RADIATION GRAFTED NATURAL FIBRES FUNCTIONALIZED WITH ALKALISED AMINE FOR TRANSESTERIFICATION OF COTTONSEED OIL TO BIODIESEL

Authors

  • Rihab Musaad Moawia Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia.
  • Mohamad Mahmoud Nasef Center for Hydrogen Energy, Institute of Future Energy, Universiti Teknologi Malaysia Kuala Lumpur, Jalan Sultan Yahya Petra (Semarak), 54100 Kuala Lumpur, Malaysia
  • Nor Hasimah Mohamed Radiation Processing Technology Division, Malaysian Nuclear Agency, Kajang, Selangor, Malaysia

DOI:

https://doi.org/10.11113/jt.v78.9571

Keywords:

Radiation induced grafting, flax fibres, glycidylmethacrylate, heterogeneous catalyst, conttonseed oil, biodiesel

Abstract

Poly(glycidyl methacrylate) grafted Linum usitatissimum (flax) fibers functionalized with diethylamine (DEA) groups followed by alkalisation were prepared and used as a heterogeneous catalyst for production of biodiesel. Particularly, the new basic catalyst was used for transesterification of cottonseed oil using different molar ratios with methanol and various reaction temperatures. The gas chromatography analysis was used to confirm the conversion of the cottonseed oil to biodiesel. The transesterification reaction temperature affected the conversion percentage significantly. The highest conversion was obtained at 60 °C. In addition, the oil/methanol ratio in the reaction mixture of 1:33 resulted in the highest conversion ratio reaching about 97 %. These results suggest that the alkaline organic catalyst prepared in this study has a potential for application in biodiesel production.

References

Monlau, F., Sambusiti, C., Barakat, A., Guo, X.M., Latrille, E., Trably, E., Steyer, J. and Carrere, H. 2012. Predic- tive Models

of Biohydrogen and Biomethane Production Based on the Compositional and Structural Features of Lig- nocellulosic Materials. Environmental Science & Technology 46: 12217-12225.

Omer, A. 2011. Energy Environment and Sustainable Development. The IIOAB Journal 2(1): 31-44.

Antolin, G., Tinaut, F.V., Briceno, Y., Castano, V., Perez, C., and Ramrez, A. 2002. Optimization of Biodiesel Production by Sunflower Oil Tansesterification. Bioresource Technology 83: 111–114.

Baxter, J., Bian. Z., Chen. G., Danielson. D., and Dresselhaus, M. 2009. Nanoscale Design to Enable the Revolution in Renewable Energy. Energy and Environmental Science 2(6): 559-588.

Janaun, J. and Ellis, N. 2010. Perspectives on Biodiesel as a Sustainable Fuel. Renewable and Sustainable Energy Reviews 14(4): 1312-1320.

Ebiura, T., Echizen, T., Ishikawa, A., Murai, K., and Baba, T. 2005. Selective Transesterification of Triolein With Methanol to Methyl Oleate and Glycerol using Alumina Loaded with Alkali Metal Salt as A Solid-Base Catalyst. Applied Catalysis A 283:111–5.

Hak, J.K., Kang, B. S., Min, J.K., and Young, M.P. 2004. Transesterification of Vegetable Oil to Biodiesel Using Heterogeneous Base Catalysts. Catalysis Today 93: 315–20.

Madrid, J.F., Ueki, Y. and Seko, N. 2013. Abaca/Polyester Nonwoven Fabric Functionalization for Metal Ion Adsorbent Synthesis Via Electron Beam-Induced Emulsion Grafting. Rad. Phys. Chem. 90: 104-110.

Ting, T.M., Nasef, M.M., and Hashim, K. 2015. Tuning N-methyl-D-glucamine Density in a New Radiation Grafted Poly(vinyl benzyl chloride)/Nylon-6 Fibrous Boron-Selective Adsorbent Using the Response Surface Method. Royal Society of Chemistry Advances 5: 37869–37880.

Ueki, Y., Mohamed, N.H., Seko, N. and Tamada, M. 2011. Rapid Biodiesel Fuel Production Using Novel Fibrous Catalyst Synthesized by Radiation-Induced Graft Polymerization. International Journal of Organic Chemistry 1: 20-25.

Moawia, R., Nasef, M.M., Mohamed, N. and Ripin, A. 2016. Modification of Flax Fibers by Radiation Induced Emulsion Graft Copolymerization of Glycidyl- methacrylate. Radiation Physics and Chemistry 122: 35-42.

Özbay, N., Oktar, N. and Tapan, N. 2008. Esterification of Free Fatty Acids in Waste Cooking Oils (WCO): Role of Ion-Exchange Resins. J. Fuel 87 (10): 1789-1798.

Bala. V.S.S., Thruvengadaravi, K.V., Senthil, P., Kumar, M., Kumar, V.V., Sankar, S.S., Kumar, M.H. and Sivanesan, S. 2012. Removal of Free Fatty Acids in Pongamia Pinnata (Karanja) Oil Using Divinylbenzene-styrene Copolymer Resins for Biodiesel Production. Biomass & Bioenergy. 37: 335-341. [14] Nasef, M M., Alinezhad, S. S., Mat, R. , Shabanzadeh, P., Yusof, R., Zakeri, M. and Farag , H. 2016. Preparation of Alkaline Polymer Catalyst by Radiation Induced Grafting for Transesterification of Triacetin Under Neural Network Optimized Conditions. Journal of Macromolecular Science, 53 (9): 557-565.

Encinar, J.M., González, J.F. and Pardal, A. 2010. Transesterification of Rabseed Oil with Methanol in The Presence of Various Co-Solvents. Third International Symposium on Energy From Biomass and Waste Venice, Italy; 8-11.

Rashid. U., Anwar, F. and Knothe, G. 2009. Evaluation of Biodiesel Obtained From Cottonseed Oil. Fuel Processing Technology. 90 (9): 1157-1163.

Downloads

Published

2016-08-10

How to Cite

RADIATION GRAFTED NATURAL FIBRES FUNCTIONALIZED WITH ALKALISED AMINE FOR TRANSESTERIFICATION OF COTTONSEED OIL TO BIODIESEL. (2016). Jurnal Teknologi, 78(8-3). https://doi.org/10.11113/jt.v78.9571