Effect of Coolant Temperature on Progressive Freeze Concentration of Refined, Bleached and Deodorised Palm Oil based on Process Efficiency and Heat Transfer

Authors

  • Norshafika Yahya Center of Lipid Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Zaki Yamani Zakaria Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Noorhalieza Ali Center of Lipid Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Mazura Jusoh Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v74.4690

Keywords:

Progressive freeze concentration, palm oil, refined bleached and deodorised palm oil, iodine value and heat transfer

Abstract

In this paper, raw material of refined bleached and deodorised palm oil (RBDPO) was separated into olein and stearin by applying progressive freeze concentration (PFC) as an alternative method to replace the conventional fractionation process using coil crystallizer. Overall heat transfer coefficient (U) was analyzed from the process by varying different coolant temperature values since both of them are closely related each other. In this case, heat transfer efficiency depends strongly on crystal of stearin formed on the inner wall of cooled surface and is explained theoretically from that angle.  At optimum flowrate, operation time and initial iodine value (IV), the best results were observed at 28ºC of coolant temperature where high IV of olein and effective partition constant (K) obtained were 55.8 wijs and 0.27 respectively. Meanwhile, the highest U obtained at coolant temperature 28oC same as result for process efficiency at 392.9183 W/m².K and time at 55 min.

References

Morad, N. A., M. K. Abdul Aziz, and R. Mohd Zin. 2006. Process Design in Degumming and Bleaching Of Palm Oil. Universiti Teknologi Malaysia.

Hamm, W. Fractionation Technology. [Online]. United Kingdom.

Sánchez, J., Y. Ruiz, J. M. Auleda, E. Hernández, and M. Raventós. 2009. Review: Freeze Concentration in the Fruit Juices Industry. Journal of Food Science and. Technology International. 15: 303–315.

Aider, M., and D. de Halleux. 2009. Cryoconcentration Technology in the Bio-Food Industry: Principles and Applications. Journal of Food Science and. Technology. 42: 679–685.

Matthews, J. S., and N. D. Coggeshall. 1959. Concentration of Impurities from Organic Compounds By Progressive Freezing. Journal of Analytical Chemistry. 31: 1124–1125.

Sánchez, J., E. Hernández, J. M. Auleda, and M. Raventós. 2011. Freeze Concentration of Whey in a Falling-Film Based Pilot Plant: Process and Characterization. Journal of Food Engineering. 103: 147–155.

Qin, F., Chen, X. D., Ramachandra, S. and Free, K. 2006. Heat Transfer and Power Consumption in a Scraped-Surface Heat Exchanger While Freezing Aqueous Solutions. Separation and Purification Technology. 48(2): 150–158.

Siew, W. L., and W. L. Ng. 1995. Partition Coefficient of Diglycerides in Crystallization of Palm Oil. Journal of the American Oil Chemists' Society. 72: 591–595.

Incorporated, G. W. Iodine Value with Model 412 [Online]. From http://www.guided-wave.com/support/notes/, [Accessed 9 May 2011].

Karabulut, I., S. Turan, and G. Ergin. 2004. Effect of Chemical Interestification on Solid Fat Content and Slip Melting Point Of Fat/Oil Blend. European Food and Research. Technology. 218: 224–9.

Berger, K., W. L. Siew and F. Oh. 1982. Factors Affecting Slip Melting Point of Palm Oil Products. Journal of the American Oil Chemists' Society. 59: 244–249.

Chong, C. L. 1993. Selected Reading on Palm Oil and Its Uses. Malaysia: Palm Oil Research Institute of Malaysia (PORIM).

Miyawaki, O., L. Liu, K. Nakamura.1998. Effective Partition Constant of Solute between Ice and Liquid Phases in Progressive Freeze-Concentration. Journal Food and Science. 63: 1–3.

Gu, X., T. Suzuki, O. Miyawaki. 2005. Limiting Partition Coefficient in Progressive Freeze Concentration. Journal Food Engineering and Physical Properties. 70: 546–551.

Miyawaki, O., L. Liu, Y. Shirai, S. Sakashita, K. Kagitani. 2005. Tubular Ice System for Scale-up of Progressive Preeze-Concentration, Journal Food Engineering. 69: 107–113.

Ainie, K., W. L. Siew, and Y. A. Tan. 2004. Test Methods-a Compendium of Test on Palm Kernel Products, Fatty Acids, Food Related Products and Others. Selangor: Malaysian Palm Oil Board.

Firestone, D. 2009. Official Method and Recommended Practices of the AOCS. USA.

Rossell, J. B., B. King, and M. J. Downes. 1985. Composition Oil. Journal of the American Oil Chemists' Society. 62: 221–230.

Azmil Haizam, A. T., W. L. Siew, and K. Ainie. 2008. Palm-based Standard Reference Material for Iodine Value and Slip Melting Point. Journal of Analytical Chemistry. 3: 127–133.

Nagendran, B. 1997. Introduction to Production and Processing of Palm Oil. Agrabad Hotel Chittagong: Palm Oil Research Institute of Malaysia (PORIM).

Kawamura, K. 1980. The DSC Thermal Analysis of Crystallization Behavior in Palm Oil II. Journal of the American Oil Chemists' Society. 57: 48–52.

Kawamura, K. 1979. Thermal Analysis of Crystallization Behavior in Palm Oil. Journal of the American Oil Chemists' Society. 56(8): 753–758.

Berger, K. 1989. Crystallization Behavior of Palm Oil. In: Proceeding of the 1989 PORIM International Palm Oil Development Conference 5-9 September 1989, 1989a Kuala Lumpur, Malaysia. Module III, Chemistry, Technology and Marketing. 48–59.

Toyokura, K., I. Hirasawa, K. Wintermantel, and G. Wellinghoff. 1995.Crystallization from the Melt. In Mersmann, A. (Ed.). Crystallization Technology Handbook. Marcel Dekkar Inc. 56–60.

Nakagawa, K., S. Maebashi, K. Maeda, Freeze-thawing as a Path to Concentrate Aqueous Solution. 2010 Journal of Separation and Purification Technology. 73: 403–408.

Chen, P., D.C. Xiao, K.W. Free, Solute Inclusion in Ice Formed From Sucrose Solutions on a Sub-cooled Surface-an Experimental Study. 1998. Journal Food Engineering. 38: 1–13.

Dzulkefly, K., W. M. Wan Rusmawati, W. H. Lim, K. Anuar, and S. Hamdan. 2001. Effect of Monoglycerol Stearate and Free Fatty Acid on the Melting Point of Palm Olein. Malaysia Journal of Analytical Sciences. 7(1): 93–96.

Ozisik, M. N. 1985. Heat Transfer: A Basic Approach. Singapore: McGraw-Hill.

Debnath, S. and K. S. M. S. Raghavarao. 2011. Hydrodynamic, Thermo-Analytical and Molecular Structural Investigations of Enzyme Interesterified Oil and Its Thermo-Oxidative Stability by Thermogravimetric Analysis. Journal of Food Engineering. 105(4): 671–679.

Downloads

Published

2015-06-01

Issue

Section

Science and Engineering

How to Cite

Effect of Coolant Temperature on Progressive Freeze Concentration of Refined, Bleached and Deodorised Palm Oil based on Process Efficiency and Heat Transfer. (2015). Jurnal Teknologi, 74(7). https://doi.org/10.11113/jt.v74.4690