EVALUATING THE ROLE OF CONDUCTIVE EPOXY COMPOSITE LAYER IN MULTI-LAYER CERAMIC CAPACITORS UNDER ENVIRONMENTAL AND THERMAL STRESSES
DOI:
https://doi.org/10.11113/jurnalteknologi.v88.25216Keywords:
Cu-Epoxy Layer, Delamination, Thermal Cycling, Humidity Preconditioning, Surface Mount Assembly (SMA)Abstract
Multi-Layer Ceramic Capacitors (MLCCs) are vital components in modern electronics, where reliability under harsh environmental and thermal conditions is essential. This study evaluates the role of conductive epoxy composite (Cu-Epoxy) layer in the MLCC during simulated reflow thermal cycling. Structural analysis revealed that the Cu-epoxy layer mitigates mechanical and thermal stresses in standard conditions, maintaining an intact interface. However, prolonged humidity exposure and thermal cycling led to delamination at the Cu-epoxy/Cu interface, compromising mechanical integrity and electrical performance. Elemental mapping confirmed alumina infiltration in delaminated area, providing evidence of structural degradation. These findings underscore the importance of optimizing reflow profiles and Cu-epoxy formulations to improve adhesion strength, moisture resistance, and thermal stability. This study offers actionable recommendations for enhancing MLCC reliability in surface mount assembly processes and demanding operating environments.
References
[1] Li, D., P. Peng, C. Xu, Y. Zhang, and C. Di. 2009. Study on the Mechanical-Electric Effect Law of Dynamic Output Voltage of Board Level Mounted BaTiO3-MLCC under High Impact. Measurement. 190: 110639. https://doi.org/10.1016/j.measurement.2021.110639.
[2] Li, N. M., S. Manoharan, D. Das, and P. McCluskey. 2018. Analysis of Indentation Measured Mechanical Properties on Multilayer Ceramic Capacitors (MLCCs). Microelectronics Reliability. 88–90: 528–533. https://doi.org/10.1016/j.microrel.2018.07.116.
[3] Keimasi, M., M. H. Azarian, and M. Pecht. 2007. Isothermal Aging Effects on Flex Cracking of Multilayer Ceramic Capacitors with Standard and Flexible Terminations. Microelectronics Reliability. 47(12): 2215–2225. https://doi.org/10.1016/j.microrel.2006.12.005.
[4] Bachok, Z., et al. 2023. Investigation of Moisture-Induced Crack Propagation in the Soft-Termination Multi-Layer Ceramic Capacitor during Thermal Reflow Process. Soldering & Surface Mount Technology. 35(5): 305–318. https://doi.org/10.1108/SSMT-01-2023-0001.
[5] Cao, R., Y. Wu, D. Zhou, X. Hou, L. Duan, and H. Zhu. 2023. Failure Analysis and Improvement Research on Flexible Termination Multilayer Ceramic Capacitors. In 2023 24th International Conference on Electronic Packaging Technology (ICEPT). 1–5. https://doi.org/10.1109/ICEPT59018.2023.10492249.
[6] Chen, F., et al. 2024. Three-Point Bending Test and Finite Element Analysis of Flexible Termination Multilayer Ceramic Capacitors. In 2024 25th International Conference on Electronic Packaging Technology (ICEPT). 1–4. https://doi.org/10.1109/ICEPT63120.2024.10668729.
[7] Lee, C. H., and J. R. Yoon. 2022. The Effect of Ag-Epoxy Electrodes on the Thermal and Mechanical Properties of Multilayer Ceramic Capacitor. Journal of Ceramic Processing Research. 23(2): 181–187. https://doi.org/10.36410/jcpr.2022.23.2.181.
[8] Vargas, O. L., S. B. Valdez, M. L. Veleva, K. R. Zlatev, W. M. Schorr, and G. J. Terrazas. 2009. The Corrosion of Silver in Indoor Conditions of an Assembly Process in the Microelectronics Industry. Anti-Corrosion Methods and Materials. 56(4): 218–225. https://doi.org/10.1108/00035590910969347.
[9] Lin, J. C., and J. Y. Chan. 1996. On the Resistance of Silver Migration in Ag-Pd Conductive Thick Films under Humid Environment and Applied D.C. Field. Materials Chemistry and Physics. 43(3): 256–265. https://doi.org/10.1016/0254-0584(95)01642-8.
[10] Donnelly, N. J., and C. A. Randall. 2009. Refined Model of Electromigration of Ag/Pd Electrodes in Multilayer PZT Ceramics under Extreme Humidity. Journal of the American Ceramic Society. 92(2): 405–410. https://doi.org/10.1111/j.1551-2916.2008.02891.x.
[11] Stewart, M. 2005. A Soft Termination MLCC Solution to Guard against Capacitor Crack Failures. In Proceedings of the 25th Symposium for Passive Components (CARTS). Palm Springs, CA, USA. 21–24.
[12] Apalowo, R. K., et al. 2023. Investigation of Hygrothermally Induced Failures in Multilayer Ceramic Capacitors during Thermal Reflow Process. Microelectronics Reliability. 146: 115028. https://doi.org/10.1016/j.microrel.2023.115028.
[13] Tsai, T. N. 2012. Thermal Parameters Optimization of a Reflow Soldering Profile in Printed Circuit Board Assembly: A Comparative Study. Applied Soft Computing. 12(8): 2601–2613. https://doi.org/10.1016/j.asoc.2012.03.066.
[14] Prymak, J. D., et al. 2009. Flexible Termination – Reliability in Stringent Environments. Accessed from https://api.semanticscholar.org/CorpusID:110870251.
[15] Ardebili, H., E. H. Wong, and M. Pecht. 2003. Hygroscopic Swelling and Sorption Characteristics of Epoxy Molding Compounds Used in Electronic Packaging. IEEE Transactions on Components and Packaging Technologies. 26(1): 206–214. https://doi.org/10.1109/TCAPT.2002.806172.
[16] Hölck, O., and B. Wunderle. 2015. Microelectronics Packaging Materials: Investigating the Influence of Moisture by Molecular Dynamics Simulations. In Molecular Modeling and Multiscaling Issues for Electronic Material Applications: Volume 2, edited by A. Wymyslowski, N. Iwamoto, M. Yuen, and H. Fan, 41–66. Cham: Springer International Publishing. https://doi.org/10.1007/978-3-319-12862-7_4.
[17] Apalowo, R. K., et al. 2024. Deformation and Crack Growth in Multilayered Ceramic Capacitor during Thermal Reflow Process: Numerical and Experimental Investigation. Microelectronics International. 41(3): 162–171. https://doi.org/10.1108/MI-03-2023-0025.
[18] Xian, G., et al. 2024. Water Absorption and Property Evolution of Epoxy Resin under Hygrothermal Environment. Journal of Materials Research and Technology. 31: 3982–3997. https://doi.org/10.1016/J.JMRT.2024.07.123.
[19] Fan, X., G. Q. Zhang, W. D. van Driel, and L. J. Ernst. 2008. Interfacial Delamination Mechanisms during Soldering Reflow with Moisture Preconditioning. IEEE Transactions on Components and Packaging Technologies. 31(2): 252–259. https://doi.org/10.1109/TCAPT.2008.921629.
[20] Akçay, S. B., M. Kocaman, M. Çelebi, O. Güler, and T. Varol. 2024. Surface Modification for Improving Interfacial, Mechanical and Thermal Performance Characteristics in Epoxy Composites: Electroless Nickel Enhancement of Dendritic Copper Particle-Reinforced Epoxy. Surface and Coatings Technology. 478: 130417. https://doi.org/10.1016/j.surfcoat.2024.130417.
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