Effect of La Doped on the Conductivity of the Perovskite Type PbZrO3

Authors

  • Salmie Suhana Che Abdullah School of Materials Engineering, University Malaysia Perlis, Perlis, Malaysia
  • Imaduddin Helmi Wan Nordin School of Mechatronics Engineering, University Malaysia Perlis, Perlis, Malaysia
  • Siti Hawa Mohamed Salleh School of Materials Engineering, University Malaysia Perlis, Perlis, Malaysia
  • Takao Esaka Department of Chemistry and Biotechnology, Graduate School of Engineering, Tottori University, Tottori, Japan

DOI:

https://doi.org/10.11113/jt.v59.2582

Keywords:

Perovskite, solid solution, interstitial ion, oxide ion electromotive force

Abstract

Electrochemical properties of Pb1-xLaxZrO3+x/2 with perovskite structure have been studied. The powdery Pb1-xLaxZrO3+x/2 has been prepared by solid-state reaction method. The X-ray diffraction analysis reveals that Pb1-xLaxZrO3+x/2 (x = 0.0-0.05) sintered at 900 ËšC was single phase structure. The electrical conductivity of the material has been investigated. By doping La at the lead site, the electrical conductivity of the Pb1-xLaxZrO3+x/2 system decreased. The undoped compound showed the highest electrical conductivity of ca. 10-3 S/cm. Electromotive Force (EMF) measurements of oxygen concentration cell confirm that the charge carrier of La doped PbZrO3 was the oxide ion.

References

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Published

2012-10-15

Issue

Vol. 59 No. 2 (2012): No. 59 (Sciences & Engineering) Suppl (2), November 2012

Section

Science and Engineering

License

Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.

How to Cite

Effect of La Doped on the Conductivity of the Perovskite Type PbZrO3. (2012). Jurnal Teknologi (Sciences & Engineering), 59(2). https://doi.org/10.11113/jt.v59.2582