Membrane Performance: TiO2 Nanoparticles Coated on Polysulfone (PSf) Ultrafiltration Membrane Surfaces

Authors

  • Siti Hawa Mohamad Advanced Materials and Manufacturing Centre (AMMC), Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia
  • Hasan Zuhudi Abdullah Faculty of Mechanical and Manufacturing Engineering, Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia
  • Maizlinda Izwana Idris Faculty of Mechanical and Manufacturing Engineering, Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia
  • Zawati Harun Advanced Materials and Manufacturing Centre (AMMC), Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v65.2330

Keywords:

Polysulfone, TiO2 nanoaprticles, UV irradiation

Abstract

This study focuses on the modification polysulfone (PSf) ultrafiltration membrane surfaces via coated and irradiated with titanium dioxide (TiO2) nanoparticles with UV lights respectively. Basically, the flat sheet membrane was prepared using phase inversion technique with three conditions: (i) uncoated PSf membrane, (ii) coated PSf membrane with TiO2 and (iii) PSf membrane coated with TiO2 irradiated to UV. The coating process was carried out using dipping method into TiO2 nanoparticles suspension at different concentrations (0.01, 0.03 and 0.05 wt.%). Membrane was immersed in all suspension for 15 and 30 minutes. Then, coated membranes were exposured under 184 Watts UV lamp at two different durations, 15 and 30 minutes. The performance of membranes was evaluated in terms of pure water flux (PWF) and humic acid (HA) rejection. The morphology of membranes was characterized using scanning electron microscopy (SEM). Analysis of the result revealed that 15 minutes immersion of membrane in TiO2 suspension showed a better performance in term permeation and rejection of compared to 30 min immersion. This is due to the pore plugging as time of immersion increased. Therefore, the coated membranes with 0.03 wt.% of TiO2 nanoparticles at 15 minutes immersion and 15 minutes exposure of UV light irradiation were determined as an ideal performance of rejection and permeation compared to the other.

References

P. Ramesh and V. G. Gaikar. 2001. Separation Purification Technology. 24: 23–34.

A. L. Linsebigler, G. Lu, J. T. Yates. 1995. Chem. Rev. 95(3): 735–758.

S. H. Mohamad, M. I. Idris, H. Z. Abdullah, A. F. Ismail. 2013. Advanced Materials Research. 795: 318–323.

H. Yamashita, H. Nakao, M. Takeuchi, Y. Nakatani, M. Anpo. 2003. Nucl. Instrum. Methods Phys. Res. B. 206: 898–901.

T. H. Bae, T. M. Tak. 2005. Journal Membrane Science. 249: 1.

A. Rahimpour, S. S. Madaeni, A. H. Taheri, Y. Mansourpanah. 2008. Journal Membrane Science. 313: 158.

S. H. Kim, S. Y. Kwak, B. H. Sohn, T. H. Park. 2003. Journal Membrane Science. 211: 157–165.

M. F. Shohur, Z. Harun, Z. Yunos, S. Hasan, and R. Jamalludin. 2013. Applied Mechanic Materials. 372: 3–7.

M. R. Jamalludin, Z. Harun, H. Basri, M. Z. Yunos, and M. F. Shohur. 2013. Applied Mechanic Materials. 372: 8–12.

Z. Harun, M. F. Shohur, M. Z. Yunos, M. R. Jamalludin, and A. F. Ismail. 2013. Advanced Materials Research. 328: 798–801.

V. Vatanpour, S. S Madaeni , A, R. Khataee, E. Salehi, S, Zinadini, H. A. Monfared. 2012. Desalination. 292: 19–29.

Z. Harun, M. R. Jamalludin, M. Z. Yunos, M. F. Shohur, and A. F. Ismail. 2013. Advanced Materials Research. 701: 319–322.

J. K. Yang, and S. M. Lee. 2006. Chemosphere. 63: 1677–1684.

D. He, X. Guan, J. Ma, X. Yang, C. Cui. 2010. Journal Hazard. Mater. 182: 681–688.

S. S. Madaeni, N. Ghaemi, A. Alizadeh, M. Joshaghani. 2011. Appl. Surf. Sci. 257: 6175–6180.

S. S. Madaeni and N. Ghaemi. 2007. Journal Membrane Science. 303: 221–233.

A. Akbari, S. Desclaux, J. C. Rouch, P. Aptel, J. C. Remigy. 2006. Journal Membrane Science. 286: 342–350.

M. Ulbricht. 2006. Polymer. 47: 2217–2266.

Y. Mansourpanah, S. S. Madaeni, A. Rahimpour, A. Farhadian, A. H. Taheri. 2009. Journal Membrane Science 330: 297–306.

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Published

2013-11-15

How to Cite

Membrane Performance: TiO2 Nanoparticles Coated on Polysulfone (PSf) Ultrafiltration Membrane Surfaces. (2013). Jurnal Teknologi (Sciences & Engineering), 65(4). https://doi.org/10.11113/jt.v65.2330