CAPTURING GREENHOUSE GAS CARBON DIOXIDE TO FORM CARBONATE COMPOUNDS
DOI:
https://doi.org/10.11113/jt.v77.7015Keywords:
CO2 capture, nanoparticles, thermodynamic consideration, physical and chemical interactions, carbonatesAbstract
The application of CuO and MgO nanoparticles in CO2 capture was evaluated experimentally using 5% CO2 in nitrogen via physisorption and chemisorption instrumentation. The structural and surface micrograph of the CuO and MgO nanoparticles were characterized by XRD and TEM, respectively. After CO2 capture by the CuO nanoparticles, the amounts of oxide, hydroxide, and carbonate phases in the adsorbents were determined by XPS measurements. No hydroxide phase was detected in the MgO nanoparticles because of the efficient transformation of MgO into MgCO3. Monolayer adsorptions of CO2 were shown to occur in the MgO nanoparticles with a total chemisorption of 5.0 mmol/g. After the fifth cycle, only 3% reduction of the CO2 chemisorption was reported because of some agglomeration by sintering during desorption.
References
Stewart, C. and M. Hessami. 2005. A Study Of Methods Of CO2 Capture And Sequestration - The Sustainability Of A Photosyntetic Bioreactor Approach. Energy Conversion & Management. 46: 403-420.
Yang, H. Q., Z. H. Xu., M. H. Fan., R. Gupta., R. B. Slimane., A. E. Bland, and I. Wright. 2008. Progress in CO2 Separation And Capture: A Review. Journal of Environmental Science. 20: 14-27.
The Annual Energy Outlook 2013 (AEO2013) was prepared by the U.S. Energy Information Administration (EIA). April 2013.
Isahak, W. N. R. W., M. W. M. Hisham., M. A. Yarmo and Y. H. Taufiq-Yap. 2012. A Review On Bio-Oil Production From Biomass By Using Pyrolysis Method. Renewable & Sustainable Energy Reviews. 16: 5910-5923.
Ramesh, T., S. Su., X. X. Yu., and J. S. Bae. 2013. Application Of Carbon Fibre Composites To CO2 Capture From Flue Gas. International Journal of Greenhouse Gas Control. 13: 191-200.
Isahak, W. N. R. W., M. W. M. Hisham, and M. A. Yarmo. 2013. Highly Porous Carbon Materials From Biomass By Chemical And Carbonization Method: A Comparison Study. Journal of Chemistry. Article ID 620346, 1-6.
Isahak, W. N. R. W., N. Hamzah., N. A. M. Nordin., M. W. M. Hisham, and M. A. Yarmo. 2013. Dehydration Studies Of Biomass Resources For Activated Carbon Production Using BET And XRD Techniques. Advanced Materials Research. 620: 491-495.
Han, K. K., Y. Zhou., Y. Chun, and J. H. Zhu. 2012. Efficient MgO-Based Mesoporous CO2 Trapper And Its Performance At High Temperature. Journal of Hazardous Materials. 203: 341-347.
Almazà n-Almazà n, M. C., J. I. Paredes., M. Perez-Mendoza., M. Domingo-Garcia., I. Fernandez-Morales., A. Martinez-Alonso and F. J. Lopez-Garzon. 2006. Surface Characteristics Of Activated Carbon Obtained By Pyrolysis Of Plasma Pretreated PET. Journal of Physical Chemistry B. 110: 11327-11332.
Park, S. J. 1999. In: Hsu, J.P., Editor. Interfacial Forces And Fields: Theory And Applications. New York: MARCEL Dekker.
S Lee, S. C., B. Y. Choi., T. J. Lee., C. K. Ryu., Y. S. Ahn, and J. C. Kim. 2006. CO2 Absorption And Regeneration Of Alkali Metal-Based Solid Sorbents. Catalysis Today. 111: 385-390.
Lee, S. C., H. J. Chae., S. J. Lee., B. Y. Choi., C. K. Yi., J. B. Lee, C. K. Ryu, and J. C. Kim. 2008. Development Of Regenerable MgO-Based Sorbent Promoted With K2CO3 For CO2 Capture At Low Temperatures. Environmental Science and Technology. 42: 2736-2741.
Baltrusaitis, J., J. Schuttlefield., E. Zeitler, and V. H. Grassian. 2011. Carbon Dioxide Adsorption On Oxide Nanoparticle Surfaces. Chemical Engineering Journal. 170: 471-481.
Abid, H.R., J. Shang., H. M. Ang, and S. Wang. 2013. Amino-Functionalized Zr-MOF Nanoparticles For Adsorption Of CO2 and CH4. International Journal of Smart Nano Materials. 4(1): 72-82.
Baltrusaitis, J. and V. H. Grassian. 2005. Surface Reactions Of Carbon Dioxide At The Adsorbed Water-Iron Oxide Interface. Journal of Physical Chemistry B. 109: 12227-12230.
Kim, B. J., K. S. Cho, and S. J. Park. 2010. Copper Oxide-Decorated Porous Carbons For Carbon Dioxide Adsorption Behaviors. Journal of Colloid Interface Science. 342: 575-578.
Isahak, W. N. R. W., Z. A. C. Ramli., M. W. Ismail., K. Ismail., M. R. Yusop., M. W. M. Hisham, and M. A. Yarmo. 2013. Adsorption-Desorption Of CO2 On Different Type Of Copper Oxides Surfaces: Physical And Chemical Attractions Studies. Journal of CO2 Utilization. 2: 8-15.
Wagman, D. D., W. H. Evans, V. B. Parker, R. H. Schumm, I. Halow, S. M. Bailey, K. L. Churney, R. L. Nutall, 1989. The NBS Tables of Chemical Thermodynamic Properties Selected Values For Inorganic And C1 C2 Organic Substance In SI Units. Journal of Physical Chemistry Reference Data. 18: 1807.
Isahak, W. N. R. W., Z. A. C. Ramli., M. W. M. Hisham, and M. A. Yarmo. 2013. Magnesium Oxide Nanoparticles On Green Activated Carbon As Efficient CO2 Adsorbent. AIP Conference Proceedings. 1571: 882-887.
Isahak, W. N. R. W., M. Ismail., J. M. Jahim., J. Salimon, and M. A. Yarmo. 2012. Characterisation And Performance Of Three Promising Heterogeneous Catalysts In Transesterification Of Palm Oil. Chemical Papers. 66: 179-187.
Isahak, W. N. R. W., M. Ismail., N. M. Nordin., N. F. Adnan., J. M. Jahim., J. Salimon, and M. A. Yarmo. 2012. Selective Synthesis Of Glycerol Monoester With Heteropoly Acid As A New Catalyst. Advanced Materials Research. 545: 373-378.
Freund, H. J. and M. W. Roberts. 1996. Surface chemistry of carbon dioxide. Surface Science Reports. 25: 225-273.
Kuhlenbeck, H., C. Xu., B. Dillmann., M. Habel., B. Adam., D. Ehrlich., S. Wohlrab., H. J. Freund., U. A. Ditzinger., H. Neddermeyer., M. Neumann, and M. Neuber. 1992. Adsorption And Reaction On Oxide Surfaces: CO and CO2 On Cr2O3 (111). Berichte der Bunsengesellschaft für Physikalische Chemie. 96: 15-27.
Atkins, P., & De Paula, P. 2010. Atkins Physical Chemistry. 9th edition. Freeman, W.H. and Company. Oxford University Press, New York.
Bhagiyalakshmi, M., Ji, Y. L., & Hyun, T. J. 2010. Synthesis Of Mesoporous Magnesium Oxide: Its Application To CO2 Chemisorption. International Journal of Greenhouse Gas Control. 4: 51-56.
Ram Reddy, M. K., Xu, Z. P., & Diniz da Costa, J. C. 2008. Influence Of Water On High Temperature CO2 Capture Using Layered Double Hydrocide Derivatives. Industrial and Engineering Chemistry Research. 47: 2630-2635.
Isahak, W.N.R.W., Ramli, Z.A.C., Hisham, M.W.M., Yarmo, M.A. 2015. Renewable and Sustainable Energy Reviews. 47: 93.
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