Synthesis and Characterization of Green Porous Carbons with Large Surface Area by Two Step Chemical Activation with KOH

Authors

  • Noor Shawal Nasri Sustainable Waste-to-Wealth Unit, UTM-MPRC Institute Oil & Gas, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mohammed Jibril Sustainable Waste-to-Wealth Unit, UTM-MPRC Institute Oil & Gas, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Muhammad Abbas Ahmad Zaini Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Rahmat Mohsin Sustainable Waste-to-Wealth Unit, UTM-MPRC Institute Oil & Gas, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Hamza Usman Dadum Sustainable Waste-to-Wealth Unit, UTM-MPRC Institute Oil & Gas, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Ahmed Murtala Musa Sustainable Waste-to-Wealth Unit, UTM-MPRC Institute Oil & Gas, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v67.2787

Keywords:

Adsorbent, coconut shell, micropores, synthesis, chemical activation, potassium hydroxide

Abstract

Porous carbons were synthesized from coconut shell using chemical activation by potassium hydroxide (KOH). N2 adsorption isotherm analysis for BET surface area and pore volume of the synthesized porous carbon were carried out. The Langmuir surface area, BET surface area and pore volume are 1646 m2/g, 1353 m2/g and 0.6 cm3/g, respectively. From the FTIR analysis, hydroxyls, alkenes, carbonyls and aromatics functional groups were identified. The proximate and ultimate analysis shows high percentage of carbon and less ash content which indicates a good precursor material for porous carbon. The carbonization temperature and time were also varied to observe their effect on the yield of char, with carbonization at 7000C for 2 h having highest yield of 32%.

References

Sahu, J. N., J. Acharya and B.C. Meikap. 2010. Optimization of Production Conditions for Activated Carbons from Tamarind Wood by Zinc Chloride Using Response Surface Methodology. Bioresource Technology. 101: 1974–1982.

Ioannidou, O. and A. Zabaniotou. 2007. Agricultural Residues as Precursors for Activated Carbon Production: A Review. Renewable and Sustainable Energy Reviews. 11(9): 1966–2005.

Hesas, R. H., W. M. A. W. Daud, J. N. Sahu and A. Arami-Niya. 2013. The Effects of a Microwave Heating Method on the Production of Activated Carbon from Agricultural Waste: A Review. Journal of Analytical and Applied pyrolysis. 100: 1–11.

Prauchner, M. J. and F. Rodríguez-Reinoso. 2012. Chemical Versus Physical Activation of Coconut Shell: A Comparative Study. Microporous and Mesoporous Materials. 152: 163–171.

Yin, C. Y., M. K. Aroua and W. M. A. W. Daud. 2007. Review of Modifications of Activated Carbon for Enhancing Contaminant Uptakes from Aqueous Solutions. Separation and Purification Technology. 52: 403–415.

Lu, X., J. Jiang, K. Sun, X. Xie and Y. Hu. 2012. Surface Modification, Characterization and Adsorptive Properties of a Coconut Activated Carbon. Applied Surface Science. 258: 8247–8252.

Chingombe, P., B. Saha and R.J. Wakeman. 2005. Surface Modification and Characterization of Coal-based Activated Carbon. Carbon. 43: 3132–3143.

Demiral, H., I. Demiral, B. Karabacakoglu and F. Tumsek. 2011. Production of Activated Carbon from Olive Bagasse by Physical Activation. Chemical Engineering Research and Design. 89: 206–213.

Daud, W. M. A. W. and W. S. W. Ali. 2004. Comparison on Pore Development of Activated Carbon Produced from Palm Shell and Coconut Shell. Bioresource Technology. 93: 63–69.

Yang, K., P. Jinhui, C. Srinivasakannan, L. Zhang, H. Xia and X. Duan. 2010. Preparation of High Surface Area Activated Carbon from Coconut Shells Using Microwave Heating. Bioresource Technology. 101: 6163–6169.

Sun, Y. and P. A. Webley. 2010. Preparation of Activated Carbons from Corncob with Large Specific Surface Area by a Variety of Chemical Activators and Their Application in Gas Storage. Chem. Eng. J. 162(3): 883–892.

Cansado, I. P. P., A. I. Falcao, M. M. L. Ribeiro and P. J. M. Carrott. 2012. The Influence of Activated Carbon Post-treament on the Phenolic Compounds Removal. Fuel Processing Technology. 103: 64–70.

Nabais, J. M. V., C. E. C. Laginhas, P. J. M. Carrott and R. Carrott. 2011. Production of Activated Carbon from Almond Shell. Fuel Processing Technology. 92: 234–240.

Cazetta, A. L., A. M. M. Vargas, E. M. Nogami, M. H. Kunita, M. R. Guilherme, A. C. Martins, T. L. Silva, J. C. G. Moraes and V. C. Almeid. 2011. NaOH Activated Carbon of High Surface Area Produced from Coconut Shell: Kinetics and Equilibrium Studies from the Methylene Blue Adsorption. Chem. Eng. J. 174: 117–125.

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Published

2014-03-15

How to Cite

Synthesis and Characterization of Green Porous Carbons with Large Surface Area by Two Step Chemical Activation with KOH. (2014). Jurnal Teknologi, 67(4). https://doi.org/10.11113/jt.v67.2787