Electrospun Conditions of Poly(vinyl chloride) Nanofibrous Membrane Plasticized with Polyurethane
DOI:
https://doi.org/10.11113/jt.v68.3032Keywords:
Electrospinning, poly(vinyl chloride), polyurethane, membraneAbstract
Electrospun poly(vinyl chloride) (PVC) nanofibrous were prepared by electrospinning. Various concentration of polyurethane (PU) were added to PVC solution for plasticization of the electrospun nanofibrous. The pristine and plasticized nanofibrous were characterized by field emission scanning electron microscopy (FE-SEM), differencial thermal analysis (DTA), and thermogravimetry analysis (TGA), respectively. Thermal properties form DTA and TGA results indicated that the addition of PU decreased glass transition temperature (Tg) of PVC and increased heat resistance of PVC nanofiber. The dielectric constant of plasticized nanofibrous measured using precision LCR meter indicated that the membrane were dense. Â
References
Lee, K. H., Kim, H. Y., Ryu, Y. J., Kim, K. W., Choi, S. W. 2003. Mechanical Behavior of Electrospun Fiber Mats of Poly(vinyl chloride)/polyurethane Polyblends. J Polym Sci Part B Polym Phys. 41: 1256–1262.
Pedicini, A., Farris R. J. 2003. Mechanical Behavior of Electrospun Polyurethane. Polymer. 44: 6857–6862.
Frenot, A., Chronakis, I.S. 2003. Polymer nanofibers assembled by electrospinning. Current Opinion in Colloid and Interface Science. 8(1): 64–75.
Zhang, Y., Xia, Z., Huang, H., Chen, H. 2009. Thermal degradation of polyurethane based on IPDI. J Anal Appl Pyrolysis. 84(1): 89–94.
Zhong, Z., Cao, Q., Jing, B., Wang, X., Li, X., Deng, H. 2012. Electrospun PVdF-PVC Nanofibrous Polymer Electrolytes for Polymer Lithium-ion Batteries. Mat Sci Eng Part B. 177(1): 86–91.
Phatcharasit, K., Taweepreda, W., Boonkerd, K., Kim, J.-K. 2014. Electrospun Epoxidized Natural Rubber with Poly(vinyl chloride) (ENR-PVC) Nanofibrous for PEMFC Applications. Advanced Materials Research. 844: 507–510.
Phatcharasit, K., Taweepreda, W., Boonkerd, K., Kim, J.-K. 2013. Preparation and Properties of Electrospun PVC Nanofiber. Advanced Materials Research. 770: 193–196.
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