PREPARATION AND CHARACTERIZATION OF ACTIVATED CARBON FROM OIL PALM EMPTY FRUIT BUNCH WASTES USING ZINC CHLORIDE

Authors

  • Riry Wirasnita Institute of Environmental Management and Water Resources (IPASA), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Tony Hadibarata Institute of Environmental Management and Water Resources (IPASA), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Abdull Rahim Mohd Yusoff Institute of Environmental Management and Water Resources (IPASA), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Zainab Mat Lazim Institute of Environmental Management and Water Resources (IPASA), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v74.4876

Keywords:

Activated carbon, chemical activation, oil palm empty fruit bunch, zinc chloride

Abstract

An oil palm empty fruit bunch-derived activated carbon has been successfully produced by chemical activation with zinc chloride and without chemical activation. The preparation was conducted in the tube furnace at 500oC for 1 h. The surface structure and active sites of activated carbons were characterized by means of Fourier transform infrared spectrometry and field emission scanning electron microscopy. The proximate analysis including moisture content, ash content, bulk density, pH, and pH at zero charge was conducted to identify the psychochemical properties of the adsorbent. The results showed that the zinc chloride-activated carbon has better characteristics compared to the carbon without chemical activation.  

References

Çeçen, F., and Aktas, Ö. 2011. Activated Carbon for Water and Wastewater Treatment: Integration of Adsorption and Biological Treatment. John Wiley & Sons.

Ali, I. 2013. Water Treatment by Adsorption Columns: Evaluation at Ground Level. Separation & Purification Reviews. 43: 175-205.

Gupta, V. K., Ali, I., Saleh, T. A., Nayak, A., and Agarwal, S. 2012. Chemical Treatment Technologies for Waste-Water Recycling—An Overview. RSC Advances. 2: 6380-6388.

Ketcha, J., Dina, D., Ngomo, H., and Ndi, N. 2012. Preparation and Characterization of Activated Carbons Obtained from Maize Cobs by Zinc Chloride Activation. American Chemical Science Journal. 2: 136-160.

Ash, B., Satapathy, D., Mukherjee, P., Nanda, B., Gumaste, J., and Mishra, B. 2006. Characterization and application of Activated Carbon Prepared from Waste Coir Pith. Journal of Scientific and Industrial Research. 65: 1008

Sudaryanto, Y., Hartono, S. B., Irawaty, W., Hindarso, H., and Ismadji, S. 2006 High Surface Area Activated Carbon Prepared from Cassava Peel by Chemical Activation. Bioresour Techno.l. 97: 734-739.

Guo, J., Luo, Y., Lua, A. C., Chi, R. a., Chen, Y. l., Bao, X. t., and Xiang, S. x. 2007. Adsorption of Hydrogen Sulphide (H2S) by Activated Carbons Derived from Oil-Palm Shell. Carbon. 45: 330-336.

Kalderis, D., Bethanis, S., Paraskeva, P., and Diamadopoulos, E. 2008. Production of Activated Carbon from Bagasse and Rice Husk by a Single-Stage Chemical Activation Method at Low Retention Times. Bioresour Technol. 99: 6809-6816.

Yalçın, N., and Sevinç, V. 2000. Studies of The Surface Area and Porosity of Activated Carbons Prepared from Rice Husks. Carbon. 38: 1943-1945.

Omar, R., Idris, A., Yunus, R., Khalid, K., and Aida Isma, M. I. 2011. Characterization of Empty Fruit Bunch for Microwave-Assisted Pyrolysis. Fuel. 90: 1536-1544.

Yusoff, S. 2006. Renewable Energy from Palm Oil–Innovation On Effective Utilization of Waste. Journal of Cleaner Production. 14: 87-93.

Abdullah, N., Sulaiman, F., and Gerhauser, H. 2011 Characterisation of Oil Palm Empty Fruit Bunches for Fuel Application. J. Phys. Sci. 22: 1-24.

Mohamed, A. R., Zainudin, N. F., Lee, K. T., and Kamaruddin, A. H. 2006. Reactivity of Absorbent Prepared from Oil Palm Ash for Flue Gas Desulfurization: Effect of SO2 Concentration and Reaction Temperature. In Studies in Surface Science and Catalysis (Hyun-Ku Rhee, I.-S. N., and Jong Moon, P. eds.), Elsevier. 449-452.

Nakagawa, Y., Molina-Sabio, M., and Rodríguez-Reinoso, F. 2007. Modification of the Porous Structure Along the Preparation of Activated Carbon Monoliths with H3PO4 and ZnCl2. Microporous Mesoporous Mater. 103: 29-34.

Al-Qodah, Z., and Shawabkah, R. 2009 Production and Characterization of Granular Activated Carbon from Activated Sludge. Brazilian Journal of Chemical Engineering. 26: 127-136.

Dhayabaran, V., Lydia, I. S., Merlin, J. P., and Sathiyan, A. 2012 Utilization of the Agricultural Wastes for Decolourisation of Congo Red. International Journal of Chemical & Environmental Engineering. 3.

Wirasnita, R., Hadibarata, T., Yusoff, A. R. M., and Yusop, Z. 2014. Removal of Bisphenol a from Aqueous Solution by Activated Carbon Derived from Oil Palm Empty Fruit Bunch. Water Air Soil Pollut. 225 1-12.

Mohanty, K., Das, D., and Biswas, M. N. 2006. Preparation and Characterization of Activated Carbons from Sterculia Alata Nutshell by Chemical Activation with Zinc Chloride to Remove Phenol from Wastewater. Adsorption. 12: 119-132.

Hayashi, J. i., Kazehaya, A., Muroyama, K., and Watkinson, A. P. 2000. Preparation of Activated Carbon from Lignin by Chemical Activation. Carbon. 38: 1873-1878.

Socrates, G. 2004. Infrared and Raman Characteristic Group Frequencies: Tables and Charts. John Wiley & Sons, England.

Bansal, R. C., and Goyal, M. 2005 Activated Carbon Adsorption. Taylor & Francis.

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Published

2015-06-25

How to Cite

PREPARATION AND CHARACTERIZATION OF ACTIVATED CARBON FROM OIL PALM EMPTY FRUIT BUNCH WASTES USING ZINC CHLORIDE. (2015). Jurnal Teknologi, 74(11). https://doi.org/10.11113/jt.v74.4876