The Effect of Ball Milling Process on Sintering and Densification Enhancement of W-Bronze Composites

Authors

  • Kahtan Sadiq Mohammed Universiti Malaysia Perlis, School of Materials Engineering-Taman Muhibah-Jejawi-Arau 02600 Perlis, Malaysia
  • Azmi Rahmat Universiti Malaysia Perlis, School of Materials Engineering-Taman Muhibah-Jejawi-Arau 02600 Perlis, Malaysia
  • Khairel Rafezi Ahmad Universiti Malaysia Perlis, School of Materials Engineering-Taman Muhibah-Jejawi-Arau 02600 Perlis, Malaysia

DOI:

https://doi.org/10.11113/jt.v59.2578

Keywords:

Metal matrix composites, mechanical alloying, sintering, microstructure, scanning electron microscopy

Abstract

Τhe miscibility of W in Sn and Cu is extremely poor. The wettability of W by those two elements is limited. To tackle this problem, two step ball milling process of the W–bronze elemental powders was proposed in this study. The softness of Sn in the first step was exploited to modify the surface morphology of the W particles. In the second step Cu was added to the ball milled mixture. To achieve this goal, two different sets of W50wt. %–pre mix bronze compacts of ball milled and of as received powders were utilized. Sintering process was performed at 1150°C. The two–step ball milled powders yielded sintered compacts of fine polygonal and homogeneous W network skeletal dispersed in bronze matrix. Sintered compacts of about 95% theoretical density were produced by this technique.

References

Xia, Z. Shen, J. Shen, Y. Li, Z. 2006. W-Sn solid solution synthesized by mechanical alloying at room temperature. J. alloys compd. 10: 1-5.

Raghu, T. Sundaresan, Ramakrishnan, R. Mohan, T. 2001. Synthesis of nanocrystalline copper–tungsten alloys by mechanical alloying. Mater. Sci. Eng. A (304–306): 438–441.

da Gosta F., da Silva, A., Gomes, U. 2003.The influence of dispersion technique on the characteristics of the W-Cu powders and on the sintering behavior. Powd. techno. 1346:123-132.

Johnson, J., German, R. 2005. Densification and distortion of liquid phase sintered W-Cu. Sintering: 291-294.

Ryu, S., Kim, Y., Moon, I. 2002. Dilatometric analysis on the sintering behavior of nanocrystalline W-Cu prepared by mechanical alloying. J. Alloys Compd. 335; 233-240.

Li, Z., Jia, C., He, Y., Chen, L., 2006. Kinetic characteristics of liquid phase sintering of mechanically activated W-15wt%Cu powder. J. of Univ. Sci. and Techno. Beijing. 13(4): 338-345.

German, R. 1997. Supersolidus liquid-phase sintering of prealloyed powders. Metall Mater. Trans. A 28A: 1553-1567.

Elliot, K. 2004. Composite material containing tungsten and bronze. Free patent on line. www.freepatentsonline.com/EP1436436.html assignee, international. Non-toxic composites publication.

Johnson, J., German, R. 1993. Phase equilibria effects on the enhanced liquid phase sintering of tungsten-copper. Metall. Trans. A 24a 11: 2369-2377.

German, R. 1992. Powder Metallurgy Science, (second edition), The Pennsylvania State University: 281: 455

Boonyongmaneerat, Y. 2007 Mechanical properties of partially sintered material. Mater. Sci. Engin. A 452-453: 773-780.

Johnson, J. Bresovesky, J. German, R. 2005. Effect of liquid content on distortion and rearrangement densification of liquid-phase-sintered W-Cu. Metall. Mater. Trans A. 36A: 1557-1565.

Kahtan, S., Azmi, R., Ismail, A. 2009. The effects of Fe additions on the liquid phase sintering of W–bronze composites. J. Alloys Compd. 482: 447-454.

Upadhyaya. A., German, R. 2001. Gravitational effects during liquid phase sintering, Mater. Chem. phys. (67): 25-31

Downloads

Published

2012-10-15

How to Cite

The Effect of Ball Milling Process on Sintering and Densification Enhancement of W-Bronze Composites. (2012). Jurnal Teknologi (Sciences & Engineering), 59(2). https://doi.org/10.11113/jt.v59.2578