MICROWAVE ASSISTED K2CO3 PALM SHELL ACTIVATED CARBON AS SORBENT FOR CO2 ADSORPTION APPLICATION

Authors

  • Usman Dadum Hamza Chemical Engineering Department, Abubakar Tafawa Balewa University Bauchi, Bauchi state, Nigeria
  • Noor Shawal Nasri UTM-MPRC Oil and Gas Institute, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Malaysia
  • Nor Aishah Saidina Amin Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Jibril Mohammed Chemical Engineering Department, Abubakar Tafawa Balewa University Bauchi, Bauchi state, Nigeria
  • Husna Mohd Zain UTM-MPRC Oil and Gas Institute, Energy Research Alliance, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Malaysia

DOI:

https://doi.org/10.11113/jt.v78.9576

Keywords:

Palm shell, microwave, activated carbon, CO2 adsorption isotherms

Abstract

Carbon dioxide is believed to be a major greenhouse gas (GHG) that contributes to global warming. In this study, palm shells were used as a precursor to prepare CO2 activated carbon sorbents via carbonization, chemical impregnation with K2CO3 and microwave activation.  Adsorption equilibrium data for CO2 adsorption on the porous carbon were obtained at different temperatures using static volumetric adsorption method. Langmuir, Freundlich, Sips and Toths models were used to correlate the experimental data. The CO2 adsorption capacity at 303.15, 343.15, 378.15 443.15 K and 1 bar on the sorbent was 2.71, 1.5, 0.77, 0.69 mmol/g respectively. Sips isotherm was found to have the best fit. The results indicated that the porous carbon sorbent prepared by carbonization and microwave K2CO3 assisted activation have good CO2 uptake. The porous carbons produced are therefore good candidates for CO2 adsorption applications

References

Lee, C.S. Y.L. Ong, M.K. Aroua, and W.M.AW. Daud. 2013. Impregnation Of Palm Shell- Based Activated Carbon With Sterically Hindered Amines for CO2 Adsorption. Chem. Eng. J. 219: 558-564.

Zaini, N. and K.S. Nor Kamarudin. 2014. Adsorption of Carbon Dioxide on Monoethanolamine (MEA)–Impregnated Kenaf Core Fiber by Pressure Swing Adsorption System (PSA). Jurnal Teknologi (Sciences & Engineering.) 68 (5): 11–16.

Olivares-Marín, M. and M. Maroto-Valer. 2012. Development of Adsorbents for CO2 Capture From Waste Materials: A Review. Greenhouse Gas Sci Technol. 2: 20–35.

Servilla, M. and A.B. Fuertes. 2011. Sustainable Porous Carbons with a Superior Performance for CO2 Capture. Energy and Environmental Science. 4: 1765-1771.

Shafeeyan, M.S. W.M. Wan Daud. A. Houshmand, and A. Shamiri. 2010. Review on Surface Modification of Activated Carbon for Carbon Dioxide Adsorption. Journal of Analytical and Applied Pyrolysis. 89: 143–151.

Su, F. C. Lu, W. Cnen, B. Hsunling, and J.F. Hwang. 2009. Capture of CO2 from Flue Gas via Multiwalled Carbon Nanotubes. Science of the Total Environment. 407: 3017-3023.

Choi, G., S. Oh, S. Lee, J. Kim. 2014. Production Of Bio-Based Phenolic Resin And Activated Carbon From Bio-Oil And Biochar Derived From Fast Pyrolysis Of Palm Kernel Shells. Bioresource Technology. 178: 99-07.

Musa. M., A. Kikuchi, Z. Abdul Majid, J. Jaafar, M. R. Salim. (2014). Activated Carbon Production from Agricultural Biomass Using Response Surface Method (RSM) for Cd (II) Removal. Jurnal Teknologi (Sciences & Engineering.) 69(3): 59–64.

Hamza, D. U., N.S. Nasri, K.A. Abdul, M.M. Ahmed, and M. Jibril. 2012. Modification of Activated Carbon for Enhancement of Gas Contaminant Removal: A Review. 11TH International Annual Symposium on Sustainability Science and Management. UMT, Terengganu, Malaysia, 1336- 1342.

Nasri, N.S., J. Mohammed, M.A.A. Zaini, R. Mohsin, U.D. Hamza, A.A. Musa. 2014. Synthesis and Characterization of Green Porous Carbons with Large Surface Area by Two Step Chemical Activation with KOH. Jurnal Teknologi (Sciences & Engineering). 67(4): 25–28.

Foo, K.Y and B.H. Hameed. 2009. Recent Developments In The Preparation And Regeneration Of Activated Carbons By Microwaves. Advances in Colloid and Interface Science. 149: 19–27.

Sudaryanto, Y., S.B. Hartono, W. Irawaty, H. Hindarso, S. Ismadji. 2006. High Surface Area Activated Carbon Prepared From Cassava Peel By Chemical Activation. Bioresource Technology. 97: 734–739.

Hesas, R.H., A. AramiNiyaa, W.A. Wan Daud, J.N. Sahu. 2013. Comparison of Oil Palm Shell-Based Activated Carbons Produced By Microwave and Conventional Heating Methods Using Zinc Chloride Activation. Journal of Analytical and Applied Pyrolysis. 104: 176–184.

Klm, Y., J. Ahn. 2014. Microwave-Assisted Decolorization and Decomposition Of Methylene Blue With Persulfate. International Biodeterioration & Biodegradation. 95: 208-211.

Wan Daud, W.A., W.S. Wan Ali. 2004. Comparison On Pore Development Of Activated Carbon Produced From Palm Shell And Coconut Shell. Bioresource Technology. 93: 63–69.

Sumathi, S., S. Bhatia, K.T. Lee, A.R. Mohamed. 2009. Optimization of Microporous Palm Shell Activated Carbon Production For Flue Gas Desulphurization: Experimental and Statistical Studies. Bioresource Technology. 100: 1614–1621.

Aktas, O., F. Cecen. 2007. Bioregeneration Of Activated Carbon: A review. International Biodeterioration & Biodegradation. 59: 257–272.

Gupta, V.K., and Suhas. 2009. Application Of Low-Cost Adsorbents for Dye Removal – A review. Journal of Environmental Management. 90: 2313–2342.

Ello, A.S., L.K.C. de Souza, A. Trokourey, and M. Jaroniec. 2013. Development of Microporous Carbons for CO2 Capture by KOH activation of African Palm Shells. Journal of CO2 Utilization. 2: 35–38.

Nasri, N.S., U.D. Hamza, S.N. Ismail, M. M. Ahmed, R. Mohsin. 2014. Assessment of Porous Carbons Derived From Sustainable Palm Solid Waste for Carbon Dioxide Capture. J. Clean. Prod. 71: 148–157.

Foo, K.Y and Hameed B.H., 2012. Textural Porosity, Surface Chemistry and Adsorptive Properties of Durian Shell Derived Activated Carbon Prepared by Microwave Assisted NaOH activation. Chemical Engineering Journal. 187: 53– 62.

Al-Hajjaj, A., B. Zamora, A.A. Shah, E. Reguera, D.V. Bavykin, and F.C. Walsh. 2011. On the Application of Standard Isotherms to Hydrogen Adsorption in Microporous Materials. Inter. Journal of Hydrogen Energy. 36: 14464-14476.

Garnier, C., G. Finqueneisel, T. Zimny, Z. Pokryszka, S. Lafortune, P.D.C. Défossez, E.C. Gaucher. 2011. Selection of Coals of Different Maturities for CO2 Storage by modelling of CH4 and CO2 Adsorption Isotherms. International Journal of Coal Geology. 87: 80–86.

Shahryari, Z., A.S. Goharrizi, and M. Azadi. 2010. Experimental Study of Methylene Blue Adsorption from Aqueous Solutions onto Carbon Nano tubes. International Journal of Water Resources and Environmental Engineering. 2(2): 016-028.

Lua, A.C., F.Y. Lau, J. Guo. 2006. Influence of Pyrolysis Conditions on Pore Development Of Oil-Palm-Shell Activated Carbons. J. Anal. Appl. Pyrolysis. 76: 96–102.

Guo, J. and A.C. Lua. 2002. Characterization of Adsorbent Prepared from Oil-Palm Shell by CO2 Activation for Removal of Gaseous Pollutants. Materials Letters. 55: 334–339.

Hu, Z., M.P. Srinivasan, and Y. Ni. 2001. Novel Activation Process For Preparing Highly Microporous And Mesoporous Activated Carbons. Carbon. 39: 877–886.

Yu-bin, T., L. Qiang, and C. Fang-yan. 2012. Preparation and Characterization Of Activated Carbon From Waste Ramulus Mori. Chemical Engineering Journal. 203: 19–24.

Ozdemier, I., Sahin, R. Orhan, M. Erdem. 2014. Preparation and Characterization Of Activated Carbon From Grape Stalk By Zinc Chloride Activation. Fuel Processing Technology. 125: 200 – 206.

Nieto-Delgado, C., M. Terrones, J.R. Rangel-Mendez. 2011. Development Of Highlymicroporous Activated Carbon From The Alcoholic Beverage Industry Organic By-Products. Biomass and Bioenergy. 35: 103-112.

Wang, Z., L. Zhan, M. Ge, F. Xie, Y. Wang, W. Qiao, X. Liang, and X. Ling. 2011. Pith Based Spherical Activated Carbon for CO2 Removal from Flue Gases. Chemical Engineering Science. 66: 5504–5511.

Garcia, S., J.J. Pis, F. Rubiera, C. Pevida. 2013. Predicting Mixed-Gas Adsorption Equilibria on Activated Carbon for Precombustion CO2 Capture. Langmuir. 29(20): 6042–6052.

Pakseresht, S., M. Kazemeini, and M.M. Akbarnejad. 2002. Equilibrium Isotherms for CO, CO2, CH4 and C2H4 on the 5A Molecular Sieve by A Simple Volumetric Apparatus. Separation and Purification Technology. 28: 53–60.

Vargas, A.M.M., A.L. Cazetta, M.H. Kunita, T.L. Silva, and V.C. Almeida. 2011. Adsorption of Methylene Blue on Activated Carbon Produced from Flamboyant Pods (Delonix regia): Study of Adsorption Isotherms and Kinetic models. Chemical Engineering Journa. 168: 722–730.

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Published

2016-08-10

How to Cite

MICROWAVE ASSISTED K2CO3 PALM SHELL ACTIVATED CARBON AS SORBENT FOR CO2 ADSORPTION APPLICATION. (2016). Jurnal Teknologi, 78(8-3). https://doi.org/10.11113/jt.v78.9576