ETHANOL SEPARATION USING SEPABEADS207 ADSORBENT

Authors

  • Mazin Abdulhusein Beden Ministry of Higher Education and Scientific Research, Baghdad, Republic of Iraq
  • Muhammad Abbas Ahmad Zaini Centre of Lipids Engineering & Applied Research (CLEAR), Ibnu-Sina Institute for Scientific & Industrial Research (ISI-SIR), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Tuan Amran Tuan Abdullah Centre of Hydrogen Economy, Institute of Future Energy, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v79.9900

Keywords:

Adsorption, ethanol, fermentation broth, Sepabeads207, stripping

Abstract

This work was aimed at evaluating the ethanol separation using Sepabeads207 adsorbent. A 10 wt% of ethanol solution was used as a model fermentation broth. The separation of ethanol from the solution was performed in a tube containing Sepabeads207 at different operating conditions: temperatures, 20 to 40oC; solution pH, 4 to 7; and contact times, 5 to 25 minutes. Recovery of ethanol via stripping was studied between 15 and 35 minutes, and at different air temperatures of 80 to 95oC. The concentration of liquid ethanol was measured using gas chromatography and refractometer. A higher ethanol concentration by Sepabeads207 adsorption was obtained at 20oC and solution pH 4 for 5 minutes, while the recovery was performed better at 80oC for 15 minutes. By applying these conditions, 10 wt% of ethanol in the solution was concentrated to 46 wt%. The ethanol adsorption data are: i). capacity of 0.22 g ethanol/g adsorbent, ii). selectivity of 7.75 (g ethanol/g water (adsorbed)) / (g ethanol/g water (original solution)), and iii). efficiency of 100%. Sepabeads207 is a promising adsorbent for ethanol separation from the dilute ethanol solution.

Author Biographies

  • Mazin Abdulhusein Beden, Ministry of Higher Education and Scientific Research, Baghdad, Republic of Iraq
    FKT UTM
  • Muhammad Abbas Ahmad Zaini, Centre of Lipids Engineering & Applied Research (CLEAR), Ibnu-Sina Institute for Scientific & Industrial Research (ISI-SIR), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
    FKT UTM
  • Tuan Amran Tuan Abdullah, Centre of Hydrogen Economy, Institute of Future Energy, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
    FKT UTM

References

Ziolkowska, J. R. 2014. Prospective Technologies, Feedstocks and Market Innovations for Ethanol and Biodiesel Production in the US. Biotechnology Reports. 4: 94-98.

Ahmed, H., Rask, N. and Baldwin, E. D. 1989. Ethanol Fuel as an Octane Enhancer in the US Fuel Market. Biomass. 19(3): 215-232.

Huang, H-J., Ramaswamy, S., Tschirner, U. W. and Ramarao, B. V. 2008. A Review of Separation Technologies in Current and Future Biorefineries. Separation and Purification Technology. 62(1): 1-21.

Banduru, V. V. R., Somalanka, S. R., Mendu, D. R., Madicherla, N. R. and Chityala, A. 2006. Optimization of Fermentation Conditions for the Production of Ethanol from Sago Starch by Co-immobilized Amyloglucosidase and Cells of Zymomonas mobilis using Response Surface Methodology. Enzyme and Microbial Technology. 38(1-2): 209-214.

Wiselogel, A., Tyson, S. and Johnson, D. 1996. Biomass Feedstock Resources and Composition. In Wyman, C. E. (Ed.). Handbook on Bioethanol: Production and Utilization. London: CRC Press.

Ibrahim, N. A. and Zaini, M. A. A. 2016. Parametric Investigation of Fixed-Tray, Semi-continuous Distillation Column for Ethanol Separation From Water. Jurnal Teknologi (Science & Engineering). In press.

Lee, L-S. and Huang, M-Y. 2000. The Vapour-liquid Equilibrium of Ethanol-water Mixture in the Presence of Benzyltriethylammonium Chloride Salt at Atmospheric Pressure. Chemical Engineering Communication. 180(1): 19-38.

Gil, I. D., Uyazan, A. M., Aguilar, J. L., Rodriguez, G. and Caicedo, L. A. 2008. Separation of Ethanol and Water by Extractive Distillation with Salt and Solvent as Entrainer: Process Simulation. Brazilian Journal of Chemical Engineering. 25(1): 207-215.

Verhoef, A., Figoli, A., Leen, B., Bettens, B., Drioli, E. and der Bruggen, B. V. 2008. Performance of a Nanofiltration Membrane for Removal of Ethanol from Aqueous Solutions by Pervaporation. Separation and Purification Technology. 60(1): 54-63.

O’Brien, D. J. and Craig Jr., J. C. 1996. Ethanol Production in a Continuous Fermentation/Membrane Pervaporation System. Applied Microbiology and Biotechnology. 44(6): 699-704.

Delgado, J. A., Uguina, M. A., Sotelo, J. L., Agueda, V. I, Gracia, A. and Roldan, A. 2012. Separation of Ethanol-water Liquid Mixtures by Adsorption on Silicalite. Chemical Engineering Journal. 180: 137-144.

Malik, R. K, Ghosh, P. and Ghose, T. K. 1983. Ethanol Separation by Adsorption-desorption. Biotechnology and Bioengineering. 25(9): 2277-2282.

Ramachandran, C. E., Chempath, S., Broadbelt, L. J. and Snurr, R. Q. 2006. Water Adsorption in Hydrophobic Nanopores: Monte Carlo Simulations of Water iIn Silicalite. Microporous and Mesoporous Materials. 90(1-3): 293-298.

Wang, K. S., Liao, C. C., Chu, R. Q. and Chung, T. W. 2010. Equilibrium Isotherms of Water and Ethanol Vapors on Starch Sorbents and Zeolite 3A. Journal of Chemical and Engineering Data. 55(9): 3334-3337.

Ophardt, P. 2003. Chemistry of Hydrogen Bond. Journal of Applied Chemistry. 73: 18-24.

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Published

2017-06-21

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Section

Science and Engineering

How to Cite

ETHANOL SEPARATION USING SEPABEADS207 ADSORBENT. (2017). Jurnal Teknologi (Sciences & Engineering), 79(5). https://doi.org/10.11113/jt.v79.9900