Adsorption of Carbon Dioxide on Monoethanolamine (MEA)–Impregnated Kenaf Core Fiber by Pressure Swing Adsorption System (PSA)

Authors

  • Nabilah Zaini Faculty of Petroleum and Renewable Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Khairul Sozana Nor Kamarudin Faculty of Petroleum and Renewable Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v68.3023

Keywords:

Kenaf, modification, monoethanolamine (MEA), CO2 adsorption, PSA system

Abstract

Emission of carbon dioxide (CO2) becomes a major concern in combating issues of global warming. The strategy to reduce the concentration of CO2 could be achieved by executing carbon capture and storage (CCS) technology such as adsorption. This study presents the used of kenaf as a green source for CO2 adsorption material. The modification of MEA on kenaf is a novelty work to enhance the capacity of adsorbent since MEA has been proved to have potential in separating CO2 in industrial applications. In this work, 10 wt % of MEA has been impregnated on kenaf via wet impregnation method. The adsorption of CO2 study was conducted by passing CO2/N2 mixture in a ratio of 30:70 in a Pressure Swing Adsorption (PSA) system with a pressure up to 1.5 bar at ambient temperature. Result obtained via SEM analysis shows that the morphology of kenaf was affected after modification with MEA. However, the presence of MEA on kenaf has improved the CO2 adsorption capacity by 16 %. In addition, the adsorption equilibrium data for kenaf and MEA modified kenaf are well fitted in Freundlich isotherm model at low pressure and well fitted in Langmuir model at higher pressure. This study indicates that the introduction of MEA on kenaf could enhance the CO2 adsorption process.  

References

Albo, A., P. Luis, and A. Irabin. 2010. Carbon Dioxide Capture from Flue Gases using a Cross–Flow Membrane Contactor and the Ionic Liquid 1–Ethyl–3–Methylimidazolium Ethylsulfate. Industrial and Engineering Chemistry Research. 49: 11045–11051.

Oh, T. H. 2010. Carbon Capture and Storage Potential in Coal–Fired Plant in Malaysia–A Review. Renewable and Sustainable Energy Reviews. 14: 2697–2709.

Yu, C. H., C. H. Huang, and C. S. Tan. 2012. A Review of CO2 Capture by Absorption and Adsorption. Aerosol and Air Quality Research. 12: 745–769.

Hook, R. J. 1997. An Investigation of Some Sterically Hindered Amines as Potential Carbon Dioxide Scrubbing Compounds. Industrial and Engineering Chemistry Research. 36: 1779–1790.

Zhang, X., C. F. Zhang, and Y. Liu. 2002. Kinetics of Absorption of CO2 into Aqueous Solution of MDEA Blended with DEA. Industrial and Engineering Chemistry Research. 41(5): 1135–1141.

Akanksha, K. K. Pant, and V. K. Srivastava. 2007. Carbon Dioxide Absorption into Monoethanolamine (MEA) in a Continuous Film Contactor. Chemical Engineering Journal. 133: 229–237.

Samanta, A. K., and S. S. Bandyopadhyay. 2009. Absorption of Carbon Dioxide into Aqueous Solutions of Piperazine Activated 2–Amino–2–Methyl–1–Propanol. Chemical Engineering Science. 64: 1185–1194.

Anson, A., C. C. H. Lin, S. M. Kuznicki, and J. A. Sawada. 2009. Adsorption of Carbon Dioxide, Ethane and Methane on Titanosilicate Type Molecular Sieves. Chemical Engineering Science. 64: 3683–3687.

An, H., B. Feng, and S. Su. 2009. CO2 Capture Capacities of Activated Carbon Fibre–Phenolic Resin Composites. Carbon. 47(10): 2396–2405.

Zhao, G., B. Aziz, and N. Hedin. 2010. Carbon Dioxide Adsorption on Mesoporous Silica Surfaces Containing Amine–Like Motifs. Applied Energy. 87: 2907–2913.

Zanganeh, K. E., A. Shafeen, and C. Salvador. 2009. CO2 Capture and Development of an Advanced Pilot–Scale Cryogenic Separation and Compression Unit. Energy Procedia. 1: 247–252.

Brunetti, A., F. Scura, G. Barbieri, and E. Drioli. 2010. Membrane Technologies for CO2 Separation. Journal of Membrane Science. 359: 115–125.

Rochelle, G. T. 2009. Amine Scrubbing for CO2 Capture. Sciences. 325: 1652–1654.

Resnik, K. P. 2004. Aqua Ammonia Process for Simultaneous Removal of CO2, SO2, and NOx. International Journal of Environmental Technology and Management. 4: 89–104.

Haszeldine, R. S. 2009. Carbon Capture and Storage: How Green Can Black Be? Science. 325: 1647–1651.

Duffy, A., G. M. Walker, and S. J. Allen. 2006. Investigations on the Adsorption of Acidic Gases using Activated Dolomite. Chemical Engineering Journal. 117: 239–244.

Plaza, M. G., C. Pevida, A. Arenillas, F. Rubiera, and J. J. Pis. 2007. CO2 Capture by Adsorption with Nitrogen Enriched Carbons. Fuel. 86: 2204–2212.

Mandal, B.P., and S.S. Bandyopadhyay. 2006. Simultaneous Absorption of CO2 and H2S into Aqueous Blends of N–Methyldiethanolamine and Diethanolamine. Environmental Science and Technology. 40: 6076–6084.

Yong, Z., V. G. Mata, and A. E. Rodrigues. 2002. Adsorption of Carbon Dioxide at High Temperature: A Review. Separation and Purification Technology. 26: 195–205.

Choi, S., J. H. Drese, and C. W. Jones. 2009. Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources. Chemistry and Sustainability Energy and Materials. 2(9): 796–854.

Dantas, T. L. P., F. M. T. Luna, I. J. Silva, A. E. B. Torres, D. C. S. Azevedo, A.E. Rodrigues, and R.F.M.P. Moreira. 2011. Carbon Dioxide–Nitrogen Separation through Pressure Swing Adsorption. Chemical Engineering Journal. 172: 698–704.

Sayari, A., Y. Belmabkhout, and R. Serna–Guerrero. 2011. Flue Gas Treatment via CO2 Adsorption. Chemical Engineering Journal. 171: 760–774.

Abdul Hamid, M. R. Kenaf Ganti Tembakau. Berita Harian. 18 July 2008.

Irmak, S., and I. Ozturk. 2010. Hydrogen Rich Gas Production by Thermocatalytic Decomposition of Kenaf Biomass. International Journal of Hydrogen Energy. 35: 5312–5317.

Abdul Khalil, H. P. S., A. F. I. Yusra, A. H. Bhat, and M. Jawaid. 2010. Cell Wall Ultrastructure, Anatomy, Lignin Distribution and Chemical Composition on Malaysian Cultivated Kenaf Fiber. Indusrial Crops and Products. 31: 113–121.

Edeerozey, A. M. M., H. M. Akil, A. B. Azhar, and M. I. Z. Ariffin. 2006. Chemical Modification of Kenaf Fibers. Materials Letters. 61: 2023–2025.

Seller, T., G. D. Miller, and M. J. Fuller. 1993. Kenaf Core as a Board Raw Material. Forest Products Journal. 43(7-8): 69–71.

Murphy, P. T., K. J. Moore, T. L. Richard, and C. J. Bern. 2007. Enzyme Enhanced Solid–State Fermentation of Kenaf Core Fiber for Storage and Pretreatment. Bioresource Technology. 98(16): 3106–3111.

Othman, M. R., and H. M. Akil. 2008. The CO2 Adsorptive and Regenerative Behaviours of Rhizopus Oligosporus and Carbonaceous Hibiscus Cannabinus L. Exposed to Thermal Swings. Microporous and Mesoporous Materials. 110: 363–369.

Wang, Q., J. Luo, Z. Zhong, and A. Borgna. 2011. CO2 Capture by Solid Adsorbents and their Applications: Current Status and New Trends. Energy and Environmental Science. 4: 42–55.

Mahmoud, D. K., M. A. M. Salleh, W. A. W. A. Karim, A. Idris, and Z. Z. Abidin. 2012. Batch Adsorption of Basic Dye using Acid Treated Kenaf Fibre Char: Equilibrium, Kinetic and Thermodynamic Studies. Chemical Engineering Journal. 181: 449–457.

Langmuir, I. 1918. The Adsorption of Gases on Plane Surfaces of Glass, Mica and Platinum. Journal of the American Chemical Society. 40: 1361–1403.

Subramanyam, B., and A. Das. 2009. Linearized and Non–Linearized Isotherm Models Comparative Study on Adsorption of Aqueous Phenol Solution in Soil. International Journal of Environmental Science and Technology. 6(4): 633–640.

Wong, Y. C., Y. S. Szeto, W. H. Cheung, and G. McKay. 2004. Adsorption of Acid Dyes on Chitosan–Equilibrium Isotherm Analyses. Process Biochemistry. 39: 693–702.

Alagumuthu, G., V. Veeraputhiran, and R. Venkataraman. 2010. Adsorption Isotherms on Fluoride Removal: Batch Techniques. Applied Science Research. 2(4): 170–185.

Freundlich, H. M. F. 1906. Over the Adsorption in Solution. Journal of Physical Chemistry. 57: 385–471.

Namasivayam, C., R. Jeyakumar, and R. T. Yamuna. 1994. Dye Removal from Wasterwater by Adsorption on Waste Fe(III)/Cr(III) Hydroxide. Waste Management. 14: 643–648.

Liu, X., L. Zhou, X. Fu, Y. Sun, W. Su, and Y. Zhou. 2007. Adsorption and Regeneration Study of the Mesoporous Adsorbent SBA–15 Adapted to the Capture/Separation of CO2 and CH4. Chemical Engineering Science. 62: 1101–1110.

Richter, E., W. Schultz, and A. L. Myers. 1989. Effect of Adsorption Equation on Prediction of Multicomponent Equilibria by the Ideal Adsorbed Solution Theory. Chemical Engineering Science. 44(8): 1609–1616.

Macias–Garcia, A., E. M. Cuerda–Correa, M. Olivares–Marin, A. Diaz Paralejo, and M. A. Diaz–Diez. 2012. Development and Characterization of Carbon–Honeycomb Monoliths from Kenaf Natural Fibers: A Preliminary Study. Industrial Crops and Products. 35: 105–110.

Hagewiesche, D. P., S. S. Ashour, H. A. Al–Ghawas , and O. C. Sandall. 1995. Absorption of Carbon Dioxide into Aqueous Blends of Monoethanolamine and N–Methyldiethanolamine. Chemical Engineering Science. 50(7): 1071–1079.

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Published

2014-05-27

How to Cite

Adsorption of Carbon Dioxide on Monoethanolamine (MEA)–Impregnated Kenaf Core Fiber by Pressure Swing Adsorption System (PSA). (2014). Jurnal Teknologi, 68(5). https://doi.org/10.11113/jt.v68.3023