THE EFFECT OF NACL ADDITION TO TiO2/NiSe/NC PHOTOCATALYTIC FOR HYDROGEN GAS PRODUCTION

Authors

  • Tiara Ardianti Departement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya, 60111, Indonesia
  • Yuly Kusumawati Departement of Chemistry, Faculty of Science and Data Analytics, Institut Teknologi Sepuluh Nopember, Kampus ITS Keputih, Sukolilo, Surabaya, 60111, Indonesia

DOI:

https://doi.org/10.11113/aej.v14.21309

Keywords:

Photocatalytic H2 production, NaCl, NiSe, TiO2, water splitting, Energy research

Abstract

The widespread utilization of fossil fuel has resulted in fuel scarcity due to population growth and increased industrialization, driving the evolution of new renewable energy sources (NRE). Alternatively, hydrogen production through solar water splitting and TiO2 as a potential photocatalyst can be developed due to its good stability, environmental friendliness, and economic viability. However, TiO2 has the disadvantage of a wide bandgap that requires high energy and fast recombination. Therefore, in this research, TiO2/NiSe (TN) was synthesized with N doped carbon dopant modified with NaCl as a photocatalyst material through a solvothermal method. The characterized material using XRD, SEM, UV-DRS, BET, and FTIR. Photocatalytic activity tests were conducted to determine hydrogen production using an MQ8 sensor integrated with an Arduino microcontroller system. The synthesized materials are TN, TNC-0, and TNC-10. The addition of NaCl in carbon doped nitrogen materials of photocatalyst TNC-10 shows a reduction of the bandgap that is the lowest bandgap value obtained was 3.09eV. The photocatalytic activity test results showed a hydrogen production of 120 ppm for TNC-10, which is six-times higher compared to bare TiO2 as a photocatalyst. The increase in hydrogen gas production is due to the addition of NaCl to NC, which can enhance the photocatalytic activity and hydrogen adsorption on the catalyst surface during hydrogen production.

References

K. C. Christoforidis and P. Fornasiero, 2017. “Photocatalytic Hydrogen Production: A Rift into the Future Energy Supply,” Chemistry Catalytic Europe 9(9): 1523–1544, doi: 10.1002/cctc.201601659.

H. Ahmad, S. K. Kamarudin, L. J. Minggu, and M. Kassim, 2015, “Hydrogen from photo-catalytic water splitting process: A review,” Renew. Sustainable Energy Review., 43: 599–610, doi: 10.1016/j.rser.2014.10.101.

N. L. D. Silva et al., 2018. “Superior solar-to-hydrogen energy conversion efficiency by visible light-driven hydrogen production via highly reduced Ti2+/Ti3+ states in a blue titanium dioxide photocatalyst,” Catal Science Technology 8(18): 4657–4664. doi: 10.1039/C8CY01212A.

D. V. Wellia, Y. Kusumawati, L. J. Diguna, N. Pratiwi, R. A. Putri, and M. I. Amal, 2020, “Mesoporous Materials for Degradation of Textile Dyes,” 255–288. doi: 10.1007/978-3-030-16427-0_10.

H. Wang, W. Chen, J. Zhang, C. Huang, and L. Mao, 2015 “Nickel nanoparticles modified CdS – A potential photocatalyst for hydrogen production through water splitting under visible light irradiation,” Internation Journal Hydrogen Energy 40: 340–345. doi: 10.1016/j.ijhydene.2014.11.005.

L. Lin, T. Hisatomi, S. Chen, T. Takata, and K. Domen, 2020 “Visible-Light-Driven Photocatalytic Water Splitting: Recent Progress and Challenges,” Trends Chemistry. 2(9): 813–824. doi: 10.1016/j.trechm.2020.06.006.

R. Zouzelka, Y. Kusumawati, M. Remzova, J. Rathousky, and T. Pauporté, 2016, “Photocatalytic activity of porous multiwalled carbon nanotube-TiO2 composite layers for pollutant degradation,” Journal. Hazardous Material, 317: 52–59, doi: 10.1016/j.jhazmat.2016.05.056.

P. Ravi, V. Navakoteswara Rao, M. V. Shankar, and M. Sathish, 2020, CuO@NiO core-shell nanoparticles decorated anatase TiO2 nanospheres for enhanced photocatalytic hydrogen production,” International Journal Hydrogen Energy, 45(13): 7517–7529, doi: 10.1016/j.ijhydene.2019.05020.

J. Wang et al., 2020, “Synergistic effects of nano-silica and fly ash on properties of cement-based composites,” Construction Building Material, 262: 120737. doi: 10.1016/j.conbuildmat.2020.120737.

N. Rozman et al., 2021 “TiO2 photocatalyst with single and dual noble metal co-catalysts for efficient water splitting and organic compound removal,” International Journal Hydrogen Energy 46(65): 32871–32881, doi: 10.1016/j.ijhydene.2021.07.129.

N. Ramesh Reddy, M. Mamatha Kumari, K. K. Cheralathan, and M. V. Shankar, 2018 “Enhanced photocatalytic hydrogen production activity of noble metal free MWCNT-TiO2 nanocomposites,” International Journal Hydrogen Energy 43(8): 4036–4043, doi: 10.1016/j.ijhydene.2018.01.011.

V. Navakoteswara Rao et al., 2021, “Metal chalcogenide-based core/shell photocatalysts for solar hydrogen production: Recent advances, properties and technology challenges,” Journal Hazardous Material, 415: 125588, doi: 10.1016/j.jhazmat.2021.125588.

R. A. Hussain and I. Hussain, 2019, “Fabrication and applications of nickel selenide,” Journal of Solid State Chemestry., 277: 316–328, doi: 10.1016/j.jssc.2019.06.015.

X. Jiang, H. Gong, Q. Liu, M. Song, and C. Huang, 2020, “In situ construction of NiSe/Mn0.5Cd0.5S composites for enhanced photocatalytic hydrogen production under visible light,” Applied Catalyst B Environment., 268: 118439, doi: 10.1016/j.apcatb.2019.118439.

H. Gong, Q. Liu, and C. Huang, 2019 “NiSe as an effective co-catalyst coupled with TiO2 for enhanced photocatalytic hydrogen evolution,” International Journal Hydrogen Energy, 44(10): 4821–4831, doi: 10.1016/j.ijhydene.2019.01.039.

A. Khan, M. Goepel, J. C. Colmenares, and R. Gläser, 2020, “Chitosan-Based N-Doped Carbon Materials for Electrocatalytic and Photocatalytic Applications,” ACS Sustainable Chemistry Engineering, 8(12): 4708–4727, doi: 10.1021/acssuschemeng.9b07522.

E. Santoso, R. Ediati, Y. Kusumawati, H. Bahruji, D. O. Sulistiono, and D. Prasetyoko, 2020, “Review on recent advances of carbon based adsorbent for methylene blue removal from waste water,” Material Today Chemistry, 16. doi: 10.1016/j.mtchem.2019.100233.

I. Aranaz et al., 2021 “Chitosan: An overview of its properties and applications,” Polymers, 13(19) doi: 10.3390/polym13193256.

M. Zeng et al., 2016, “N-doped mesoporous carbons supported palladium catalysts prepared from chitosan/silica/palladium gel beads,” International Journal Biology Macromolecules, 89: 449–455. doi: 10.1016/j.ijbiomac.2016.05.011.

R. Shi et al., 2018, “NaCl-templated synthesis of hierarchical porous carbon with extremely large specific surface area and improved graphitization degree for high energy density lithium ion capacitors,” Journal Material Chemistry A, 6(35): 17057–17066, doi: 10.1039/c8ta05853a.

Q. Wu et al., 2019, “N-doped porous carbon from different nitrogen sources for high-performance supercapacitors and CO2 adsorption,” Journal of Alloys Compounds, 786: 826–838. doi: 10.1016/j.jallcom.2019.02.052.

J. Ding, P. Wang, S. Ji, H. Wang, D. J. L. Brett, and R. Wang, 2019, “Mesoporous nickel selenide N-doped carbon as a robust electrocatalyst for overall water splitting,” Electrochimica Acta, 300: 93–101. doi: 10.1016/j.electacta.2019.01.093.

L. Zheng, S. Han, H. Liu, P. Yu, and X. Fang, 2016. “Hierarchical MoS2 Nanosheet@TiO2 Nanotube Array Composites with Enhanced Photocatalytic and Photocurrent Performances,” Small, 12(11): 1527–1536, doi: 10.1002/smll.201503441.

Z. Zhang, Z. Zhou, H. Peng, Y. Qin, and G. Li, 2014 “Nitrogen- and oxygen-containing hierarchical porous carbon frameworks for high-performance supercapacitors,” Electrochimica Acta, 134: 471–477. doi: 10.1016/j.electacta.2014.04.107.

A. J. Alabdulghani, 2016. “Novel Techniques to Characterize Pore Size of Porous Materials,”

Y. Liu et al., 2023, “NaCl-assisted synthesis of porous carbons with ultra-high electrical conductivity for high-performance supercapacitors,” Journal of Power Sources, 553 doi: 10.1016/j.jpowsour.2022.232301.

N. Moloto, M. J. Moloto, N. J. Coville, and S. Sinha Ray, 2009. “Optical and structural characterization of nickel selenide nanoparticles synthesized by simple methods,” Journal of Crystal Growth, 311(15): 3924–3932. doi: 10.1016/j.jcrysgro.2009.06.006.

M. S. Begum and A. J. Ahamed, 2015. “Synthesis and characterization of NiSe and Doped NiSe: Mn,” 9,

D. P. Rahmadani, A. Rahmada, F. Marendra, H. J. Rimbawan, R. B. Cahyono, and T. Ariyanto, 2021. “Biogas Purification Using Chitosan-Impregnated Porous Carbon,”

K. Osler, N. Twala, O. O. Oluwasina, and M. O. Daramola, 2017. “Synthesis and Performance Evaluation of Chitosan/Carbon Nanotube (Chitosan/MWCNT) Composite Adsorbent for Post-combustion Carbon Dioxide Capture,” in Energy Procedia, Elsevier Ltd. 2330–2335. doi: 10.1016/j.egypro.2017.03.1368.

P. Praveen, G. Viruthagiri, S. Mugundan, and N. Shanmugam, 2014, “Structural, optical and morphological analyses of pristine titanium di-oxide nanoparticles – Synthesized via sol–gel route,” Spectrochimia Acta Part A: Molecular Biomolecular Spectroscopy, 117: 622–629 doi: 10.1016/j.saa.2013.09.037.

J. Yu and J. Ran, 2011, “Facile preparation and enhanced photocatalytic H2-production activity of Cu(OH)2 cluster modified TiO2,” Energy and Environmental Science 4(4): 1364–1371. doi: 10.1039/c0ee00729c.

Downloads

Published

2024-08-31

Issue

Section

Articles

How to Cite

THE EFFECT OF NACL ADDITION TO TiO2/NiSe/NC PHOTOCATALYTIC FOR HYDROGEN GAS PRODUCTION. (2024). ASEAN Engineering Journal, 14(3), 115-122. https://doi.org/10.11113/aej.v14.21309