DEGRADATION KINETICS OF TEXTILE AZO DYE REACTIVE ORANGE-16 BY GAMMA IRRADIATION

Authors

  • Fifi Nurfiana ᵃDepartment Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Kampus UGM, Yogyakarta 55281, Indonesia ᶜPolytechnic Institute of Nuclear Technology, National Research and Innovation Agency Jl. Babarsari Kotak POB 6101/YKKB, Yogyakarta 55281, Indonesia
  • Rochmadi Rochmadi Department Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Kampus UGM, Yogyakarta 55281, Indonesia
  • Rochim Bakti Cahyono Department Chemical Engineering, Faculty of Engineering, Universitas Gadjah Mada, Jl. Grafika No. 2, Kampus UGM, Yogyakarta 55281, Indonesia
  • Hendig Winarno Research Center for Radiation Process Technology, National Research and Innovation Agency KST B.J. Habibie, Jl. Puspiptek, Tangerang Selatan, Banten15314, Indonesia
  • Sugili Putra Polytechnic Institute of Nuclear Technology, National Research and Innovation Agency Jl. Babarsari Kotak POB 6101/YKKB, Yogyakarta 55281, Indonesia

DOI:

https://doi.org/10.11113/jurnalteknologi.v86.21973

Keywords:

Gamma radiation, Reactive Orange-16, degradation, peroxide, radiolytic

Abstract

Gamma radiation have become attention since their high potential for degrading compounds, especially organic pollutants. In this research, gamma radiation was studied for degrading the Reactive Orange-16 (RO-16) dye, a toxic and carcinogenic pollutant. The radiolytic degradation process was studied in a batch reactor with a gamma-ray dose rate of 2.930 kGy/h. The effect of experimental variable such as initial peroxide concentration, initial pH, initial dye concentration, and addition of inorganic anion were studied. The highest degradation rates were achieved at a peroxide concentration ranging from 2 to 4 mM. In contrast, the higher peroxide concentration indicated the slower degradation process caused by the scavenging effect of the peroxide. Degradation of 88% RO-16 dye with 0.1 mM initial concentration, was achieved at 2.0 kGy irradiation dose and 97.4% degradation in the presence of 4 mM peroxide. The dose constant (d) for those degradation processes was 1.0657 kGy-1 and 1.8420 kGy-1 respectively. The degradation was more efficient in acid pH. The degradation process increased with lower initial dye concentrations. The degradation of RO-16 dye by gamma-ray was inhibited by the presence of inorganic anions in the following sequence: NO3-→ CO32− → HCO3 → CH3COO-→ Cl-.

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Published

2024-09-17

Issue

Section

Science and Engineering

How to Cite

DEGRADATION KINETICS OF TEXTILE AZO DYE REACTIVE ORANGE-16 BY GAMMA IRRADIATION. (2024). Jurnal Teknologi (Sciences & Engineering), 86(6). https://doi.org/10.11113/jurnalteknologi.v86.21973