Removal of Cadmium Using Ferro Magnetic Gels

Authors

  • Muhammad Aizat Azizul Rahman Department of Bioprocess Engineering, Faculty of Chemical Engineering, c/o Institute of Bioproduct Development, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Effaliza Misran Department of Bioprocess Engineering, Faculty of Chemical Engineering, c/o Institute of Bioproduct Development, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Ani Idris Department of Bioprocess Engineering, Faculty of Chemical Engineering, c/o Institute of Bioproduct Development, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Noordin Mohd Yusof Department of Manufacturing and Industrial Engineering, Faculty of Mechanical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v67.2726

Keywords:

Photocatalyst, PVA-alginate magnetic beads, cadmium

Abstract

The removal of cadmium (Cd) from aqueous solution of cadmium chloride using ferromagnetic photocatalyst gel was investigated. The experiments were performed under sunlight and also away from sunlight. Recycling experiments were also performed to determine the durability of the ferromagnetic photocatalyst gel. The results revealed that removal of cadmium was higher in the presence of sunlight irradiation compared to without sunlight. Apparently the treatment process for Cd involved both adsorption and photocatalytic process. The removal rate of Cd was faster when it was exposed to sunlight where almost 100% of Cd was removed within 4 hours. The presence of pores was observed from FESEM images and such morphology was considered helpful for mass transfer of Cd(II) to the photocatalyst active sites embedded in the PVA-alginate magnetic beads. The PVA-alginate magnetic beads produced were reused after treating with 25 ppm of Cd(II) solutions without washing them. The performance of each cycle was about the same as the previous cycle until it reached the seventh cycle where the ferro photo gels start to lose its removal efficiency.

References

Barakat, M. A. 2010. New Trends in Removing Heavy Metals from Industrial Wastewater. Arabian Journal of Chemistry. 4(4): 361–377.

Patterson, J. W. 1985. Industrial Wastewater Treatment. 2nd ed. Boston- London-Sydney-Wellington-Durban-Toronto: Butterworth Publisher.

Nosier, S. A. 2003. Removal of Cadmium Ions from Industrial Wastewater by Cementation, Chemical and. Biochemical Engineering Quarterly. 17(3): 219–224

Litter, M. I. 1999. Review: Heterogeneous Photocatalysis—transition Metal Ions in Photocatalytic Systems. Applied Catalysis B: Environmental. 23: 89–114.

Rocher, V., J. M. Siaugue, B. Cabuil, and A. Bee. 2008. Removal of Organic Dyes by Magnetic Alginate Beads. Water Research. 42: 1290–1298.

Idris, A., N. Hassan, N. Mohd Ismail, E. Misran, N. Yusuf, A. F. Ngomsik, and A. Bee. 2010. Photocatalytic Magnetic Separable Beads for Chromium (VI) Reduction. Water Research. 44(6): 1683–1688.

Idris, A., N. Hassan, R. Rashid, and A.F. Ngomsik. 2011. Kinetic and Regeneration Studies of Photocatalytic Magnetic Separable Beads for Chromium (VI) Reduction under Sunlight. Journal of Hazardous Materials. 186(1): 629–635.

Massart, R. 1981. Preparation of a Aqueous Magnetic Liquids in Alkaline and Acidic Media. IEEE Transaction on Magnetics. 17: 1247–1248.

Bee, A., R. Massart, S. Neveu. 1995. Synthesisn of Very Fine Maghemite Particles. Journal of Magnetism and Magnetic Materials. 149(1–2): 6–9.

Jeon, C., J. Y. Park, and Y. J. Yoo. 2002. Novel Immobilization of Alginic Acid for Heavy Metal Removal. Journal of Biochemical Engineering. 11: 159–166.

Idris, A., N.A. Mohd Zain, and M.S. Suhaimi. 2008. Immobilization of Baker’s Yeast Invertase in PVA-alginate Matrix Using Innovative Immobilisation Technique. Process Biochemistry. 43: 331–338.

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Published

2014-02-28

How to Cite

Removal of Cadmium Using Ferro Magnetic Gels. (2014). Jurnal Teknologi, 67(2). https://doi.org/10.11113/jt.v67.2726