ENHANCING MECHANICAL PERFORMANCE OF EPOXY-BASED HYBRID COMPOSITES USING ALKALI-TREATED PINEAPPLE LEAF FIBER AND MWCNT

Authors

  • Budi Noviyantoro Fadjrin Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Lambert Hotma Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Nur Cholis Majid Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Hana Hermawan Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Marsalyna Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Supriana Suwanda Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Khamda Herbandono Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Katri Yulianto Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Dwi Jaya Febriansyah Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Intan Satwika Putri Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Muizuddin Azka Research Center for Process and Manufacturing Industry Technology, National Research and Innovation Agency of the Republic of Indonesia (BRIN), South Tangerang, Indonesia, 15314
  • Wahyu Erlangga Gadjah Mada University, Departerment of mechanical and industrial engineering, Sleman, Special Region of Yogyakarta, 55284

DOI:

https://doi.org/10.11113/jurnalteknologi.v88.25032

Keywords:

Hybrid Composite, Natural Fiber, MWCNT, alkali treatment, mechanical properties

Abstract

The increasing interest in environmentally friendly materials in industries such as automotive, civil construction, and packaging has encouraged a lot of research related to environmentally friendly composites using natural fibers as reinforcement. This study is conducted to evaluate the performance of epoxy resin as a matrix with pineapple leaf fiber and multi wall carbon nanotube powder (MWCNT) as the reinforcements in hybrid composites. Pineapple leaf fiber is alkali treated by soaking the fiber in 5%wt alkali solution. The fibers are woven into unidirectional fiber sheets. A proper manufacturing process obtains quality unidirectional composites, which is carried out by configuring volume fraction ratio and matrix 30% and 70%, respectively. Hybrid composites, which consist of five fiber sheets with a configuration of pineapple leaf fibers, mixed with epoxy resin matrix and supplemented with MWCNT of 0.1, 0.3; 0.5 and 1 wt%, are composed by vacuum infusion method. The results show that alkali treatment improves the mechanical properties of epoxy/pineapple leaf fiber hybrid composites. The most optimal MWCNT content is obtained at 0.5%wt, resulted in a rise of tensile strength by 26.70%, bending strength by 17.82%, and impact toughness by 5.90%. Fiber alkali treatment and MWCNT addition to the hybrid composite increase water absorption. The existence of a good interface bond between pineapple leaf fibers and the matrix is indicated by the visible epoxy matrix and MWCNT particles which stick to the pineapple leaf fibers surface, proved by the FE-SEM observations.

References

Brucely, Y., M. R. Sahoo, S. Halder, M. Thiyagu, A. S. Kumar, and L. Parida. 2022. Investigating Mechanical Strength of Luffa and Pineapple Fibre Reinforced Polymer Composite. Materials Today: Proceedings. 69: 1300–1303. https://doi.org/10.1016/j.matpr.2022.08.407.

Thakur, V. K., M. K. Thakur, and R. K. Gupta. 2013. Synthesis of Lignocellulosic Polymer with Improved Chemical Resistance through Free Radical Polymerization. International Journal of Biological Macromolecules. 61: 121–126. https://doi.org/10.1016/j.ijbiomac.2013.06.045.

Mohanty, A. K., A. Wibowo, M. Misra, and L. T. Drzal. 2004. Effect of Process Engineering on the Performance of Natural Fiber Reinforced Cellulose Acetate Biocomposites. Composites Part A: Applied Science and Manufacturing. 35: 363–370. https://doi.org/10.1016/j.compositesa.2003.09.015.

Bernardes, G. P., M. D. P. Andrade, and M. Poletto. 2023. Effect of Alkaline Treatment on the Thermal Stability, Degradation Kinetics, and Thermodynamic Parameters of Pineapple Crown Fibres. Journal of Materials Research and Technology. 23: 64–76. https://doi.org/10.1016/j.jmrt.2022.12.179.

Ridzuan, M., M. A. Majid, M. Afendi, S. A. Kanafiah, J. Zahri, and A. Gibson. 2016. Characterization of Natural Cellulosic Fibers from Pennisetum purpureum Stem as Potential Reinforcement of Polymer Composites. Materials & Design 89: 839–847. https://doi.org/10.1016/j.matdes.2015.10.052.

Bajuri, F., N. Mazlan, M. R. Ishak, and J. Imatomi. 2016. Flexural and Compressive Properties of Hybrid Kenaf/Silica. Procedia Chemistry. 19: 955–960. https://doi.org/10.1016/j.proche.2016.03.133.

Ramesh, M., C. Deepa, G. R. Arpitha, and V. Gopinath. 2019. Effect of Hybridization on Properties of Hemp-Carbon Fibre-Reinforced Hybrid Polymer Composites Using Experimental and Finite Element Analysis. World Journal of Engineering. 16(2): 248–259. https://doi.org/10.1108/WJE-04-2018-0125.

Bollino, F., V. Giannella, E. Armentani, and R. Sepe. 2023. Mechanical Behavior of Chemically-Treated Hemp Fibers Reinforced Composites Subjected to Moisture Absorption. Journal of Materials Research and Technology. 22: 762–775.

Faruk, O., A. K. Bledzki, H.-P. Fink, and M. Sain. 2012. Biocomposites Reinforced with Natural Fibers: 2000–2010. Progress in Polymer Science. 37: 1552–1596. https://doi.org/10.1016/j.progpolymsci.2012.04.003.

Bledzki, A. K., and J. Gassan. 1999. Composites Reinforced with Cellulose Based Fibers. Progress in Polymer Science. 24: 221–274. https://doi.org/10.1016/S0079-6700(98)00018-5.

Mwaikambo, L. Y., N. Tucker, and A. J. Clark. 2007. Mechanical Properties of Hemp-Fibre-Reinforced Euphorbia Composites. Macromolecular Materials and Engineering. 292(9): 993–1000.

Liu, W., S. V. Hoa, and M. Pugh. 2005. Fracture Toughness and Water Uptake of High-Performance Epoxy/Nanoclay Nanocomposites. Composites Science and Technology. 65(15–16): 2364–2373. https://doi.org/10.1016/j.compscitech.2005.06.007.

Cha, J., S. Jin, J. H. Shim, C. S. Park, H. J. Ryu, and S. H. Hong. 2016. Functionalization of Carbon Nanotubes for Fabrication of CNT/Epoxy Nanocomposites. Materials & Design. 95: 1–8. https://doi.org/10.1016/j.matdes.2016.01.077.

Uthaman, A., H. M. Lal, C. Li, G. Xian, and S. Thomas. 2021. Mechanical and Water Uptake Properties of Epoxy Nanocomposites with Surfactant-Modified Functionalized Multiwalled Carbon Nanotubes. Nanomaterials. 11(5): 1234. https://doi.org/10.3390/nano11051234.

Joseph, P. V., K. Joseph, S. Thomas, C. K. S. Pillai, V. S. Prasad, G. Groeninckx, and M. Sarkissova. 2003. The Thermal and Crystallization Studies of Short Sisal Fiber Reinforced Polypropylene Composites. Composites Part A: Applied Science and Manufacturing. 34(3): 253–266. https://doi.org/10.1016/S1359-835X(02)00185-9.

Shen, X., J. Jia, C. C. Y. Li, and J.-K. Kim. 2014. Enhancement of Mechanical Properties of Natural Fiber Composites via Carbon Nanotube Addition. Journal of Materials Science. 49: 3225–3233. https://doi.org/10.1007/s10853-014-8027-4.

Kushwaha, P. K., C. N. Pandey, and R. Kumar. 2014. Study on the Effect of Carbon Nanotubes on Plastic Composite Reinforced with Natural Fiber. Journal of the Indian Academy of Wood Science. 11: 82–86. https://doi.org/10.1007/s13196-014-0121-3.

Saba, N., F. Mohammad, M. Pervaiz, M. Jawaid, O. Y. Alothman, and M. Sain. 2017. Mechanical, Morphological and Structural Properties of Cellulose Nanofibers Reinforced Epoxy Composites. International Journal of Biological Macromolecules. 97: 190–200. https://doi.org/10.1016/j.ijbiomac.2017.01.029.

Muthusamy, M., K. Arumugam, and A. V. Ponnusamy. 2022. Evaluation of Wear Properties and Water Absorption Behavior of Banana and Sisal Fiber Reinforced Epoxy Hybrid Composites: Influence of Fiber Length. Journal of Natural Fibers. 19(15): 10447–10461. https://doi.org/10.1080/15440478.2021.1994088.

Khalil, H. P. S. A., M. Jawaid, and A. A. Bakar. 2011. Woven Hybrid Composites: Water Absorption and Thickness Swelling Behaviors. BioResources. 6(2): 1042–1052.

Yang, J., K. Zhang, D. Chen, Y. Zhang, X. Zhang, and Z. Yang. 2024. Effect of Alkali Treatment on Water Absorption Deterioration and Mechanism of Wheat Straw/PVC Composites. Polymer Testing. 131: 108348. https://doi.org/10.1016/j.polymertesting.2024.108348.

Khalil, H. P. S. A., M. Jawaid, and A. A. Bakar. 2011. Woven Hybrid Composites: Water Absorption and Thickness Swelling Behaviors. BioResources. 6(2): 1042–1052.

Bera, T., N. Mohanta, V. Prakash, S. Pradhan, and S. K. Acharya. 2019. Moisture Absorption and Thickness Swelling Behaviour of Luffa Fibre/Epoxy Composite. Journal of Reinforced Plastics and Composites. 38(19–20). https://doi.org/10.1177/0731684419856703.

Azhary, T., Kusmono, M. W. Wildan, and H. Herianto. 2022. Mechanical, Morphological, and Thermal Characteristics of Epoxy/Glass Fiber/Cellulose Nanofiber Hybrid Composites. Polymer Testing. 110: 107560. https://doi.org/10.1016/j.polymertesting.2022.107560.

Chee, S. S., M. Jawaid, M. T. H. Sultan, O. Y. Alothman, and L. C. Abdullah. 2020. Effects of Nanoclay on Physical and Dimensional Stability of Bamboo/Kenaf/Nanoclay Reinforced Epoxy Hybrid Nanocomposites. Journal of Materials Research and Technology. 9(3): 5871–5880. https://doi.org/10.1016/j.jmrt.2020.03.099.

Muthusamy, M., K. Arumugam, and A. V. Ponnusamy. 2022. Evaluation of Wear Properties and Water Absorption Behavior of Banana and Sisal Fiber Reinforced Epoxy Hybrid Composites: Influence of Fiber Length. Journal of Natural Fibers. 19(15): 10447–10461. https://doi.org/10.1080/15440478.2021.1994088.

Ariawan, D., T. S. Rivai, E. Surojo, S. Hidayatulloh, H. I. Akbar, and A. R. Prabowo. 2020. Effect of Alkali Treatment of Salacca zalacca Fiber (SZF) on Mechanical Properties of HDPE Composite Reinforced with SZF. Alexandria Engineering Journal. 59(6): 3981–3989.

Ghahramani, P., K. Behdinan, R. Moradi-Dastjerdi, and H. E. Naguib. 2022. Theoretical and Experimental Investigation of MWCNT Dispersion Effect on the Elastic Modulus of Flexible PDMS/MWCNT Nanocomposites. Nanotechnology Reviews. 11(1): 55–64. https://doi.org/10.1515/ntrev-2022-0006.

Gomes, A., K. Goda, and J. Ohgi. 2004. Effects of Alkali Treatment to Reinforcement on Tensile Properties of Curaua Fiber Green Composites. JSME International Journal Series A: Solid Mechanics and Materials Engineering. 47(4): 541–546. https://doi.org/10.1299/jsmea.47.541.

Vinod, A., R. Vijay, D. L. Singaravelu, A. Khan, M. Sanjay, S. Siengchin, F. Verpoort, K. A. Alamry, and A. M. Asiri. 2022. Effect of Alkali Treatment on Performance Characterization of Ziziphus mauritiana Fiber and Its Epoxy Composites. Journal of Industrial Textiles. 51: 2444S–2466S. https://doi.org/10.1177/1528083720942614.

Kamaraj, M., E. A. Dodson, and S. Datta. 2019. Effect of Graphene on the Properties of Flax Fabric Reinforced Epoxy Composites. Advanced Composite Materials. 29(5): 443–458. https://doi.org/10.1080/09243046.2019.1709679.

Khan, A., A. M. Asiri, M. Jawaid, N. Saba, and Inamuddin. 2020. Effect of Cellulose Nanofibers and Nanoclays on Mechanical, Morphological, Thermal and Dynamic Mechanical Performance of Kenaf/Epoxy Composites. Carbohydrate Polymers. 248: 116248. https://doi.org/10.1016/j.carbpol.2020.116248.

Panchagnula, K. K., and P. Kuppan. 2019. Improvement in the Mechanical Properties of Neat GFRPs with Multi-Walled CNT. Journal of Materials Research and Technology. 8(1): 366–376. https://doi.org/10.1016/j.jmrt.2018.03.013.

Gojny, F. H., M. H. G. Wichmann, U. Kopke, B. Fiedler, and K. Schulte. 2004. Carbon Nanotube-Reinforced Epoxy-Composites: Enhanced Stiffness and Fracture Toughness at Low Nanotube Content. Composites Science and Technology. 64: 2363–2371. https://doi.org/10.1016/j.compscitech.2004.04.002.

Saba, N., F. Mohammad, M. Pervaiz, M. Jawaid, O. Alothman, and M. Sain. 2017. Mechanical, Morphological and Structural Properties of Cellulose Nanofibers Reinforced Epoxy Composites. International Journal of Biological Macromolecules. 97: 190–200. https://doi.org/10.1016/j.ijbiomac.2016.12.025.

Peng, S. X., S. Shrestha, Y. Yoo, and J. P. Youngblood. 2017. Enhanced Dispersion and Properties of a Two-Component Epoxy Nanocomposite Using Surface Modified Cellulose Nanocrystals. Polymer. 109: 359–368. https://doi.org/10.1016/j.polymer.2016.12.082.

Xu, S., N. Girouard, G. Schueneman, M. L. Shofner, and J. C. Meredith. 2013. Mechanical and Thermal Properties of Waterborne Epoxy Composites Containing Cellulose Nanocrystals. Polymer. 54(26): 6589–6598. https://doi.org/10.1016/j.polymer.2013.10.035.

Kumar, S., B. G. Falzon, J. Kun, E. Wilson, G. Graninger, and S. C. Hawkins. 2020. "High Performance Multiscale Glass Fibre Epoxy Composites Integrated with Cellulose Nanocrystals for Advanced Structural Applications. Composites Part A: Applied Science and Manufacturing. 131: 105780.

Nayak, B. A., Shubham, R. K. Prusty, and B. C. Ray. 2020. Effect of Nanosilica and Nanoclay Reinforcement on Flexural and Thermal Properties Glass Fiber/Epoxy Composites. Materials Today: Proceedings. 33: 5098–5102. https://doi.org/10.1016/j.matpr.2020.02.852.

Mahato, K. K., K. Dutta, and B. C. Ray. 2019. Assessment of Mechanical, Thermal and Morphological Behavior of Nano-Al₂O₃ Embedded Glass Fiber/Epoxy Composites at In-Situ Elevated Temperature. Composites Part B: Engineering. 173: 688–700. https://doi.org/10.1016/j.compositesb.2019.06.039.

Asadi, A., M. Miller, R. J. Moon, and K. Kalaitzidou. 2016. Improving the Interfacial and Mechanical Properties of Short Glass Fiber/Epoxy Composites by Coating the Glass Fibers with Cellulose Nanocrystals. eXPRESS Polymer Letters. 10(7): 587–597. https://doi.org/10.3144/expresspolymlett.2016.55.

Siakeng, R., M. Jawaid, M. Asim, N. Saba, M. R. Sanjay, S. Siengchin, and H. Fouad. 2020. Alkali Treated Coir/Pineapple Leaf Fibers Reinforced PLA Hybrid Composites: Evaluation of Mechanical, Morphological, Thermal and Physical Properties. eXPRESS Polymer Letters. 14(8): 717–730. https://doi.org/10.3144/expresspolymlett.2020.59.

Yang, Y., J. Wu, Y. Ma, and L. Zhang. 2018. Cellulose Nanofiber/Carbon Nanotube Conductive Nano-Network as a Reinforcement Template for Polydimethylsiloxane Nanocomposite. Polymers. 10(9): 1000. https://doi.org/10.3390/polym10091000.

Rashid, M., and S. Bhowmik. 2012. Scanning Electron Microscopy Study of Fiber Reinforced Polymeric Nanocomposites. In Scanning Electron Microscopy, edited by K. Y. Zhi, 335–350. Rijeka: IntechOpen. https://doi.org/10.5772/38834.

Yetgin, S. H. 2019. Effect of Multi-Walled Carbon Nanotube on Mechanical, Thermal and Rheological Properties of Polypropylene. Journal of Materials Research and Technology. 8(5): 4725–4735. https://doi.org/10.1016/j.jmrt.2019.08.018.

Nitodas, S. F., R. Shah, and M. Das. 2025. Research Advancements in the Mechanical Performance and Functional Properties of Nanocomposites Reinforced with Surface-Modified Carbon Nanotubes: A Review. Applied Sciences. 15(1): 374. https://doi.org/10.3390/app15010374.

Amin, M. N., A. E. Ismail, F. Mustapha, and E. G. Ng. 2024. Enhancing Mechanical Performance of MWCNT Filler with Jute/Kenaf/Glass Composite: A Statistical Optimization Study Using RSM and ANN. Journal of Thermoplastic Composite Materials. https://doi.org/10.1080/10667857.2024.2381156.

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Published

2026-06-16

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Science and Engineering