SEPARATION OF ETHYL ACETATE FROM WATER MIXTURE USING SAGO/POLY (VINYL ALCOHOL) BLENDED MEMBRANES: EFFECT OF SAGO BLENDED RATIOS

Authors

  • Abdulhakim M. Alamaria Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mohd Ghazali Mohd Nawawi Centre of Lipid Engineering and Applied Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v75.2976

Keywords:

Sago, membrane, pervaporation, blended

Abstract

Relatively new Sago/PVA blended membranes were prepared by solution casting technique. Homogenous sago/PVA membranes were prepared with different ratio of sago content in the membrane. The blended membranes were characterized using Fourier Transform Infrared Spectroscopy (FTIR), contact angle measurements, and degree of swelling (DS). The blended membranes were tested for pervaporation of ethyl acetate-water mixture at a range of 1-4wt% of water in the solution. The effects of feed temperature and concentration were investigated. The permeation flux increased around 30% with sago content in the blend membranes from 3wt% to 7wt% at 60oC. However, the separation factor decreased from 433 to 387 for same membrane.

Author Biography

  • Abdulhakim M. Alamaria, Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
    FKK

References

Fu, Y.-J., Lai, C.-L., Chen, J.-T., Liu, C.-T., Huang, S.-H., Hung, W.-S., Hu, C.-C. & Lee. 2014. Hydrophobic Composite Membranes for Separating of Water–Alcohol Mixture by Pervaporation at High Temperature. Chemical Engineering Science. 111: 203-210.

Zhou, K., Zhang, Q. G., Han, G. L., Zhu, A. M. & Liu, Q. L. 2013. Pervaporation of Water–Ethanol and Methanol–MTBE Mixtures Using Poly (Vinyl Alcohol)/Cellulose Acetate Blended Membranes. Journal of Membrane Science. 448: 93-101.

Koch, K. & Gorak, A. Pervaporation of Binary and Ternary Mixtures of Acetone, Isopropyl Alcohol and Water Using Polymeric Membranes: Experimental Characterisation and Modelling. Chemical Engineering Science.

An, Q. F., Qian, J. W., Sun, H. B., Wang, L. N., Zhang, L. & Chen, H. L. 2003. Compatibility of PVC/EVA Blends and the Pervaporation of Their Blend Membranes for Benzene/Cyclohexane Mixtures. Journal of Membrane Science. 222: 113-122.

Chen, J. H., Liu, Q. L., Zhu, A. M., Zhang, Q. G. & Fang, J. 2008. Pervaporation Separation of MeOH/DMC Mixtures using STA/CS Hybrid Membranes. Journal of Membrane Science. 315: 74-81.

Wang, L., Li, J., Lin, Y. & Chen, C. 2007. Separation of Dimethyl Carbonate/Methanol Mixtures by Pervaporation with Poly(Acrylic Acid)/Poly(Vinyl Alcohol) Blend Membranes. Journal of Membrane Science. 305: 238-246.

Bengtsson, E., Tragardh, G. & Hallstrom, B. 1993. Concentration polarization during the enrichment of aroma compounds from a water solution by pervaporation. Journal of Food Engineering, 19, 399-407.

JiangI, L. Y., Wang, Y., Chung, T.-S., Qiao, X. Y. & Lai, J.-Y. 2009. Polyimides Membranes for Pervaporation and Biofuels Separation. Progress in Polymer Science. 34: 1135-1160.

Xiao, S., Huang, R. Y. M. & Feng, X. 2006. Preparation and Properties of Trimesoyl Chloride Crosslinked Poly(Vinyl Alcohol) Membranes for Pervaporation Dehydration of Isopropanol. Journal of Membrane Science. 286: 245-254.

Alghezawi, N., Şanli, O., Aras, L. & Asman, G. 2005. Separation of Acetic Acid–water Mixtures Through Acrylonitrile Grafted Poly(Vinyl Alcohol) Membranes by Pervaporation. Chemical Engineering and Processing: Process Intensification. 44: 51-58.

Zhu, Y., Xia, S., Liu, G. & Jin, W. 2010. Preparation of Ceramic-Supported Poly(Vinyl Alcohol)–Chitosan Composite Membranes and Their Applications in Pervaporation Dehydration of Organic/Water Mixtures. Journal of Membrane Science. 349: 341-348.

Li, B.-B., Xu, Z.-L., Alsalhy Qusay, F. & Li, R. 2006. Chitosan-poly (vinyl alcohol)/poly (acrylonitrile) (CS–PVA/PAN) Composite Pervaporation Membranes for the Separation of Ethanol–Water Solutions. Desalination. 193: 171-181.

Yong Nam, S. & Moo Lee, Y. 1999. Pervaporation of Ethylene Glycol–water Mixtures: I. Pervaporation Performance of Surface Crosslinked Chitosan Membranes. Journal of Membrane Science. 153: 155-162.

Bai, Y., Qian, J., Zhang, C., Zhang, L., An, Q. & Chen, H. 2008. Cross-linked HTPB-based Polyurethaneurea Membranes for Recovery of Ethyl Acetate from Aqueous Solution by Pervaporation. Journal of Membrane Science. 325: 932-939.

Yongquan, D., Ming, W., Lin, C. & Mingjun, L. 2012. Preparation, Characterization of P(VDF-HFP)/[bmim]BF4 ionic Liquids Hybrid Membranes and Their Pervaporation Performance for Ethyl Acetate Recovery from Water. Desalination. 295: 53-60.

Parvez, A. M., Luis, P., Ooms, T., Vreysen, S., Vandezande, P., Degreve, J. & Van Der Bruggen, B. 2012. Separation of Ethyl Acetate–Isooctane Mixtures by Pervaporation and Pervaporation-Based Hybrid Methods. Chemical Engineering Journal. 210: 252-262.

Garc’A-Ivars, J., AlcainaL-Miranda, M. I., Iborra-Clar, M. I. & Iborra-Clar, A. 2012. Fabrication and Characterization of Organic Pervaporation Membranes to Recover Ethyl Acetate of Aqueous Solutions. Procedia Engineering. 44: 678-680

D. R. Lu, C. M. X., S. J. Xu 2009. Starch-based Completely Biodegradable Polymer Materials. EXPRESS Polymer Letters. 6: 366-375.

Masuda, T., Takatsuka, M., Tang, B.-Z. & Higashimura, T. 1990. Pervaporation of Organic Liquid-water Mixtures Through Substituted Polyacetylene Membranes. Journal of Membrane Science. 49: 69-83.

SHAO, P. & HUANG, R. Y. M. 2007. Polymeric Membrane Pervaporation. Journal of Membrane Science. 287: 162-179.

Yeom, C.-K. & Lee, K.-H. 1996. Pervaporation Separation Of Water-Acetic Acid Mixtures through Poly(Vinyl Alcohol) Membranes Crosslinked With Glutaraldehyde. Journal of Membrane Science. 109: 257-265.

Huang, R. Y. M. & Xu, Y. F. 1989. Pervaporation Separation Of Acetic Acid-water Mixtures Using Modified Membranes. Part II. Gammaray-Induced Grafted Polyacrylic Acid (PAA)-Nylon 6 Membranes. Journal of Membrane Science. 43: 143-148.

Ghazali, M., NawawI, M. & Huang, R. Y. M. 1997. Pervaporation Dehydration of Isopropanol with Chitosan Membranes. Journal of Membrane Science. 124: 53-6.

Downloads

Published

2015-06-29

Issue

Section

Science and Engineering

How to Cite

SEPARATION OF ETHYL ACETATE FROM WATER MIXTURE USING SAGO/POLY (VINYL ALCOHOL) BLENDED MEMBRANES: EFFECT OF SAGO BLENDED RATIOS. (2015). Jurnal Teknologi, 75(1). https://doi.org/10.11113/jt.v75.2976