CHARACTERIZATION OF BITUMEN PROPERTIES INCORPORATING USED COOKING OIL AS A MODIFIER
DOI:
https://doi.org/10.11113/mjce.v38.25985Keywords:
Bitumen properties, modifiers, used cooking oil, asphalt pavement, pavement distress., Used cooking oil, bitumen modification, sustainable asphalt, pavement performance, binder characterization, waste valorization.Abstract
The investigation of waste-derived resources as modifiers for asphalt binders has been prompted by the growing need for high-performance and sustainable paving materials. Among these, used cooking oil (UCO) has attracted considerable interest because it can improve binder properties while also addressing environmental issues related to waste disposal. The long-term performance and longevity of bituminous pavements are nevertheless impacted by pavement distress such as fatigue cracking, rutting, bleeding, and irreversible deformation, despite advancements in asphalt technology. Therefore, to improve the properties of bitumen, this study explores characterization and bitumen modification using UCO. In this study, various contents of UCO, ranging from 2% to 10% by binder weight, were added to typical penetration grade bitumen (50/60). To assess the impact of UCO on the bitumen properties, laboratory tests such as penetration, softening point, flash point, and fire point were carried out. The findings show that adding UCO greatly increases the workability and flexibility of the bitumen while preserving acceptable properties. Additionally, the modification lessens the bitumen's vulnerability to hardening brought on by aging, which may enhance pavement performance over time. An optimum UCO dosage of 4% was found among the mixes tested, offering the most balanced increase in penetration and thermal stability. The results show that UCO is a promising, environmentally friendly modifier that can improve bitumen performance and encourage reusing waste-derived resources.
References
[1] L. Gupta and A. Bellary, 2018, “Comparative study on the Behavior of Bituminous Concrete Mix and Warm Mix Asphalt Prepared Using Lime and Zycotherm as Additive,” Material Today Proceedings, 5(1): 2074–2081, DOI: 10.1016/j.matpr.2017.09.203.
[2] G. Mac and A. L. Faxina, 2021, “Asphalt concrete mixtures modified with polymeric waste by the wet and dry processes : A literature review,” Construction and Building Materials, 312. DOI: 10.1016/j.conbuildmat.2021.125408.
[3] H. H. Joni and H. H. Mohammed, 2019, “Effect of Warm Asphalt Additive on Pavement Performance,” Journal of Engineering and Sustainable Development, 23(5): 137–146, DOI: 10.31272/jeasd.23.5.10.
[4] M. M. A. Aziz, M. T. Rahman, M. R. Hainin, and W. A. W. A. Bakar, 2015, “An overview on alternative binders for flexible pavement,” Construction and Building Materials, 84: 315–319, DOI: 10.1016/j.conbuildmat.2015.03.068.
[5] A. Ameli, D. Nasr, R. Babagoli, A. Hossein Pakshir, N. Norouzi, and S. Davoudinezhad, 2020, “Laboratory evaluation of rheological behavior of binder and performance of stone matrix asphalt (SMA) mixtures containing zycotherm nanotechnology, sasobit, and rheofalt warm mixture additives,” Construction and Building Materials, 262: 120757, DOI: 10.1016/j.conbuildmat.2020.120757.
[6] M. A. Bilema, M. Y. Aman, N. A. Hassan, and N. F. A. Abdullah, “Investigation on rheology and physical properties of asphalt binder blended with waste cooking oil,” IOP Conference Series: Material Science and Engineering, vol. 527, no. 1, 2019, DOI: 10.1088/1757-899X/527/1/012045.
[7] P. Cong, B. Chen, and H. Zhao, 2020, “Coupling effects of wasted cooking oil and antioxidant on aging of asphalt binders,” International Journal of Pavement Research and Technology, 13(1): 64–74, DOI: 10.1007/s42947-019-0086-0.
[8] A. B. Chhetri, K. C. Watts, and M. R. Islam, 2008, “Waste cooking oil as an alternate feedstock for biodiesel production,” Energies, 1(1): 3–18, DOI: 10.3390/en1010003.
[9] R. Foroutan, H. Esmaeili, S. M. Mousavi, S. A. Hashemi, and G. Yeganeh, 2019, “The physical properties of biodiesel-diesel fuel produced via transesterification process from different oil sources,” Physical Chemistry Research, 7(2): 415–424, DOI: 10.22036/pcr.2019.173224.1600.
[10] A. Sharma, P. Kodgire, and S. S. Kachhwaha, 2020. "Investigation of ultrasound-assisted KOH and CaO catalyzed transesterification for biodiesel production from waste cotton-seed cooking oil: Process optimization and conversion rate evaluation", Journal of Cleaner Production, 259. Elsevier Ltd, DOI: 10.1016/j.jclepro.2020.120982.
[11] H. Asli, E. Ahmadinia, M. Zargar, and M. R. Karim, 2012, “Investigation on physical properties of waste cooking oil – Rejuvenated bitumen binder,” Construction and Building Materials, 37: 398–405, DOI: 10.1016/j.conbuildmat.2012.07.042.
[12] M. Zargar, E. Ahmadinia, H. Asli, and M. R. Karim, 2012, “Investigation of the possibility of using waste cooking oil as a rejuvenating agent for aged bitumen,” Journal of Hazardous Materials, 233–234: 254–258, DOI: 10.1016/j.jhazmat.2012.06.021.
[13] Z. Sun, J. Yi, Y. Huang, D. Feng, and C. Guo, 2016, “Properties of asphalt binder modified by bio-oil derived from waste cooking oil,” Construction and Building Materials, 102: 496–504, DOI: 10.1016/j.conbuildmat.2015.10.173.
[14] X. Feng, H. Liang, and Z. Dai, 2022, “Rheological properties and microscopic mechanism of waste cooking oil activated waste crumb rubber modified asphalt,” Journal of Road Engineering, 2(4): 357–368, DOI: 10.1016/j.jreng.2022.09.001.
[15] J. Kim et al., 2021, “Valorization of waste-cooking oil into sophorolipids and application of their methyl hydroxyl branched fatty acid derivatives to produce engineering bioplastics,” Journal of Waste Management, 124: 195–202, DOI: 10.1016/j.wasman.2021.02.003.
[16] M. Irsyad, M. D. S. Es, A. Rizki, and D. Putra, 2023, “Results in Engineering Experimental study of the thermal properties of waste cooking oil applied as thermal energy storage,” Results in Engineering, 18: 101080, DOI: 10.1016/j.rineng.2023.101080.
[17] C. Wang, L. Xue, W. Xie, Z. You, and X. Yang, 2018, “Laboratory investigation on chemical and rheological properties of bio-asphalt binders incorporating waste cooking oil,” Construction and Building Materials, 167: 348–358, DOI: 10.1016/j.conbuildmat.2018.02.038.
[18] T. H. Kim and J. K. Han, 2012, “Viscosity Characteristics of Waste Cooking Oil with Ultrasonic Energy Irradiation,” Journal of Biosystem Engineering, 37(6): 429–433, DOI: 10.5307/jbe.2012.37.6.429.
[19] C. Plati, 2019, “Sustainability factors in pavement materials, design, and preservation strategies : A literature review,” Construction and Building Materials, 211: 539–555, DOI: 10.1016/j.conbuildmat.2019.03.242.
[20] R. Joumblat, Z. Al Basiouni Al Masri, G. Al Khateeb, A. Elkordi, A. R. El Tallis, and J. Absi, 2023, “State-of-the-Art Review on Permanent Deformation Characterization of Asphalt Concrete Pavements,” Sustainability, 15(2): 1–34, DOI: 10.3390/su15021166.
[21] A. M. Yel-shorbag, S. M. El-badawy, and A. R. Gabr, 2019, “Investigation of waste oils as rejuvenators of aged bitumen for sustainable pavement,” Construction and Building Materials, 220: 228–237, DOI: 10.1016/j.conbuildmat.2019.05.180.
[22] S. Banga and V. V Pathak, 2023 “Biodiesel production from waste cooking oil : A comprehensive review on the application of heterogeneous catalysts,” Energy Nexus,. 10: 100209. DOI: 10.1016/j.nexus.2023.100209.
[23] J. P. Aguiar-Moya, J. Salazar-Delgado, A. Baldi-Sevilla, F. Leiva-Villacorta, and L. Loria-Salazar, 2015, “Effect of aging on adhesion properties of asphalt mixtures with the use of bitumen bond strength and surface energy measurement tests,” Transportation Research Record, 2505: 57–65, DOI: 10.3141/2505-08.
[24] D. Khan, R. Khan, M. Tariq, and M. Alam, 2023, “ScienceDirect Performance of hot-mix asphalt using polymer-modified bitumen and marble dust as a filler,” Journal of Traffic and Transport Engineering (English Edition), 10(3): 385–398, DOI: 10.1016/j.jtte.2022.12.002.
[25] W. Zhang et al., 2022, “Evaluation method of storage stability of SBS modified bitumen based on dynamic rheological properties,” Construction and Building Materials, 323: 126615, DOI: 10.1016/j.conbuildmat.2022.126615.
[26] U. J. Nkanga, J. A. Joseph, F. V. Adams, and O. U. Uche, 2017, “Characterization of Bitumen/Plastic Blends for Flexible Pavement Application,” Journal of Procedia Manufacturing, 7: 490–496, DOI: 10.1016/j.promfg.2016.12.051.
[27] M. Paliukaite, V. Vorobjovas, M. Bulevičius, and V. Andrejevas, 2016, “Evaluation of Different Test Methods for Bitumen Adhesion Properties,” Transportation and Research Procedia, 14: 724–731, DOI: 10.1016/j.trpro.2016.05.339.
[28] S. Geetha, M. Selvakumar, and S. Muthulakshmi, 2021, “Characteristics of Polymer Modified Reclaimed Bitumen and Aggregate as a Sustainable Pavement Material,” IOP Conference Series: Material Science and Engineering, DOI: 10.1088/1757-899X/1055/1/012019.
[29] K. Blażejowski, J. Olszacki, H. Peciakowski, and M. Wójcik-Wisniewska, 2017, “Testing of bitumen-aggregate affinity by various methods,” E&E Congress Proceedings, DOI: 10.14311/ee.2016.397.
[30] S. Shiung, R. Keey, A. Jusoh, C. Tung, F. Nasir, and H. A. Chase, 2016, “Progress in waste oil to sustainable energy, with emphasis on pyrolysis techniques,” Renewable and Sustainable Energy Review, 53: 741–753, DOI: 10.1016/j.rser.2015.09.005.
[31] Y. Zhu, S. Zhou, Y. Wei, B. Li, and H. Wang, 2023, “Insight into the function of waste cooking oil in the magnetite reduction process,” Renewable Energy, 210: 188–195, DOI: 10.1016/j.renene.2023.04.068.
[32] J. Xiong et al., 2023, “Production of bio-oil from waste cooking oil via microwave-assisted pyrolysis in the presence of waste eggshell CaO and HZSM-5 : Process optimization and catalyst lifetime exploration,” Energy, 283: 128416, DOI: 10.1016/j.energy.2023.128416.
[33] F. Frota, D. A. Landi, C. Fabiani, B. Castellani, F. Cotana, and A. Laura, 2022, “Environmental assessment of four waste cooking oil valorization pathways,” Journal of Waste Management, 138: 219–233, DOI: 10.1016/j.wasman.2021.11.037.
[34] D. Oldham et al., 2021, “Transesterification of Waste Cooking Oil to Produce A Sustainable Rejuvenator for Aged Asphalt,” Resources, Conservation & Recycling, 168: 105297, DOI: 10.1016/j.resconrec.2020.105297.
[35] L. Xu, Y. Li, M. Liao, Q. Song, C. Wang, and J. Weng, 2023, “Catalytic pyrolysis of waste cooking oil for hydrogen-rich syngas production over bimetallic Fe-Ru / ZSM-5 catalyst,” Fuel Processing Technology, 247 DOI: 10.1016/j.fuproc.2023.107812.
[36] N. Xu, H. Wang, H. Wang, M. Kazemi, and E. Fini, 2023, “Research progress on resource utilization of waste cooking oil in asphalt materials : A state-of-the-art review,” Journal of Cleaner Production, 385: 135427, DOI: 10.1016/j.jclepro.2022.135427.
[37] Y. Buyang, R. Edra, H. Holilah, and H. Bahruji, 2023, “South African Journal of Chemical Engineering Dolomite catalyst for fast pyrolysis of waste cooking oil into hydrocarbon fuel,” South African Journal of Chemical Engineering, 45: 60–72, DOI: 10.1016/j.sajce.2023.04.007.
[38] K. Jacobson, R. Gopinath, L. C. Meher, and A. K. Dalai, 2008, “Solid acid catalyzed biodiesel production from waste cooking oil,” Applied Catalysis B: Environmental, 85(1–2): 86–91, DOI: 10.1016/j.apcatb.2008.07.005.
[39] C. A. W. Allen and K. C. Watts, 2000, “Comparative analysis of the atomization characteristics of fifteen biodiesel fuel types,” Transactions of the American Society of Agricultural Engineering, 43(2): 207–211, DOI: 10.13031/2013.2695.
[40] W. N. A. W. Azahar et al., 2016, “The potential of waste cooking oil as bio-asphalt for alternative binder – An overview,” Jurnal Teknologi, 78(4): 111–116, DOI: 10.11113/jt.v78.8007.
[41] J. Ma, G. Sun, D. Sun, Y. Zhang, A. Cannone, and T. Lu, 2020, “Rubber asphalt modified with waste cooking oil residue : Optimized preparation, rheological property, storage stability, and aging characteristic,” Construction and Building Materials, 258: 120372, DOI: 10.1016/j.conbuildmat.2020.120372.
[42] M. C. Cavalli, M. Zaumanis, E. Mazza, M. N. Partl, and L. D. Poulikakos, 2018, “Effect of ageing on the mechanical and chemical properties of binder from RAP treated with bio-based rejuvenators,” Composition Part B, 141: 174–181, DOI: 10.1016/j.compositesb.2017.12.060.
[43] D. Zhang, M. Chen, S. Wu, J. Liu, and S. Amirkhanian, 2017, “Analysis of the relationships between waste cooking oil qualities and rejuvenated asphalt properties,” Materials (Basel), 10(5): 508, DOI: 10.3390/ma10050508.
[44] Q. Chen, C. Wang, Z. Qiao, and T. Guo, 2020, “Graphene/tourmaline composites as a filler of hot mix asphalt mixture : Preparation and properties,” Construction and Building Materials. 239: 117859, DOI: 10.1016/j.conbuildmat.2019.117859.
[45] O. Awogbemi, D. Vandi, V. Kallon, and V. Sunday, 2021, “Case Studies in Chemical and Environmental Engineering Advances in biotechnological applications of waste cooking oil,” Case Studies in Chemical and Environmental Engineering, 4: 100158, DOI: 10.1016/j.cscee.2021.100158.
[46] Y. Wang and P. Hao, 2021, “Rheological and fatigue-healing durability of asphalt containing synthesized microcapsules with refined waste oil core,” Construction and Building Materials, 274: 121964, DOI: 10.1016/j.conbuildmat.2020.121964.
[47] S. Yan, Q. Dong, X. Chen, C. Zhou, S. Dong, and X. Gu, 2022, “Application of waste oil in asphalt rejuvenation and modification : A comprehensive review,” Construction and Building Materials, 340: 127784, DOI: 10.1016/j.conbuildmat.2022.127784.
[48] W. M. Kedir, K. T. Wondimu, and G. S. Weldegrum, 2023, “Heliyon Optimization and characterization of biodiesel from waste cooking oil using modified CaO catalyst derived from snail shell,” Heliyon, 9(5): e16475, DOI: 10.1016/j.heliyon.2023.e16475.
[49] J. R. Joshi, K. K. Bhanderi, and J. V Patel, 2023, “Journal of the Indian Chemical Society Waste cooking oil as a promising source for bio lubricants- A review,” Journal of the Indian Chemical Society, 100(1): 100820, DOI: 10.1016/j.jics.2022.100820.
[50] H. Wen, M. Asce, S. Bhusal, and B. Wen, 2014, “Laboratory Evaluation of Waste Cooking Oil-Based Bioasphalt as an Alternative Binder for Hot Mix Asphalt,” Journal of Materials in Civil Engineering, 25(10): 1432–1437, DOI: 10.1061/(ASCE)MT.1943-5533.0000713.
[51] Y. Zhao, M. Chen, S. Wu, Z. Cao, and X. Zhou, 2023, “Full-component cascade utilization of waste cooking oil in asphalt materials,” Construction and Building Materials, 404: 133355, DOI: 10.1016/j.conbuildmat.2023.133355.
[52] C. Rodrigues, S. Capit, and L. Picado-santos, 2020, “Full Recycling of Asphalt Concrete with Waste Cooking Oil as Rejuvenator and LDPE from Urban Waste as Binder Modifier”, Sustainability, 12(19): 8222, https://doi.org/10.3390/su12198222
[53] A. M. Al-Sabaeei, M. B. Napiah, M. H. Sutanto, W. S. Alaloul, and A. Usman, 2020, “A systematic review of bio-asphalt for flexible pavement applications: Coherent taxonomy, motivations, challenges and future directions,” Journal of Cleaner Production, 249: 34227-1 DOI: 10.1016/j.jclepro.2019.119357.
[54] J. Ma et al., 2021, “Understanding the role of waste cooking oil residue during the preparation of rubber asphalt,” Resources, Conservation & Recycling, 167: 105235, DOI: 10.1016/j.resconrec.2020.105235.
[55] M. Carlini, S. Castellucci, and S. Cocchi, 2014, “A pilot-scale study of waste vegetable oil transesterification with alkaline and acidic catalysts,” Energy Procedia, 45: 198–206, DOI: 10.1016/j.egypro.2014.01.022.
[56] A. A. Mamun and H. I. A. Wahhab, 2020, “Comparative laboratory evaluation of waste cooking oil rejuvenated asphalt concrete mixtures for high contents of reclaimed asphalt pavement,” International Journal of Pavement Engineering, 21(11): 1–12, DOI: 10.1080/10298436.2018.1539486.
[57] D. Sun, T. Lu, F. Xiao, X. Zhu, and G. Sun, 2017, “Formulation and aging resistance of modified bio-asphalt containing high percentage of waste cooking oil residues,” Journal of Cleaner Production, 161: 1203–1214, DOI: 10.1016/j.jclepro.2017.06.155.
[58] D. Sun et al., 2017, “Evaluation of optimized bio-asphalt containing high content waste cooking oil residues,” Fuel, 202: 529–540, DOI: 10.1016/j.fuel.2017.04.069.
[59] H. Hosseinzadeh-bandbafha, C. Li, X. Chen, and W. Peng, 2022, “Managing the hazardous waste cooking oil by conversion into bioenergy through the application of waste-derived green catalysts : A review,” Journal of Hazardous Materials, 424(PC): 127636, DOI: 10.1016/j.jhazmat.2021.127636.
[60] K. Yan, Y. Li, Z. Long, L. You, M. Wang, and M. Zhang, 2022, “Mechanical behaviors of asphalt mixtures modified with European rock bitumen and waste cooking oil,” Construction and Building Materials, 319(December): 125909, DOI: 10.1016/j.conbuildmat.2021.125909.
[61] W. Cao and C. Wang, 2019, “Fatigue performance characterization and prediction of asphalt binders using the linear amplitude sweep-based viscoelastic continuum damage approach,” International Journal of Fatigue, 119(October): 112–125, DOI: 10.1016/j.ijfatigue.2018.09.028.
[62] J. Ma, D. Sun, Q. Pang, G. Sun, M. Hu, and T. Lu, 2019, “Potential of recycled concrete aggregate pretreated with waste cooking oil residue for hot mix asphalt,” Journal of Cleaner Production, 221: 469–479, DOI: 10.1016/j.jclepro.2019.02.256.
[63] A. Behnood, 2020, “A review of the warm mix asphalt (WMA) technologies: Effects on thermo-mechanical and rheological properties,” Journal of Cleaner Production, 359: 129195. DOI: 10.1016/j.jclepro.2020.120817.
[64] M. Sukhija, N. Saboo, and A. Pani, 2023, “Effect of warm mix asphalt ( WMA ) technologies on the moisture resistance of asphalt mixtures,” Construction and Building Materials, 369(November): 130589, DOI: 10.1016/j.conbuildmat.2023.130589.
[65] R. Singh, R. Kumar, N. Atray, and S. Kumar, 2023, “Industrial Crops & Products Potential valorization of used cooking oil into novel biolubricating grease through chemical modification and its performance evaluation,” Industrial Crops and Products, 205(September): 117555, DOI: 10.1016/j.indcrop.2023.117555.
[66] R. Zhang, A. Ranjbar, F. Zhou, and D. Deb, 2023, “Effect of chemical warm-mix additives on asphalt binder rheological and chemical properties in the context of aging,” Construction and Building Materials, 393(October): 132061, DOI: 10.1016/j.conbuildmat.2023.132061.
[67] A. Eltwati et al., 2023, “Effect of Warm Mix Asphalt (WMA) Antistripping Agent on Performance of Waste Engine Oil-Rejuvenated Asphalt Binders and Mixtures,” Sustainability, 15(4): 3807. DOI: 10.3390/su15043807.
[68] Q. Song, M. Guo, and T. Ling, 2022, “A review of elevated-temperature properties of alternative binders : Supplementary cementitious materials and alkali-activated materials,” Construction and Building Materials, 341(May): 127894, DOI: 10.1016/j.conbuildmat.2022.127894.
[69] D. Rys, M. Jaczewski, M. Pszczola, P. Jaskula, and W. Bankowski, 2020, “Effect of bitumen characteristics obtained according to EN and Superpave specifications on asphalt mixture performance in low-temperature laboratory tests,” Construction and Building Materials, 231: 117156, DOI: 10.1016/j.conbuildmat.2019.117156.
[70] M. Zargar, E. Ahmadinia, H. Asli, and M. R. Karim, 2012, “Investigation of the possibility of using waste cooking oil as a rejuvenating agent for aged bitumen,” Journal of Hazardous Materials, 233–234: 254–258, DOI: 10.1016/j.jhazmat.2012.06.021.
[71] H. Asli, 2011. “Implementation of Waste Cooking Oil as RAP Rejuvenator,” Proceedings of the Eastern Asia Society for Transportation Studies, 8,
[72] M. R. Keymanesh, S. Amani, A. T. Omran, and M. M. Karimi, 2023, “Evaluation of the impact of long-term aging on fracture properties of warm mix asphalt (WMA) with high RAP contents,” Construction and Building Materials, 400(January): 132671, DOI: 10.1016/j.conbuildmat.2023.132671.
[73] Z. Ye, W. Ren, H. Yang, Y. Miao, F. Sun, and L. Wang, 2021, “An improved asphalt penetration test method,” Materials (Basel), 14(1): 1–12, DOI: 10.3390/ma14010147.
[74] Z. Ye and Y. Zhao, 2023, “Polyolefin Elastomer Modified Asphalt: Performance Characterization and Modification Mechanism,” Buildings, 13(5): 1291 DOI: 10.3390/buildings13051291.
[75] A. K. Banerji, D. Chakraborty, A. Mudi, and P. Chauhan, 2022 “Materials Today : Proceedings Characterization of waste cooking oil and waste engine oil on physical properties of aged bitumen,” Material Today Proceedings, 59: 1694–1699. DOI: 10.1016/j.matpr.2022.03.401.













