IDENTIFICATION OF ODOR COMPONENTS OF AGARWOOD
DOI:
https://doi.org/10.11113/jt.v77.5986Keywords:
Agarwood, chemical constituents, HS-SPME-GCMS, Z-scoreAbstract
This article presents the use of Z-score in assessing the significant chemical compounds extracted by head space solid phase microextraction (HS-SPME) and gas chromatography – mass spectrometry (GC-MS) analysis of an agarwood oil obtained from Melaka, Malaysia. Two types of SPME fiber; polydimethylsiloxane (PDMS) and divinylbenzene-carboxen-polydimethylsiloxane (DVB-CAR-PDMS) were used. During the extraction analysis, the results showed that at least 27 and 29 compounds were identified using PDMS and DVB-CAR-PDMS fiber, respectively. DVB-CAR-PDMS fiber was found to be more efficient in terms of selectivity of compounds extraction. The application of Z-score showed that eight and eleven marker compounds were determined in PDMS and DVB-CAR-PDMS fibers, respectively. 4-Phenyl-2-butanone, a-guaiene, β-agarofuran, a-bulnesene, a-agarofuran and 10-epi-g-eudesmol were some of the compounds selected and were often reported significantly in agarwood oils as key odor compounds. The information gathered will be used for compound selection towards grading of agarwood oils by sensor technology.
References
Ishihara, M., Tsuneya, T., Shiga, M. and Uneyama, K. 1991. Three Sesquiterpenes from Agarwood. Phytochemistry. 30: 563-566.
Pornpunyapat, J., Chetpattananondh, P. and Tongurai, C. 2011. Mathematical Modeling for Extraction of Essential Oil from Aquilaria crassna by Hydrodistillation and Quality of Agarwood Oil. Bangladesh Journal of Pharmacology. 6: 18-24.
Naef, R. 2011. The Volatile and Semi-Volatile Constituents of Agarwood, The Infected Heartwood of Aquilaria Species: A Review. Flavour and Fragrance Journal. 26: 73-87.
Tajuddin, S. N. and Yusoff, M. M. 2010. Chemical Composition of Volatile Oils of Aquilaria malaccensis (Thymeleaceae) from Malaysia. Natural Product Communications. 5: 1965-1968.
Nor Azah, M. A., Majid, J. A., Mailina, J., Said, A. A., Husni, S. S., Hasnida, H. N., Arip, M. A. M. N. M. and Chang, Y. S. 2009. Profiles of Selected Supreme Agarwood oils from Malaysia. Herbal Globalisation: A New Paradigm for Malaysian Herbal Industry (MAPS 2008). 393-398.
Pripdeevech, P., Khummueng, W. and Park, S. K. 2011. Identification of Odor-active Components of Agarwood Essential Oils from Thailand by Solid Phase Microextraction-GC/MS and GC-O. Journal of Essential Oil Research. 23: 46-53.
Mei, W. L., Yang, D. L., Wang, H., Yang, J. L., Zeng, Y. B., Guo, Z. L., Dong, W. H. and Dai, H. F. 2013. Characterisation and Determination of 2-(2-phenyllethyl) Chromones in Agarwood by GC-MS. Molecules. 18: 12324-12345.
Nor Azah, M. A., Nurlaila, I., Mailina, J., Mohd. Nasir, T. and Mohd Hezri, F.R. 2012. Analysis of Aroma Compounds from Gaharu Oil by Head-space Solid Phase Microextraction and Gas Chromatography-Mass Spectrometry. In Proceedings of Seminar on Medicinal and Aromatic Plants (MAPS-13). 25-26 September.
Jirovetz, G., Buchbauer, M. B., Ngassoum, and Geissler, M. 2002. Aroma Compound Analysis of Piper Nigrum and Piper Guineense Essential Oils from Cameroon Using Solid-Phase Microextraction–Gas Chromatography, Solid-Phase Microextraction–Gas Chromatography–Mass Spectrometry and Olfactometry. Journal of Chromatography. 976: 265-275.
Lias, S., Sulaiman, N., Murat, Z. H. and Taib, M. N. 2010. IQ Index using Alpha-Beta Correlation of EEG Power Spectrum Density (PSD). 2010 IEEE Symposium on Industrial Electronics & Applications (ISIEA). 612-616.
Thatcher, R. W., Biver, C. J. and North, D. M. 2004. Z-Score EEG Biofeedback: Technical Foundations. Applied Neuro sciences Inc.
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.