Effect of Corrossion on the Electrical Conductivity of Metals and Polymer Composite
DOI:
https://doi.org/10.11113/jt.v59.2566Keywords:
PEMFC, bipolar plate, corrosion, potentiostatic test, metal plate, composite plateAbstract
Applications of a metallic bipolar plate in a proton exchange membrane fuel cell (PEMFC) are currently being developed in the market. The main challenge for metal usage is the effect of corrosion on the overall performance of a PEMFC. The materials used in this study are stainless steel 316L (SS316L), aluminum 6061, titanium, compressed graphite, and graphite/CNTs/epoxy nanocomposite. The materials and its measurements were studied using digital multimeter to obtain the conductivity of the material, potentiostatic test to determine the corrosion rate, pH meter to determine the pH level of the sulfuric acid, and microscope to study the topography surface of the corrosion material before and after the corrosion test. Results show that aluminum corrosion is the fastest and the most severe, followed by SS316L, titanium, compressed graphite, and graphite/CNTs/epoxy nanocomposite. Corrosion decreases the electrical conductivity of the material and the pH level of sulfuric acid, consequently making the material dull and coarse. Metal plates face more severe corrosion problems compared with compressed graphite and graphite/CNTs/epoxy nanocomposite. Despite the corrosion problems it creates, metal use is low cost, easy to fabricate, light, and has good heat and electric conductivity. Hence, the development of the metallic bipolar plate shows high potential, and its modification is encouraged.References
Amphlett, J. C., Mann, R. F., Peppy, B. A., Roberge, P. R., Rodrigues, A. & Salvador, J. P. 1998. Simulation of a 250 kW Diesel Fuel Processor / PEM Fuel Cell System. Journal of Power Sources. 71: 179–184.
Kumar, A., Ramana, G. R. 2003. Polymer Electrolyte Membran Fuel Cell with Metal Foam in the Gas Flow-Field of Bipolar/End Plates. Journal of New Materials Electrochemistry Systems. 6: 231–236.
Wind, J., Spah, R., Kaiser, W., Bohm, G. 2002. Metallic Bipolar Plate for PEM Fuel Cells. Journal of Power Sources. 105: 256–260.
Wang, S., Peng, J., Lui, W. 2006. Performance of the gold-plated Titanium Bipolar Plates for the Light Weight PEM Fuel Cells. Journal of Power Sources. 162: 486–491.
Kumar, A., Ramana, G. R. 2004. Materials and Design Development for Bipolar/End Plate in Fuel Cells. Journal of Power Sources. 129: 62–67
Yuan, X. Z., Wang, H., , Zhang, J., , Wilkinson, D. P. 2006. Bipolar Plate for PEM Fuel Cells-From Material to Processing. Journal of New Materials for Eletrochemical System. 8: 257–267.
Brady, M. P., More, K. L., Tortorelli, P. F., Walker, L. R. 2003. Cost-Effective Surface Modification for Metallic Bipolar Plates. FY 2003 Progress Report.
Kim, J. S., Peelen, W. H. A., Hemmes, K., Makkus, R. C. 2002. Effect of Alloying Elements on the Contact Resistance and the Passivation Behavior of Stainless Steel. Corrosion Society. 44: 635–655.
Jayaraj, J., Kim, Y. C., Kim, K. B., Seok, H. K., Fleury, E. 2005. Corrosion Studies on Fe-based Amorphous Alloy in Simulated PEM Fuel Cell Environment. Journal of Science and Technology of Advanced Materials. 6: 282–289.
Wang, Y., Northwood, D. O. 2007. Effects of O2 and H2 on the Corrosion of SS 316 L Metallic Bipolar Plate Materials in Simulated Anode and Cathode Environments of PEM Fuel Cells. Journal of Electrochimia Acta. 52: 6793–6798.
Hung, Y., EL-Khatib, K. M., Tawfik, H. 2005. Corrosion-Resistant Lightweight Metallic Bipolar Plates for PEM Fuel Cells. Journal of Applied Electrochemistry. 35: 445–447.
Yue Hung, K. M. EL-Khatib, Hazem Tawfik. 2005. Corrosion-Resistant Lightweight Metallic Bipolar Plates for PEM Fuel Cells. Journal of Applied Electrochemistry. 35: 445–447.
ASTM G5-94. 1995. Standard Reference Test Method for Marking Potensiostatic and Potentiodynamic Anodic Polarization Measurements, American Society for Testing and Materials, Philadelphia.
Yue Hung, Hazem Tawfik. 2005. Testing and Evaluation of Aluminum Coated Bipolar Plate of PEM Fuel Cells Operating at 70 °C. Third International Conference on Fuel Cell Science, Engineering and Technology.
Hui Xu, Rong-Gui Du, Yu Liu, Chang-Jian Lin. 2006. Effect of pH on the Corrosion Behavior of Reinforcing Steel in Simulated Concrete Pore Solutions. State Key Laboratory for Physical Chemistry of Solid Surfaces, Department of Chemistry
Lee, S., Huang, C., Chen Y. 2003. Investigation of PVD Coating on Corrosion Resistance of Metallic Bipolar Plate in PEM Fuel Cell. Journal of Materials Processing Technology. 140: 688–693.
Burstein, G. T. 2005. A Century of Tafel’s Equation: 1905-2005 A Commemorative Issue of Corossion Science. Corrosion Science. 47: 2858–2870.
Yan Wang, Derek O. Northwood. 2006. An Investigation on Metallic Bipolar Plate Corrosion in Simulated Anode and Cathode Environments of PEM Fuel Cells using Potential-pH Diagrams. Journal of Electrochemical Science. 1: 447–455.
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.