Development of Rigid Biocomposite Polyurethane Foam for Load Bearing Application

Authors

  • Mohd Haziq Dzulkifli Centre for Composites (CfC), Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia
  • Mohd Yazid Yahya Centre for Composites (CfC), Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia
  • Farhana Shakira Md Akhir Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia
  • Rohah Abd Majid Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v68.2929

Keywords:

Rigid polyurethane foams, palm oil polyoil, mechanical properties, thermal properties

Abstract

Polyurethane (PU) foams are widely used today in automotive and as insulation system. Due to environmental issues, efforts have been made to replace petrochemical polyol with natural-based polyol in PU foam production, without sacrificing any properties. This study aims as to produce palm oil-based polyurethane composite foam for load bearing purposes. Palm oil-based polyol (POP) was reacted with polymeric 4,4-diphenylmethane diisocyanate (p-MDI) with water as blowing agent and silicone surfactant to produce rigid PU foams. The foams obtained were varied by NCO:OH ratios and water content and characterized for their morphology and compressive strength. Scanning electron micrographs (SEM) indicated the cells within the obtained foams are closed cells. Compressive strength of obtained foams shows considerable improvement but only up to NCO:OH ratio of 1:1.35. 

References

Chuayjuljit, S., Maungchareon, A., and Saravari, O. 2010. Preparation and Properties of Palm Oil-Based Rigid Polyurethane Foams. Journal of Reinforced Plastics and Composites. 29(2): 218–225.

Prociak, A., Rojek, P., and Pawlik, H. 2012. Flexible Polyurethane Foams Modified with Natural Oil Based Polyols. Journal of Cellular Plastics. 48(6): 489–499.

Rashmi, B. J., Rusu, D., Prashantha, K., Lacrampe, M. F., and Krawczak, P. 2012. Development of Water-Blown Bio-Based Thermoplastic Polyurethane Foams Using Bio-derived Chain Extender. Journal of Applied Polymer Science. 128: 292–303.

Chian, K. S., and Gan, L. H. 1998. Development of a Rigid Polyurethane Foam from Palm Oil. Journal of Applied Polymer Science. 68: 509–515.

Tan, S., Abraham, T., Ference, D., and Macosko, C.W. 2011. Rigid polyurethane foams from a soybean-based Polyol. Polymer. 52(13): 2840–2846.

Ali, E.S., and Ahmad, A. 2012. Bionanocomposite Hybrid Polyurethane Foam Reinforced with Empty Fruit Bunch and Nanoclay. Composites: Part B. 43(7): 2813–2816.

Tanaka, R., Hirose, S., and Hatakeyama, H. 2008. Preparation and Characterization of Polyurethane Foams Using a Palm Oil-based Polyol. Bioresource Technology. 99(9): 3810–3816.

Ji, D., Fang, Z., Wan, Z., Chen, H., He, W., Li, X., and Guo, K. 2013. Rigid Polyurethane Foam Based on Modified Soybean Oil. Advanced Materials Research. 724–725: 1681–1684.

Badri, K. H., Othman, Z., Ahmad, S. H. 2004. Rigid Polyurethane Foams from Oil Palm Resources. Journal of Materials Science. 39: 5541–5542.

Veronese, V. B., Menger, R. K., Forte, M. M. de C., and Petzhold, C. L. 2011. Rigid Polyurethane Foam Based on Modified Vegetable Oil. Journal of Applied Polymer Science. 120: 530–537.

Mat Rejab, M. R. 2004. Polymeric Foam as Core of Side Door Impact Beam. Master Thesis. Universiti Teknologi Malaysia.

Shen, S. Y., Masters, F. J., Upjohn II, H. L., and Ferraro, C. C. 2013. Mechanical Resistance properties of FRP/polyol-isocyanate foam sandwich panel. Composite Structures. 99: 419–432.

Siriruk, A., Weitsman, Y. J., and Penumadu, D. 2009. Polymeric Foams and Sandwich Composites: Material Properties, Environmental Effect, and Shear-lag Modeling. Composites Science and Technology. 69: 814–820.

Langdon, G. S., von Klamperer, C. J., Rowland, B. K., and Nurick, G. N. 2012. The Response of Sandwich Structures with Composite Face Sheets and Polymer Cores to Air-blast Loading: Preliminary Experiment. Engineering Structures. 36: 104–112.

Downloads

Published

2014-05-01

How to Cite

Development of Rigid Biocomposite Polyurethane Foam for Load Bearing Application. (2014). Jurnal Teknologi (Sciences & Engineering), 68(3). https://doi.org/10.11113/jt.v68.2929