Influence of Hydrophilic Polymer on Proteins Separation, Molecular Weight Cut-off (MWCO) and Average Pore Size of Polysulfone Blend Membrane

Authors

  • Asmadi Ali School of Ocean Engineering Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia
  • Rosli Mohd Yunus Faculty of Chemical and Natural Resources, Universiti Malaysia Pahang, 26300 Gambang, Pahang, Malaysia
  • Mohamad Awang School of Ocean Engineering Universiti Malaysia Terengganu, 21030 Kuala Terengganu, Terengganu, Malaysia
  • Mohd Azizi Che Yunus Centre of Lipid Engineering and Applied Research (CLEAR), Ibnu Sina Insititute for Industrial and Scientific Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v74.4698

Keywords:

CAP, blend membrane, proteins, MWCO, average pore size, pore density

Abstract

The aim of this study is to investigate the influence of different composition of cellulose acetate phtalate (CAP) on the membrane structural properties of polysulfone (PSf) membrane which in turn affect the separation performance of PSf/CAP blend membrane. The PSf/CAP blend membranes were prepared by using casting solutions contain 17 wt% of polymer via wet phase inversion process. The results showed that increasing the composition of CAP in PSf/CAP blend membranes increased molecular weight cut-off (MWCO), average pore size and pore density which then increased protein solution permeate fluxes but reduced proteins rejection of PSf/CAP blend membranes. Pure PSf membranehas the lowest membrane structural properties compared to blend membranes. This characteristic contributed to decrease in protein permeation flux and increase proteins rejection. 

References

Arthanareeswaran, G., Thanikaivelan, P., Jaya, N., Mohan, D., Raajenthiren, M. 2007. Removal of Chromium from Aqueous Solution Using Cellulose Acetate and Sulfonated Poly(Ether Ether Ketone) Blend Ultrafiltration Membranes. Journal of Hazardous Materials B. 139: 44–49.

Bowen, W. R., Doneva, T. A., Yin, H. B. 2001. Polysulfone-sulfonated Poly(Ether Ether) Ketone Blend Membranes: Systematic Synthesis and Characterization. Journal of Membrane Science. 181: 253–263.

Mulder, M. 1996. Basic Principles of Membrane Technology. The Netherlands: Kluwer Academic Publishers.

Rahimpour, A., Madaeni, S. S. 2007. Polyethersulfone (PES)/cellulose Acetate Phthalate (CAP) Blend Ultrafiltration Membranes: Preparation, Morphology, Performance and Antifouling Properties. Journal of Membrane Science. 305: 299–312.

Ding, Y., Bikson, B. 2010. Macro and Meso Porous Polymeric Materials from Miscible Polysulfone/Polyimide Blens by Chemical Decomposition of Polyimides. Polymer. 51: 46–52.

M’Bareck. C., Nguyen, Q. T., Alaoui, O. T., Barillier, D. 2009. Elaboration, Characterization and Application of Polysulfone and Polyacrylic Acid Blends as Ultrafiltration Membranes for Removal of Some Heavy Matals from Water. Journal of Hazardous Materials. 171: 93–101.

Tsai, H. A., Huang, D. H., Fan, S. C., Wang, Y. C., Li, C. L., Lee, K. R., Lai, J. Y. 2002. Investigation of Surfactant Addition on the Vapor Permeation of Aqueous Ethanol Mixtures Through Polysulfone Hollow Fiber Membranes. Journal of Membrane Science. 198: 245–258.

Ai-Lian, L., Qing, C. 1995. Polyacrylonitrilic/polysulfone (PAN/PS) Blend Ultrafiltration (UF) Membranes. Desalination. 101: 51–56.

Nguyen, T. D., Solomon, B. A. 1993. New One-step Process for Preparation of Microporous Composite Polysulfone/Polyurethane Hollow-Fiber Membranes. Desalination. 90: 3–13.

Ali A., Awang, M., Mat, R., Johari, A. Kamaruddin, M.J., Sulaiman, W.R.W. 2014. Influence of Hydrophilic Polymer on Pure Water Flux, Permeability Coefficient, and Porosity of Polysulfone Blend Membranes. Advanced Materials Research. 931–932: 168–172.

Sarbolouki, M. N. 1982. A General Diagram for Estimating Pore Size of Ultrafiltration and Reverse Osmosis Membranes. Separation Science Technology. 17(2): 381–386.

Kimmerle, K., Strathmann, H. 1990. Analysis of the Structure Determining Process of Phase Inversion Membranes. Desalination. 79: 283–302.

Hwang, J. R., Koo, S. H, Kim, J. H., Higuchi, T. M. 1996. Effects of Casting Solution Composition Performance of Poly(Ether Sulfone) Membranes. Journal of Applied Polymer Science. 60: 1343–1348.

Paul, D. R., Barlow, J. M., Keskkula, H. 1989. Polymer Blends. Encyclopedia of Polymer Science and Engineering. Vol. 12. New York: John Wiley and Sons.

Rajesh, S., Maheswari, P., Senthikumar, S., Jayalakshmi, A., Mohan, D. 2011. Preparation and Characterization of Poly(Amide-Imide) Incorporated Cellulose Acetate Membranes for Polymer Enhanced Ultrafiltration of Metal Ions. Chemical Engineering Journal. 171: 33–44.

Kesting, R. E. 1985. Synthetic Polymeric Membranes, In: A Structural Perspective. New York: Wiley.

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Published

2015-06-02

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Section

Science and Engineering

How to Cite

Influence of Hydrophilic Polymer on Proteins Separation, Molecular Weight Cut-off (MWCO) and Average Pore Size of Polysulfone Blend Membrane. (2015). Jurnal Teknologi, 74(7). https://doi.org/10.11113/jt.v74.4698