The Acid - Catalysed Hydrolysis Of Sulphinate Esters

Abstract

Hidrolisis berbagai ester sulfinat dalam larutan berair asid galian telah dikaji secara kinetik. Analisis data kinetik yang diperolehi mengikut kaedah Dunnett dan Bunnett-Olsen dan entropi keaktifan menunjukkan bahawa hidrolisis berlaku mengikut mekanisma A-2. The hydrolysis of substituted sulphinate esters in aqueous mineral acids have been kinetically studied. Analysis of the kinetic data by Dunnett and Bunnett-Olsen criteria and by entropy of activation suggest that the hydrolysis proceed with an A-2 mechanism.