THERMAL DIFFUSIVITY STUDIES OF ZnO-CuO AT HIGH TEMPERATURES

Authors

  • Rabiatuladawiyah Md Akhir Faculty of Applied Sciences, Universiti Teknologi MARA, Shah Alam, Selangor, Malaysia
  • Zaidan Abd Wahab Faculty of Science, Universiti Putra Malaysia, Serdang, Selangor, Malaysia

DOI:

https://doi.org/10.11113/jt.v76.5505

Keywords:

VZinc oxide, copper oxide, solid state, thermal diffusivity, laser flash analysis

Abstract

An n-type semiconducting oxide such as Zinc Oxide (ZnO) has been exploited for their well-known gas sensing properties. Previous studies on these applications have mainly focused on electrical properties. Only limited reports were available on thermophysical properties of ZnO-based ceramics gas sensor. Therefore in this work, we report on the thermal diffusivity of Zinc Oxide-Copper Oxide (ZnO-CuO) ceramic composites by solid-state method using a laser flash technique. Thermal diffusivity of samples was measured at temperatures between 27 °C to 400 °C. The role of CuO was observed to enhance the thermal diffusivity of ZnO system with respect to the temperatures. ZnO-CuO samples played a significant role in improvement of thermal diffusivity value at temperature of 200 °C and above. Subsequently, sample of higher thermal diffusivity will exhibit lower initialization time for gas sensor to activate. Hence, the enhanced thermal diffusivity suggested that ZnO-CuO composite samples hold a promising possibility in gas sensor application. 

References

Ellmer, K., Klein, A. and Rech, B. 2008. Transparent Conductive Zinc Oxide, Springer, New York.

Oh, B.Y., Jeong, M.C., Moon, T.H., Lee, W. and Myoung, J.M. 2006. Transparent conductive Al-doped ZnO ï¬lms for liquid crystal. Phys. 99.

Huang, J., Dai, Y., Gu, C. and Liu, J. 2013. Preparation of porous flower-like CuO/ZnO nanostructures and analysis of their gas-sensing property. J. of Alloys and Compounds. 575: 115–122.

Zuca, S. T., Terzi, M., Zaharescu, M. and Matiasovski, K. 1991. Effect of Various Oxide Additives on Sintering Capacity and Electrical Conductivtiy of SnO2. J. of Material Science 26: 1673-1676.

Humaidi, S. 2000. The Sensitivity of Ceramic Gas Sensor Based on SnO2-Nb2O5-CuO System. Msc. Thesis, Universiti Teknologi Malaysia.

Nikodemski, S., Tong , J. and O'Hayre , R. 2013. Solid-state reactive sintering mechanism for proton conducting ceramics. Solid State Ionics. 253: 201-210.

Behzad, K., Yunus, W.M.M., Talib, Z. A., Zakaria A. and Bahrami, A. 2012. Preparation And Thermal Characterization Of Annealed Gold Coated Porous Silicon. J. Materials. 5: 158-168.

Srinivasan, R., Jayachandran, M. and Ramachandran, K. 2007. Photoacoustic studies on optical and thermal properties of p-type and n-type nanostructured porous silicon for (100) and (111) orientations. Cryst. Res. Technol. 42: 266–274.

Zou, J. and Balandin, A. 2001. Phonon heat conduction in a semiconductor nanowire. J. Appl. Phys. 89: 2932–2938.

Sondergaard, M., Espe, D., Kasper, B. A., Christensen, B. S., Christensen, M. and Iversen, B. B. 2013. Sintering and annealing effects on ZnO microstructure and thermoelectric properties. Acta Materialia. 61: 3314-3323

Downloads

Published

2015-09-14

How to Cite

THERMAL DIFFUSIVITY STUDIES OF ZnO-CuO AT HIGH TEMPERATURES. (2015). Jurnal Teknologi (Sciences & Engineering), 76(3). https://doi.org/10.11113/jt.v76.5505