EFFECT OF SPUTTERING PRESSURE ON THE STRUCTURAL AND OPTICAL PROPERTIES OF ZNO FILMS DEPOSITED ON FLEXIBLE SUBSTRATE

Authors

  • Lam Mui Li Faculty of Science and Natural Resources, Universiti Malaysia Sabah 88999, Kota Kinabalu, Sabah, Malaysia
  • Azmizam Manie @ Mani Faculty of Science and Natural Resources, Universiti Malaysia Sabah 88999, Kota Kinabalu, Sabah, Malaysia
  • Farah Lyana Shain Faculty of Science and Natural Resources, Universiti Malaysia Sabah 88999, Kota Kinabalu, Sabah, Malaysia
  • Afishah Alias Faculty of Science and Natural Resources, Universiti Malaysia Sabah 88999, Kota Kinabalu, Sabah, Malaysia
  • Saafie Salleh Faculty of Science and Natural Resources, Universiti Malaysia Sabah 88999, Kota Kinabalu, Sabah, Malaysia

DOI:

https://doi.org/10.11113/jt.v75.5171

Keywords:

Zinc Oxide, flexible substrates, RF powered magnetron sputtering

Abstract

Zinc Oxide (ZnO) has get attention because of its excellent optical transmittance approximately ~80%. A systematic study has been made of the effect of sputtering pressure on the structural and optical properties of the deposited ZnO films. ZnO thin films were deposited on plastic substrate by RF powered magnetron sputtering using ZnO disk with 99.99% purity. The RF power of 100 W and argon gas flow from 10 - 30 sccm was used to perform the sputtering process. The argon sputtering pressure was varied between 3 mTorr to 11 mTorr and the growth time is constant at 25 minute. The deposited ZnO thin films are characterized structurally and optically.  Structural analysis using X-Ray Diffraction (XRD) show that all the films exhibit a (002) preferential orientation and the estimated grain size measured was varied from 24.5 nm to 29.8 nm. Surface Profilometer was used to measure the thickness and RMS of the deposited films where the thickness decrease from 900 nm to 600 nm and the root mean square (RMS) roughness increase from 4.97 nm to 11.45 nm. The optical transparency value that achieved from UV-Vis Spectrometer is over 80% in the visible range and the band gap energy is within 3.27 eV-3.29 eV range.

References

Medina-Montes, M. I., Lee, S. H., Perez, M., Baldenegro-Perez, L. A., Quevedo- Lopez, M. A., Gnade, B., and Ramirez-Bon, R. 2011. Effect of Sputtered ZnO Layers on Behavior of Thin-Film Transistors Deposited at Room Temperature in a Nonreactive Atmosphere. Journal of Electronic Materials. 40(6).

Koidis, C., Logothetidis, S., Laskarakis, A., Tsiaoussis, I., and Frangis, N. 2009. Thin Film and Interface Properties During Zno Deposition Onto High-barrier Hybrid/PET Flexible Substrates. Micron. 40: 130-134.

Ondo-Ndong, R., Pascal-Delannoy, F., Boyer, A., Giani, A., and Foucaran, A. 2003. Structural Properties of Zinc Oxide Thin Films Prepared by R.F. Magnetron Sputtering. Materials Science and Engineering. B97: 68-73.

Guillen, C., and Herrero, J. 2010. Optical, Electrical and Structural Characteristics of Al:ZnO Thin Films with Various Thicknesses Deposited by DC Sputtering at Room Temperature and Annealed in Air or Vacuum. Vacuum. 84: 924-929.

Srinivasan, G., and Kumar, J. 2006. Optical and Structural Characterization of Zinc Oxide Thin Films Prepared by Sol-Gel Process. Cryst. Res. Technol. 41: 893-896.

Gumus, C., Ozkendir, O., M Kavak, H., and Ufuktepe, Y. 2006. Structural and Optical Properties of Zinc Oxide Thin Films Prepared by Spray Pyrolysis Method. Journal of Optoelectronics and Advanced Materials. 8(1): 299-303.

Shan, F. K., and Yu, Y. S. 2003. Optical Properties of Pure and Al Doped Zno Thin Films Fabricated with Plasma Produced by Excimer Laser. Thin Solid Films. 435: 174-178.

Hyung, G. W., Park, J., Koo, J. R., Choi, K. M., Kwon, S. J., Cho, E. S., Kim, Y. S., and Kim, Y. K. 2012. ZnO Thin-film Transistors with a Polymeris Gate Insulator Built on a Polyethersulfone Substrate. Solid State Electronics. 69: 27-30.

Fahoume, M., Maghfoul, O., Aggour, M., Hartiti, B., Chraibi, F., and Ennaoni, A. 2006. Growth and Characterization of Zno Thin Films Prepared by Electrodeposition Technique. Sol. Energy Mater. Sol. Cells. 90: 1437-1444.

Terasako, T., Yagi, M., Ishizaki, M., Senda, Y., Matsuura, H., and Shirakata, S. 2007. Growth of Zinc Oxide Films and Nanowires by Atmospheric-Pressure Chemical Vapor Deposition Using Zinc Powder and Water as Source Materials. Surf. Coat. Technol. 201: 8924-8930.

Lin, S. S., and Jow, L. H. 2004. Effect of the Thickness on the Structural and Optical Properties of Zno Films by R.F. Magnetron Sputtering. Surface & Coatings Technology. 185: 222-227.

Kim, J. J., Lee, J. H., Lee, J. Y., Lee, D. J., Jang B. R., and Kim, H. S. 2009. Characteristics of ZnO Films Deposited on Plastic Substrates at Various Rf Sputtering Powers. Journal of the Korean Physical Society. 55(5): 1910-1914.

Lee, J. H. 2009. Effect of Sputtering Pressure and Thickness on Properties of Zno:Al Films Deposited on Polymer Substrates. Journal of Electroceramics. 23: 512-518.

Fernandez, S. and Naranjo, F. B. 2010. Optimization of Aluminium-Doped Zinc Oxide Films Deposited at Low Temperature by Radio-Frequency Sputtering on Flexible Substrates for Solar Cellapplications. Solar Energy Materials and Solar Cells. 94: 157-163.

Wong, F. L., Fung, M. K., Tong, S. W., Lee, C. S., and Lee S. T. 2004. Flexible Organic Light-emitting Device Based on Magnetron Sputtered Indium-Tin-Oxide on Plastic Substrate. Thin Solid Film. 466: 225-230.

Hoon, J. W., Chan, K. Y., Krishnasamy, J., Tou, T. Y., and Knipp D. 2011. Direct Current Magnetron Sputter-deposited Zno Thin Films. Applied Surface Science. 257: 2508-2515.

Hezam, M., Tabet, D., and Mekki, D. 2010. Synthesis and Characterization of DC Magnetron Sputtered Zno Thin Films under high working pressure. Thin Solid Films. 518: e161-e164.

Subba Reddy, R., Sreedhar, A., Sivasankar Reddy A., and Uthanna, S. 2012. Effect of Film Thickness on the Structural Morphological and Optical Properties of Nanocrystalline Zno Films Formed by RF Magnetron Sputtering. Advanced Materials Letters. 3(3): 239-245.

Lai, L. W. and Lee, C. T. 2008. Investigation of Optical and Electrical Properties of Zno Thin Films. Materials Chemistry and Physics. 110: 393-396.

Acosta, M., Riech, I., and Martin-Tovar, E. 2013. Effect of the Argon Pressure on the Optical Band Gap of Zinc Oxide Thin Films Grown by Nonreactive RF Sputtering. Advanced in Condensed Matter Physics. 2013: 1-6.

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Published

2015-08-18

How to Cite

EFFECT OF SPUTTERING PRESSURE ON THE STRUCTURAL AND OPTICAL PROPERTIES OF ZNO FILMS DEPOSITED ON FLEXIBLE SUBSTRATE. (2015). Jurnal Teknologi, 75(7). https://doi.org/10.11113/jt.v75.5171