THE INFLUENCE OF NI-TI RATIO ON THE REVERSIBLE AUSTENITE-MARTENSITE TRANSFORMATION AND MECHANICAL PROPERTIES PRODUCED BY METAL INJECTION MOULDING

Authors

  • Rosliza Razali Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam Selangor, Malaysia
  • Zulaila Abdullah Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam Selangor, Malaysia
  • Istikamah Subuki Faculty of Chemical Engineering, Universiti Teknologi MARA, 40450 Shah Alam Selangor, Malaysia
  • Norhamidi Muhamad Faculty of Engineering & Built Environment, Universiti Kebangsaan Malaysia, 43600, Bangi Selangor, Malaysia
  • Muhammad Hussain Ismail Centre for Advanced Materials Research (CAMAR), Faculty of Mechanical Engineering, MARA, 40450 Shah Alam Selangor, Malaysia

DOI:

https://doi.org/10.11113/jt.v76.5799

Keywords:

Metal injection moulding, austenite-martensite, elemental, NiTi alloy

Abstract

This paper highlights the influence of Ni-Ti ratio on the phase constituents, the reversible austenite-martensite transformation and mechanical properties produced by metal injection molding (MIM). The binder system used was mainly palm stearin with minor fraction of polyethylene. Injection moulding was done successfully at 130˚C to form tensile shape samples. It was followed by solvent extraction,  thermal debinding at 500oC and subsequently sintered in high vacuum at 1100˚C. The result showed that as the Ni content increased, the fraction of austenite phase also increased owing to greater fraction of transient liquid phase formation during the sintering, thus improved the mechanical tensile properties. However, the reversible austenite to martensite phase transformation temperatures (PTTs) seemed to be broadened with increased Ni content due to formation of metastable R-phase.

References

Fuentes, J. S. J. M. G. and Gümpel, P. 2002. Phase Change Behavior of Nitinol Shape Memory Alloys Influence of Heat and Thermomechanical Treatments. Advanced Engineering Materials. 7: 437–451.

Fatiha, B., Feninat, E., Laroche, G., Fiset, M. and Mantovani, D. 2002. Shape Memory Materials for Biomedical Applications. Advanced Engineering Materials. 3: 91–104.

Schöller, E., Krone, L. Bram, M., Buchkremer, H. P. and Ståaver, D. 2005. Metal Injection Molding Of Shape Memory Alloys Using Prealloyed Niti Powders. Journal of Materials Science. 40: 4231–4238.

Bhaumik, S. K. 2011. Nickel-Titanium Base Shape Memory Alloys ( SMAs ): Smart Metallic Materials,†in 6th Symposium on National Frontiers of Engineering.

Thompson, S. A. 2000. An Overview Of Nickel-Titanium Alloys Used In Dentistry. International Endodontic Journal. 33(4): 297 - 310.

Machado, L. G. and Savi, M. A. 2003. Medical Applications Of Shape Memory Alloy. Brazilian Journal of Medical and Biological Research. 36: 683-691.

Pelton, A., Russell, S. and DiCello, J. 2003. The Physical Metallurgy Of Nitinol For Medical Applications. Journal of the Minerals, Metals and Materials Society. 55(5): 33-37.

Elahinia, M. H., Hashemi, M., Tabesh, M. and Bhaduri, S. B. 2012. Manufacturing And Processing Of Niti Implants: A Review. Progress in Materials Science. 57(5): 911–946.

Yen, F.-C., Hwang, K.-S., Wu, S.-K. and Wu, S.-H. 2011.TiNi Shape Memory Alloys with High Sintered Densities and Well-Defined Martensitic Transformation Behavior. Metallurgical and Materials Transaction A. 42 (8): 2431–2441.

Razali, R., Abdullah, Z., Subuki, I., Ismail, M. H. and Muhamad, N. 2014. Feedstock Characterization of Elemental Nickel and Titanium Powders Mixture for Metal Injection Moulding Process. Applied Mechanics and Materials. 575: 78 - 82.

Azuddin, M., Choudhury, I. A. and Taha, Z. 2012. Development And Performance Evaluation Of A Low-Cost Custom-Made Vertical Injection Molding Machine. J. Braz. Soc. Mech. Sci. Eng.1-8.

Ismail, M. H. 2012. Porous Niti Alloy By Metal Injection Moulding (MIM) Using Partly Water Soluble Binder System. University of Sheffield, PhD Dissertation.

Su P. C. and Wu S. K. 2004. The Four-Step Multiple Stage Transformation In Deformed And Annealed Ti49Ni51 Shape Memory Alloy. Acta Materialia. 52: 1117.

Shugo Y., Hanada S. and Honma T.1985. Bull. Res. Inst. Min. Dress. Metall. 41: 35.

Ismail, M. H., Goodall, R. Davies, H. A. and Todd, I. 2012. Formation Of Microporous Niti By Transient Liquid Phase Sintering Of Elemental Powders. Materials Science and Engineering C. 32(6): 1480–1485.

Whitney, W. Corbin, S. F. and Gorbet, R. B. 2009. Investigation Of The Influence Of Ni Powder Size On Microstructural Evolution And The Thermal Explosion Combustion Synthesis Of Niti. Intermetallics. 17(11): 894–906

Köhl M., Habijan T., Bram M, Buchkremer H. P., Stöver D. and Köller M. 2009. Powder Metallurgical Near-Net-Shape Fabrication of Porous NiTi Shape Memory Alloys for Use as Long-Term Implants by the Combination of the Metal Injection Molding Process with the Space-Holder Technique. 11: 959.

Yuan, B., Chung, C. Y. and Zhu, M. 2004. Microstructure And Martensitic Transformation Behavior Of Porous Niti Shape Memory Alloy Prepared By Hot Isostatic Pressing Processing. Materials Science and Engineering A. 382(1–2): 181–187.

Lagoudas, Dimitris C., Vandygriff and Eric L. 2002. Processing and Characterization of NiTi Porous SMA by Elevated Pressure Sintering. Journal of Intelligent Materials Systems and Structures. 13: 837-850.

Downloads

Published

2015-10-11

How to Cite

THE INFLUENCE OF NI-TI RATIO ON THE REVERSIBLE AUSTENITE-MARTENSITE TRANSFORMATION AND MECHANICAL PROPERTIES PRODUCED BY METAL INJECTION MOULDING. (2015). Jurnal Teknologi, 76(10). https://doi.org/10.11113/jt.v76.5799