IDENTIFICATION OF ODOR COMPONENTS OF AGARWOOD

Authors

  • Nor Azah Mohamad Ali Herbal Product Development Programme, Natural Products Division, Forest Research Institute Malaysia, 52109 Kepong, Selangor, Malaysia
  • Nurlaila Ismail Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
  • Mailina Jamil Herbal Product Development Programme, Natural Products Division, Forest Research Institute Malaysia, 52109 Kepong, Selangor, Malaysia
  • Azrina Aziz Herbal Product Development Programme, Natural Products Division, Forest Research Institute Malaysia, 52109 Kepong, Selangor, Malaysia
  • Sahrim Lias Herbal Product Development Programme, Natural Products Division, Forest Research Institute Malaysia, 52109 Kepong, Selangor, Malaysia
  • Mohd Hezri Fazalul Rahiman Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia
  • Mohd Nasir Taib Faculty of Electrical Engineering, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia

DOI:

https://doi.org/10.11113/jt.v77.5986

Keywords:

Agarwood, chemical constituents, HS-SPME-GCMS, Z-score

Abstract

This article presents the use of Z-score in assessing the significant chemical compounds extracted by head space solid phase microextraction (HS-SPME) and gas chromatography – mass spectrometry (GC-MS) analysis of an agarwood oil obtained from Melaka, Malaysia. Two types of SPME fiber; polydimethylsiloxane (PDMS) and divinylbenzene-carboxen-polydimethylsiloxane (DVB-CAR-PDMS) were used. During the extraction analysis, the results showed that at least 27 and 29 compounds were identified using PDMS and DVB-CAR-PDMS fiber, respectively. DVB-CAR-PDMS fiber was found to be more efficient in terms of selectivity of compounds extraction. The application of Z-score showed that eight and eleven marker compounds were determined in PDMS and DVB-CAR-PDMS fibers, respectively. 4-Phenyl-2-butanone, a-guaiene, β-agarofuran, a-bulnesene, a-agarofuran and 10-epi-g-eudesmol were some of the compounds selected and were often reported significantly in agarwood oils as key odor compounds. The information gathered will be used for compound selection towards grading of agarwood oils by sensor technology.

References

Ishihara, M., Tsuneya, T., Shiga, M. and Uneyama, K. 1991. Three Sesquiterpenes from Agarwood. Phytochemistry. 30: 563-566.

Pornpunyapat, J., Chetpattananondh, P. and Tongurai, C. 2011. Mathematical Modeling for Extraction of Essential Oil from Aquilaria crassna by Hydrodistillation and Quality of Agarwood Oil. Bangladesh Journal of Pharmacology. 6: 18-24.

Naef, R. 2011. The Volatile and Semi-Volatile Constituents of Agarwood, The Infected Heartwood of Aquilaria Species: A Review. Flavour and Fragrance Journal. 26: 73-87.

Tajuddin, S. N. and Yusoff, M. M. 2010. Chemical Composition of Volatile Oils of Aquilaria malaccensis (Thymeleaceae) from Malaysia. Natural Product Communications. 5: 1965-1968.

Nor Azah, M. A., Majid, J. A., Mailina, J., Said, A. A., Husni, S. S., Hasnida, H. N., Arip, M. A. M. N. M. and Chang, Y. S. 2009. Profiles of Selected Supreme Agarwood oils from Malaysia. Herbal Globalisation: A New Paradigm for Malaysian Herbal Industry (MAPS 2008). 393-398.

Pripdeevech, P., Khummueng, W. and Park, S. K. 2011. Identification of Odor-active Components of Agarwood Essential Oils from Thailand by Solid Phase Microextraction-GC/MS and GC-O. Journal of Essential Oil Research. 23: 46-53.

Mei, W. L., Yang, D. L., Wang, H., Yang, J. L., Zeng, Y. B., Guo, Z. L., Dong, W. H. and Dai, H. F. 2013. Characterisation and Determination of 2-(2-phenyllethyl) Chromones in Agarwood by GC-MS. Molecules. 18: 12324-12345.

Nor Azah, M. A., Nurlaila, I., Mailina, J., Mohd. Nasir, T. and Mohd Hezri, F.R. 2012. Analysis of Aroma Compounds from Gaharu Oil by Head-space Solid Phase Microextraction and Gas Chromatography-Mass Spectrometry. In Proceedings of Seminar on Medicinal and Aromatic Plants (MAPS-13). 25-26 September.

Jirovetz, G., Buchbauer, M. B., Ngassoum, and Geissler, M. 2002. Aroma Compound Analysis of Piper Nigrum and Piper Guineense Essential Oils from Cameroon Using Solid-Phase Microextraction–Gas Chromatography, Solid-Phase Microextraction–Gas Chromatography–Mass Spectrometry and Olfactometry. Journal of Chromatography. 976: 265-275.

Lias, S., Sulaiman, N., Murat, Z. H. and Taib, M. N. 2010. IQ Index using Alpha-Beta Correlation of EEG Power Spectrum Density (PSD). 2010 IEEE Symposium on Industrial Electronics & Applications (ISIEA). 612-616.

Thatcher, R. W., Biver, C. J. and North, D. M. 2004. Z-Score EEG Biofeedback: Technical Foundations. Applied Neuro sciences Inc.

Downloads

Published

2015-10-28

How to Cite

IDENTIFICATION OF ODOR COMPONENTS OF AGARWOOD. (2015). Jurnal Teknologi (Sciences & Engineering), 77(2). https://doi.org/10.11113/jt.v77.5986