Sulfate and Sulfuric Acid Resistance of Geopolymer Mortars Using Waste Blended Ash

Authors

  • M. Aamer Rafique Bhutta Construction Research Centre (UTM CRC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Nur Farhayu Ariffin Dept. of Structures & Materials, Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mohd Warid Hussin Construction Research Centre (UTM CRC), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Nor Hasanah Abdul Shukor Lim Dept. of Structures & Materials, Faculty of Civil Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v61.1762

Keywords:

Sulfate resistance, sulfuric acid resistance, geopolymer mortar, mass change, residual compressive strength

Abstract

This paper presents the chemical resistance of geopolymer mortars prepared from the combination of palm oil fuel ash (POFA) and pulverized fuel ash (PFA) from agro–industrial waste as cement replacement and activated by alkaline solution. Alkaline solution was prepared by combining sodium silicate and sodium hydroxide. The concentration of alkaline solution used was 14 Molar. The optimum mix proportions of geopolymer mortars with PFA: POFA mass ratio of 70:30 was used together with alkaline solution. The ratio of sodium silicate solution–to–sodium hydroxide solution by mass was 2.5:1. The mass ratio of sand to blended ashes was 3:1. Test specimens 70×70×70 mm cube were prepared and cured at room temperature (28°C) for 28–d and heat–cured at 90°C for 24 h, respectively. Then specimens were exposed to 5% sodium sulfate solution and 2% sulfuric acid solution for 28–d, 56–d, 90–d, 180–d and 365–d .The evaluation was done by visual observation, mass change, and loss of compressive strength. The test results revealed that geopolymer mortars showed higher resistance to acids as compared to ordinary Portland cement mortar due to the elimination of cement in the mixture.

References

Bhutta, M. A. R., Hussin, M. W., Azreen, M. A., Nor Hasanah and Nur Farhayual. 2011. Mix Design and Compressive Strength of FA-POFA-Based Geopolymer Mortar. Proceedings of 9th International Symposium on High Performance Concrete, Rotorua, New Zealand. 14. [2] Bakharev, T. 2005. Durability of Geopolymer Materials in Sodium and Magnesium Sulfate Solutions. Cement and Concrete Research. 35: 1233–46. [3] Bakharev, T. 2005. Resistance of Geopolymer Materials to Acid Attack. Cement and Concrete Research. 35: 658–70. [4] Davidovits, J. 1991. Geopolymer: Inorganic Polymeric New Materials. Them Anal. 37:1633–56. [5] Davidovits, J., Comrie, D. C., Paterson, J. H., and Ritcey, D. J. 1990. Geopolmeric Concretes for Environmental Protection. ACI Concrete International. 12: 30–40. [6] Davidovits, J. 1994. Geopolymer Man-Made Rock Geosynthesis and The Resulting Development of Very Early High Strength Cement. J. Mater. Educ. 16: 91. [7] Davidovits, J. 1994. Properties Of Geopolymer Cements. Proceedings of the First International Conference on Alkaline Cements and Concretes. vol.1, SRIBM, Kiev, Ukrain. 131–149. [8] Thokchom, S., Dr. Partha Ghosh, P. and Ghosh, S. 2009. Acid Resistance of Fly Ash Based Geopolymer Mortars. International Journal of Recent Trends in Engineering. 1(6): 39. [9] Rangan, B. V. 2008. Studies on Fly Ash Based Geopolymer Concrete. Malaysia Construction Research Journal. 3: 124. [10] Hardjito, D. and Rangan, B. V. 2005. Development and Properties of Low Calcium Fly Ash-based Geopolymer Concrete. Research Report GC1. Curtin University of Technology, Perth, Australia. [11] Rangan, B. V. 2008. Low-Calcium Fly Ash-Based Geopolymer Concrete. Chapter 26 in Concrete Construction Engineering Handbook. Second Edition. New York: CRC Press, [12] Rangan, B. V. 2009. Engineering Properties of Geopolymer Concrete. Chapter 13 in Geopolymer: Structures, Processing, Properties, and Applications. Editors: J.Provis and J. van Deventer. London: Woodhead Publishing Limited,

Downloads

Published

2013-03-15

Issue

Section

Science and Engineering

How to Cite

Sulfate and Sulfuric Acid Resistance of Geopolymer Mortars Using Waste Blended Ash. (2013). Jurnal Teknologi (Sciences & Engineering), 61(3). https://doi.org/10.11113/jt.v61.1762