THE EFFECT OF WATER QUALITY ON REMOVAL OF ACETAMINOPHEN IN SURFACE WATER BY OZONATION PROCESS
DOI:
https://doi.org/10.11113/jt.v74.4853Keywords:
Ozonation, river water, acetaminophenAbstract
The effectiveness of ozone to remove acetaminophen in surface water was studied. The results demonstrated that the removal of acetaminophen in surface water by ozone was achieved less than 30 minutes. Ozonation experiment was conducted with the initial concentration of 3.3 x 10-3 mM acetaminophen and para-cholobenzoic acid was selected as hydroxyl radical probe. The second-order rate constants for the reactions between acetaminophen and ozone have been evaluated in different quality of surface water. Based on the result obtained, ozonewas reducing rapidly in water samples according to the level of water quality. The presence of various organic and inorganic compounds in the water samples, which greatly influence the decomposition of dissolved ozone, hydroxyl exposure and removal of acetaminophen. The rate constants showed the minimum value (7.34 x 10-4 M-1 s-1) in lower water quality and maximum value (4.57 x 10-2 M-1 s-1) in high-quality water.
References
Andreozzi, R., Caprio, V., Marotta, R., & Vogna, D. 2003. Paracetamol Oxidation from Aqueous Solutions by Means of Ozonation and H 2 O 2 / UV System. 37: 993-1004.
Rivera-Utrilla, J., Sánchez-Polo, M., Ferro-GarcÃa, M. Ã., Prados-Joya, G., & Ocampo-Pérez, R. 2013. Pharmaceuticals as Emerging Contaminants and Their Removal from Water. A Review. Chemosphere. 93(7): 1268-87.
Kümmerer, K. 2009. The Presence of Pharmaceuticals in the Environment Due to Human Use-Present Knowledge and Future Challenges. J. Environ. Manage. 90: 2354-2366.
Kolpin, D. W., Furlong, E. T., Meyer, M. T., Thurman, E. M., Zaugg, S. D., Barber, L. B., Buxton, H. T. 2002. Pharmaceuticals, Hormones, and Other Organic Wastewater Contaminants in U.S. Streams, 1999–2000: A National Reconnaissance. Environ. Sci. Technol. 36: 1202-1211.
Yuan, F., Hu, C., Hu, X., Qu, J., Yang, M. 2009. Degradation of Selected Pharmaceuticals in Aqueous Solution with UV and UV/H2O2. Water Res. 43: 1766-1774.
Hai-yan, L. I., Jiu-hui, Q. U., & Hui-juan, L. I. U. 2007. Decomposition of Alachlor by Ozonation and its Mechanism. 19: 769-775.
Cho, M., Chung, H., & Yoon, J. 2003. Disinfection of Water Containing Natural Organic Matter by Using Ozone-Initiated Radical Reactions. 69(4): 2284-2291.
Hoigné J, Bader H. 1983a. Rate Constants of Reaction of Ozone with Organic and Inorganic Compounds in Water I. Non-Dissociating Organic Compounds. Water Res. 17: 173-183.
Elovitz, M.; von Gunten, U. 1999. Hydroxyl Radical/ozone Ratio During Ozonation Process I. The Rct Concept. Ozone Sci. Eng. 21: 239-260.
Haag, W., Yao, C. 1992. Rate Constants for Reaction of Hydroxyl Radicals with Several Drinking Water Contaminants. Environ. Sci. Technol. 26: 1005-1013.
von Gunten, U. 2003. Ozonation of Drinking Water: Part I. Oxidation Kinetics and Product Formation. Water Research. 37(7): 1443e1467.
Broséus, R., Vincent, S., Aboulfadl, K., Daneshvar, A., & Sauve, S. 2009. Ozone Oxidation of Pharmaceuticals, Endocrine Disruptors and Pesticides During Drinking Water Treatment. 43: 4707-4717.
Hoigné J. 1998 Chemistry of Aqueous Ozone, and Transformation of Pollutants by Ozonation and Advanced Oxidation Processes. In: J. Hubrec, editor. The Handbook of Environmental Chemistry Quality and Treatment of Drinking Water. Berlin: Springer.
Stettler, R., Courbat, R., von Gunten, U., Kaiser, H-P., Walther, J-L., Gaille, P., Jordan, R., Ramseier, S., Revelly, P. 1998. Utilisation de l’ozone pour le traitement des eaux potables en Suisse. Gas Wasser Abwasser. 78: 76-890.
Clesceri, L. S., Greenbery, A. E., & Eaton, A. D. 1998. Standard Methods for the Examination of Water and Wastewater. 20th ed.
Staehelin, J., Hoigné, J. 1985. Decomposition of Ozone in Water in the Presence of Organic Solutes Acting as Promoters and Inhibitors of Radical Chain Reactions. Environ. Sci. Technol. 19(12): 1206-1213.
Park, H.-S. 2001. Characterization of Raw Water For the Ozone Application Measuring Ozone Consumption Rate. 35(11): 2607-2614.
Hoigne, J., & Staehelld, J. 1985. Decomposition of Ozone in Water in the Presence of Organic Solutes Acting as Promoters and Inhibitors of Radical Chain Reactionst. 19(12): 1206-1213.
Elovitz, M., von Gunten, U. 1999. Hydroxyl Radical/Ozone Ratio During Ozonation Process I. The Rct Concept. Ozone Sci. Eng. 21: 239-260.
Acero, J. L., von Gunten, U. 2001. Characterization of Oxidation Processes: Ozonation and the AOP O3/H2O2. J. Am. Water Works Ass. 93(10): 90-100.
Buffle, M. O.; Schumacher, J.; Salhi, E.; Jekel, M.; von Gunten, U., 2006: Measurement of the Initial Phase of Ozone Decomposition in Water and Wastewater by Means of a Continuous Quench-flow System: Application to Disinfection and Pharmaceutical Oxidation. Water Res. 40(9): 1884-1894.
Elovitz, M., Von Gunten, U., Kaiser, H. P. 2000. Hydroxyl Radical/Ozone Ratio During Ozonation Processes. II the Effect of Temperature, Ph, Alkalinity and DOM Properties. Ozone Sci. Eng. 22: 123-150.
Hoigné, J., Bader, H. 1976. The Role of Hydroxyl Radical Reactions in Ozonation Processes in Aqueous Solutions. Water Res. 10: 377-386.
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