The Influence of pH on the Removal of Ammonia from a Scheduled Waste Landfill Leachate

Authors

  • A. Sani Air Resources Research Laboratory, Malaysia-Japan International Institute of Technology, 54100 UTM Kuala Lumpur, Malaysia
  • M. Rashid Air Resources Research Laboratory, Malaysia-Japan International Institute of Technology, 54100 UTM Kuala Lumpur, Malaysia
  • N. Hanira Department of Biological & Agricultural Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Selangor, Malaysia
  • C. M. Hasfalina Department of Biological & Agricultural Engineering, Faculty of Engineering, Universiti Putra Malaysia, 43400 Selangor, Malaysia

DOI:

https://doi.org/10.11113/jt.v68.3026

Keywords:

Scheduled waste landfill, ammonia removal, pH, leachate

Abstract

Leachates are formed as the result of water or other liquid passing through the landfilled waste. These leachates contain high amounts of inorganic and organic matter such as ammonia which must be treated before being discharged into the environment. A pretreatment is required to increase the efficiency of the ammonia removal process. This paper presents the influence of pH on the removal of ammonia in leachate sample by lime precipitation. A raw leachate sample taken from a scheduled waste landfill was treated with different amount of lime (2, 4, 6, 8 and 10 g/L) to investigate the removal or release of ammonia. The removal of ammonia of raw leachate (average pH=9.43) was 26% and increases to the optimum dosage of 4 g/L with 54% removal at pH=12.39. However, addition of lime of more than 6 g/L does not show any significant effect on ammonia removal due to restabilization of colloids and re-dispersion of the colloidal particulates. An appropriate dosage of lime is an important factor that could save cost and time for the downstream secondary treatment.  

References

Kjeldsen, P., M. A. Barlaz, A. P. Rooker, A. Baun, A. Ledin, and T. H. Christensen. 2002. Present and Long-term Composition of MSW Landfill Leachate: A Review. Environmental Science and Technology. 32: 297–336.

Jokela, J. P. Y., and J. A. Rintala. 2003. Anaerobic Solubilisation of Nitrogen from Municipal Solid Waste (MSW). Environmental Science and Biotechnology. 2: 67–77.

Lopez, A., M. Pagano, A. Volpe, and A. Di Pinto. 2004. Fenton’s Pre-treatment of Mature Landfill Leachate. Chemosphere. 54: 1005–1010.

Renou, S., S. Poulain, J. G. Givaudan, and P. Moulin, 2008. Treatment Process Adapted To Stabilized Leachates: Lime Precipitation-Prefilteration-Reverse Osmosis. Journal of Membrane Science. 313: 9–22.

Aziz, H. A., Z. Daud, M. N. Adlan, and Y. T. Hung. 2009. The Use of Polyaluminum Chloride for Removing Colour, COD and Ammonia From Semi-aerobic Leachate. International Journal of Environmental Engineering. 1: 20–35.

Cheung, K. C., L. M. Chu, and M. H. Wong. 1997. Ammonia Stripping as a Pretreatment for Landfill Leachate. Water, Air and Soil Pollution. 94: 209–221.

Kurniawan, T. A., W. H. Lo, and G. Y. S. Chan. 2006. Physico-chemical Treatments For Removal Of Recalcitrant Contaminants From Landfill Leachate. Journal of Hazardous Materials. B129: 80–100.

Zainol, N. A., H. A. Aziz, and M. S. Yusoff, 2012. Characterization of Leachate from Kuala Sepetang and Kulim Landfills: A Comparative Study. Energy and Environment Research. 2(2): 45–52.

Umar, M., H. A. Aziz, and M. S. Yusoff. 2010. Variability of Parameters Involved in Leachate Pollution Index and Determination of LPI from Four Landfills in Malaysia. Chemosphere. 54: 1005–1010.

Kim, D. J., D. I. Lee, and J. Keller. 2006. J. Effect of Temperature and Free Ammonia on Nitrification and Nitrite Accumulation in Landfill Leachate and Analysis of Its Nitrifying Bacterial Community by FISH. Bioresource Technology. 97(3): 459–468.

APHA, 2005. Standard Methods for the Examination of Water and Wastewater. 21st ed. Washington, DC: American Public Health Association.

National Lime Association. 2007. Lime Terminology, Standards & Properties. 1–10

Ferraz, F. M., J. Povinelli, and E. M. Vieira. 2013. Ammonia Removal from Landfill Leachate by Air Stripping and Absorption. Environmental Technology. 34(15): 2317–2326.

Downloads

Published

2014-05-27

How to Cite

The Influence of pH on the Removal of Ammonia from a Scheduled Waste Landfill Leachate. (2014). Jurnal Teknologi, 68(5). https://doi.org/10.11113/jt.v68.3026