnson, B. B., Mainali, B. and Angove, M. J. 2018. Manganese Oxides and Their Application to Metal Ion and Contaminant Removal from Wastewater. Journal of Water Process Engineering. 26: 264-280.

Song, H. J. and Kim, C. K. 2013. Fabrication and Properties of Ultrafiltration Membranes Composed of Polysulfone and Poly (1-vinylpyrrolidone) Grafted Silica Nanoparticles. Journal of Membrane Science. 444: 318-326.

Yu, L., Yang, F. and Xiang, M. 2014. Phase Separation in a Psf/DMF/Water System: A Proposed Mechanism for Macrovoid Formation. RSC Advances. 4(80): 42391-42402.

Afsaneh, M. and Dariush, V. 2018. Nanofibrous Tubular Membrane for Blood Hemodialysis. Applied Biochemistry and Biotechnology.

Gong, X., Dai, Y., Yan, X., Wu, X., Wang, Q., Zhen, D., Li, T., Chen, W. and He, G., 2018. Electrospun Imidazolium Functionalized Multiwalled Carbon Nanotube/Polysulfone Inorganic-organic Nanofibers for Reinforced Anion Exchange Membranes. International Journal of Hydrogen Energy. 43(46): 21547-21559.

Pascariu Dorneanu, P., Cojocaru, C., Samoila, P., Olaru, N., Airinei, A. and Rotaru, A. 2018. Novel fibrous Composites Based on Electrospun PSF and PVDF Ultrathin Fibers Reinforced with Inorganic Nanoparticles: Evaluation as Oil Spill Sorbents. Polymers for Advanced Technologies. 29(5): 1435-1446.

Khayet, M. and Wang, R. 2018. Mixed Matrix Polytetrafluoroethylene/Polysulfone Electrospun Nanofibrous Membranes for Water Desalination by Membrane Distillation. ACS Applied Materials & Interfaces.

Díez, B., Amariei, G. and Rosal, R. 2018. Electrospun Composite Membranes for Fouling and Biofouling Control. Industrial & Engineering Chemistry Research. 57(43): 14561-14570.

Liu, Y. L., Lin, G. C. and Wu, C. S. 2008. Preparation of Polysulfoneâ€gâ€poly (Nâ€isopropylacrylamide) Graft Copolymerst Atom Transfer Radical Polymerization and Formation of Temperatureâ€responsive Nanoparticles. Journal of Polymer Science Part A: Polymer Chemistry. 46(14): 4756-4765.

Zhao, C., Xue, J., Ran, F. and Sun, S. 2013. Modification of Polyethersulfone Membranes–A Review of Methods. Progress in Materials Science. 58(1): 76-150.

Subramanian, V., Zhu, H. and Wei, B. 2008. Alcohol-Assisted Room Temperature Synthesis of Different Nanostructured Manganese Oxides and Their Pseudocapacitance Properties in Neutral Electrolyte. Chemical Physics Letters. 453(4-6): 242-249.

Zahari, A. M., Yusoff, A. R. M., Aziah, N., Buang, P. S., Jasni, M. J. F. and Yusop, Z. 2015. Fabrication and Characterization of Polyvinylidene Fluoride Composite Nanofiber Membrane for Water Flux Property. Jurnal Teknologi. 74(11): 9-14.

Reneker, D. H. and Yarin, A. L. 2008. Electrospinning Jets and Polymer Nanofibers. Polymer. 49(10): 2387-2425.

Choi, J. S., Lee, S. W., Jeong, L., Bae, S. H., Min, B. C., Youk, J. H. and Park, W. H. 2004. Effect of Organosoluble Salts on the Nanofibrous Structure of Electrospun Poly (3-hydroxybutyrate-co-3-hydroxyvalerate). International Journal of Biological Macromolecules. 34(4): 249-256.

Zong, X., Kim, K., Fang, D., Ran, S., Hsiao, B. S. and Chu, B., 2002. Structure and Process Relationship of Electrospun Bioabsorbable Nanofiber Membranes. Polymer. 43(16): 4403-4412.

Uzal, N., Ates, N., Saki, S., Bulbul, Y.E. and Chen, Y. 2017. Enhanced Hydrophilicity and Mechanical Robustness of Polysulfone Nanofiber Membranes by Addition of Polyethyleneimine and Al2O3 Nanoparticles. Separation and Purification Technology. 187: 118-126.

Al-Husaini, I. S., Yusoff, A. R. M., Lau, W. J., Ismail, A. F., Al-Abri, M. Z., Al-Ghafri, B. N. and Wirzal, M. D. H. 2019. Fabrication of Polyethersulfone Electrospun Nanofibrous Membranes Incorporated with Hydrous Manganese Dioxide for Enhanced Ultrafiltration of Oily Solution. Separation and Purification Technology. 212: 205-214.

Downloads

Published

2019-06-25

Issue

Section

Science and Engineering

How to Cite

SOLUTION PARAMETER EFFECT ON POLYSULFONE FIBERS VIA ELECTROSPINNING: FABRICATION, CHARACTERIZATION AND WATER FLUX PROPERTY. (2019). Jurnal Teknologi (Sciences & Engineering), 81(4). https://doi.org/10.11113/jt.v81.13439