Effect of Zeolite Synthesized from Rice Husk Silica Towards Mixed Matrix Polysulfone Ultrafiltration Membrane

Authors

  • Nurafiqah Rosman Advanced Material and Manufacturing Centre, Faculty of Mechanical Engineering, Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia
  • Zawati Harun Advanced Material and Manufacturing Centre, Faculty of Mechanical Engineering, Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia
  • Muhammad Zaini Yunos Advanced Material and Manufacturing Centre, Faculty of Mechanical Engineering, Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia
  • Sulaiman Hasan Advanced Material and Manufacturing Centre, Faculty of Mechanical Engineering, Universiti Tun Hussein Onn Malaysia, Batu Pahat 86400, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v70.3443

Keywords:

Polysulfone (PSf), rice husk ash, zeolite, ultrafiltration

Abstract

In the present work, polysulfone (PSf) ultrafiltration membranes were prepared by solution casting via phase inversion process. The effects of synthesized rice husk (RH) zeolite on the properties and performance of the casted PSf membrane were observed and investigated. Characterization of synthesized RH zeolite and morphology of membrane were conducted by using X-ray diffractometer (XRD), field emission microscopy (FESEM) and scanning electron microscopy (SEM). XRD analysis shows a mixture of zeolite A, Y and P, while FESEM images showed agglomeration of cubic-shaped morphology of the synthesized RH zeolite. SEM analysis on membrane morphology indicates that the addition of synthesized RH zeolite obviously changed the microstructure of the membrane sub layer. At 2g RHY content, the membranes held the highest water permeability (315.29 Lm-2h-1) and continuously decreased with higher RHY content. The incorporation of the RHY particles beyond 2% causes declination to the membrane flux and increment to the humic acid rejection from 95.8 to 99.6%.

References

P. cote, D. Thompson. 2000. Water Sci. Technol. 41(10–11): 209–215.

B. Jefferson, A. L. Laine, T. Stephenson. 2000. Water Sci. Technol. 41(1): 197–204.

W. Huiqing, T. Beibei, W., Peiyi. 2014. Journal of Membrane Science. 451: 94–102.

H. Basri, A. F. Ismail, M. Aziz. 2011. Desalination. 273: 72–80.

M. C. García-Payo, M. Essalhi, M. Khayet. 2010. Journal of Membrane Science. 347: 209–219.

S. Khoonsap, S. Amnuaypanich. 2011. Journal of Membrane Science 367: 182–189.

A. Jomekian, M. Pakizeh, A. R. Shafiee, S. A. Akbar Mansoori. 2011. Separation and Purification Technology. 80: 556–565E.

Z.Yuan, X. Dan-Li. 2008. Desalination. 223: 438–447.

C. H. Loh and R. Wang. 2012. Chinese Journal of Chemical Engineering. 20(1): 71–79.

Y. Ma, F. Shi, Z. Wang, M. Wu, J. Ma, C. Gao. 2012. Desalination. 286: 131–137.

Z. Harun, M. R. Jamalludin, M. Z. Yunos, M. F. Shohur, A. F. Ismail. 2013. Advanced Materials Research. 701: 319–322.

M. R. Jamalludin, Z. Harun, H. Basri,M. Z. Yunos, M. F. Shohur. 2013. Applied Mechanics and Materials. 372: 8–12.

Corma, A. 2003. Journal of Catalysis. 216: 298–312.

Xu R., Pang w., Yu J., Huo Q., Chen J. 2007. Chemistry of Zeolites and Related Porous Materials: Synthesis and Structure. John Wiley & Son.

Y-J Hu, C-C Hu, K-R Lee, J-Y Lai. 2006. Desalination. 193: 119–128.

C. I.Chaidou, G. Pantoleontos, D. E. Koutsonikolas, S. P Kaldis., S. G. P. Sakellaropoulos. 2012. Separation Science and Technology. 47: 950–962.

R. Han, S. Zhang, C. Liu, Y. Wang, X. Jian. 2009. Journal of Membrane Science. 345: 5–12.

Weitkamp J. and Puppe L. 1999. Catalysis and Zeolites-Fundamentals and Applications Springer-Verlag Berlin Heidelberg New York.

Ramli, Z., Listiorini, E., Hamdan, H. Disember 1996. Jurnal Teknologi, 25: 27–35.

Turnbull M. S. 2010. Hydrogen Storage in Zeolites: Activation of the Pore Space Through Incorporation of Guest Materials. PHD thesis, University of Birmingham, UK.

R. Han, S. Zhang, C. Liu, Y. Wang, X. Jian. 2009). Journal of Membrane Science. 345: 5–12.

Emadzadeh, W. J. Lau, T. Matsuura, M. Rahbari-Sisakht, A. F. Ismail. 2014. Chemical Engineering Journal. 237: 70–80.

Liu F., Ma B-R, Zhou D., Xiang Y-h, Xue L-x. 2014. Microporous and Mesoporous Materials. 186: 113–120.

Mousa, H. 2007. Desalination. 217(1–3): 38–51.

Han R., Zhang S., Liu C., Wang Y., Jian X. 2009. Journal of Membrane Science. 345: 5–12.

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Published

2014-09-02

How to Cite

Effect of Zeolite Synthesized from Rice Husk Silica Towards Mixed Matrix Polysulfone Ultrafiltration Membrane. (2014). Jurnal Teknologi (Sciences & Engineering), 70(2). https://doi.org/10.11113/jt.v70.3443