Numerical Prediction Performance of Kraft Lignin Extraction Using Boundary Breakage Model
DOI:
https://doi.org/10.11113/jt.v74.4701Keywords:
Emulsion liquid membrane, kraft lignin extraction, boundary breakage model, Pulping industryAbstract
This study predicts the performance of kraft lignin extraction using emulsion liquid membrane (ELM) from pulping wastewater using boundary breakage model. The model was developed based on the previous study with some modifications and assumptions. Therefore, in developing kraft lignin extraction model, it will consider emulsion globule approach and the emulsion swelling and breakage during the ELMs process. It was found to be numerically stable and reliable in predicting the behavior of kraft lignin extraction using ELM for long duration of time. MATLAB software was used to predict the performance of ELM on extracting kraft lignin from pulping wastewater based on the model developed. At optimum condition, the simulation prediction result was found to have a small deviation with the experimental data on extraction efficiency.The model was computed with some parameter effects including initial feed concentrations; treat ratio and agitation speed, which demonstrated that the prediction results were in agreement with the theoretical study of ELM. The data instills confidence in the model as a useful prediction model on kraft lignin removal by ELM process in pulping industry.Â
References
Li, S.-N. Sun, F. Xu and R.-C. Sun. 2012. Sequential Solvent Fractionation of Heterogeneous Bamboo Organosolv Lignin for Value-added Application. Separation and Purification Technology. 101: 18–25.
Ali, M. and T.R. Sreekrishnan. 2001. Aquatic Toxicity from Pulp and Paper Mill Effluents: A Review. Advances in Environmental Research. 5: 175–196.
Wang, G. and H. Chen. 2013. Fractionation of Alkali-extracted Lignin from Steam-exploded Stalk by Gradient Acid Precipitation. Separation and Purification Technology. 105: 98–105.
Zaied, M. and N. Bellakhal. 2009. Electrocoagulation Treatment of Black Liquor fFrom Paper Industry. Journal of Hazardous Materials. 163: 995–1000.
Zheng, Y., L.-Y. Chai, Z.-H. Yang, C.-J. Tang, Y.-H. Chen and Y. Shi. 2012. Enhanced Remediation of Black Liquor by Activated Sludge Bioaugmented with a Novel Exogenous Microorganism Culture. Applied Microbiology and Biotechnology. 97: 1–11.
Wallberg, O. and A.-S. Jönsson. 2006. Separation of Lignin in Kraft Cooking Liquor from a Continuous Digester by Ultrafiltration at Temperatures Above 100°C. Desalination. 195: 187–200.
Liu, G., Y. Liu, J. Ni, H. Shi and Y. Qian. 2004. Treatability of Kraft Spent Liquor by Microfiltration and Ultrafiltration. Desalination. 160: 131–141.
Toledano, A., A. GarcÃa, I. Mondragon and J. Labidi. 2010. Lignin Separation and Fractionation by Ultrafiltration. Separation and Purification Technology. 71: 38–43.
Chakravorty, B. and A. S. Srivastava. 1987. Application of Membrane Technologies for Recovery of Water from Pulp and Paper Mill Effluents. Desalination. 67: 363–369.
Luong, N., N. Binh, L. Duong, D. Kim, D.-S. Kim, S. Lee, B. Kim, Y. Lee and J.-D. Nam. 2012. An Eco-friendly and Efficient Route of Lignin Extraction from Black Liquor and a Lignin-based Copolyester Synthesis. Polymer Bulletin. 68: 879–890.
Xian, C. K., N. Othman, N. Harruddin, N. A. Nasruddin and Z. Y. Ooi. 2014. Extraction of Lignosulfonate Using Toa-kerosene-Pvdf in Supported Liquid Membrane Process. Jurnal Teknologi(Sciences and Engineering). 67: 59–63.
Ooi, Z. Y., N. Othman, M. Mohamad and R. Rashid. 2014. Removal Performance of Lignin Compound from Simulated Pulping Wastewater Using Emulsion Liquid Membrane Process. International Journal of Global Warming. 6: 270–283.
Yan, C. N., Othman N. and O. Z. Y. 2014. Prediction of Kraft Lignin Extraction Performance Using Emulsion Liquid Membrane Carrier-Diffusion Model. Jurnal Teknologi. 67: 17–21.
Li, N. N. 1971. Separation of Hydrocarbons by Liquid Membrane Permeation. Industrial & Engineering Chemistry Process Design and Development. 10: 215–221.
Chanukya, B. S. and N. K. Rastogi. 2013. Extraction of Alcohol From Wine and Color Extracts Using Liquid Emulsion Membrane. Separation and Purification Technology. 105: 41–47.
Garavand, F. and A. Madadlou. 2014. Recovery of Phenolic Compounds from Effluents by a Microemulsion Liquid Membrane (mlm) Extractor. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 443: 303–310.
Chuannan, L., X. Zhongpeng, W. Xueying and L. Zhen. 2009. Extraction of p-phenylenediamine from Aqueous Solutions Using Emulsion Liquid Membranes. In 3rd International Conference On Bioinformatics and Biomedical Engineering. Beijing.
Venkatesan, S. and K .M. Meera Sheriffa Begum. 2009. Emulsion Liquid Membrane Pertraction of Benzimidazole Using a Room Temperature Ionic Liquid (rtil) Carrier. Chemical Engineering Journal. 148: 254–262.
Othman, N., S. N. Zailani and N. Mili. 2011. Recovery of Synthetic Dye from Simulated Wastewater Using Emulsion Liquid Membrane Process Containing Tri-Dodecyl Amine as a Mobile Carrier. Journal of Hazardous Materials. 198: 103–112.
Lee, S.C. and K.-S. Hyun. 2010. Development of an Emulsion Liquid Membrane System for Separation of Acetic Acid from Succinic Acid. Journal of Membrane Science. 350: 333–339.
Teresa, M., A. Reis and J. M. R. Carvalho. 1993. Recovery of Zinc from an Industrial Effluent by Emulsion Liquid Membranes. Journal of Membrane Science. 84: 201–211.
Sabry, R., A. Hafez, M. Khedr and A. El-Hassanin. 2007. Removal of Lead by aAn Emulsion Liquid Membrane: Part I. Desalination. 212: 165–175.
Bhowal, A., G. Bhattacharyya, B. Inturu and S. Datta. 2012. Continuous Removal of Hexavalent Chromium by Emulsion Liquid Membrane in a Modified Spray Column. Separation and Purification Technology. 99: 69–76.
Othman, N., H. Mat and M. Goto. 2006. Separation of Silver from Photographic Wastes by Emulsion Liquid Membrane System. Journal of Membrane Science. 282: 171–177.
Othman, N., H. Mat and M. Goto. 2005. Selective Extraction of Silver from Liquid Photographic Waste. Solvent Extraction Research and Development-Japan. 12: 27–34.
Sahoo, G. C. and N. N. Dutta. 1998. Studies on Emulsion Liquid Membrane Extraction of Cephalexin. Journal of Membrane Science. 145: 15–26.
Biscaia Junior, E. C., M. B. Mansur, A. Salum and R. M. Z. Castro. 2001. A Moving Boundary Problem and Orthogonal Collocation in Solving A Dynamic Liquid Surfactant Membrane Model Including Osmosis And Breakage. Brazilian Journal of Chemical Engineering. 18: 1–17.
Othman, N. 2006. Selective Emulsion Liquid Membrane Extraction of Silver from Liquid Phtographic Waste Industries. Universiti Teknologi Malaysia.
Nakashio, F., M. Goto, M. Matsumoto, J. Irie and K. Kondo. 1988. Role of Surfactants in the Behavior of Emulsion Liquid Membranes —Development of New Surfactants. Journal of Membrane Science. 38: 249–260.
Reis, M. T. A. and J. M. R. Carvalho. 2004. Modelling of Zinc Extraction from Sulphate Solutions With Bis(2-Ethylhexyl)Thiophosphoric Acid by Emulsion Liquid Membranes. Journal of Membrane Science. 237: 97–107.
Kumbasar, R. A. and İ. Şahin. 2008. Separation and Concentration of Cobalt from Ammoniacal Solutions Containing Cobalt and Nickel by Emulsion Liquid Membranes Using 5,7-Dibromo-8-Hydroxyquinoline (dbhq). Journal of Membrane Science. 325: 712–718.
Datta, S., P. K. Bhattacharya and N. Verma. 2003. Removal of Aniline from Aqueous Solution in a Mixed Flow Reactor Using Emulsion Liquid Membrane. Journal of Membrane Science. 226: 185–201.
Chakraborty, M., C. Bhattacharya and S. Datta. 2003. Effect of Drop Size Distribution on Mass Transfer Analysis of the Extraction of Nickel(Ii) by Emulsion Liquid Membrane. Colloids and Surfaces A: Physicochemical and Engineering Aspects. 224: 65–74.
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