Reactive Dye Removal from Simulated Wastewater using Tetrabutyl Ammonium Bromide as an Extractant

Authors

  • Norasikin Othman Centre of Lipid Engineering and Applied Research (CLEAR), Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bharu, Johor, Malaysia
  • Noor Sa’ida Nafisah Mohd Aziz Centre of Lipid Engineering and Applied Research (CLEAR), Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bharu, Johor, Malaysia
  • Norlisa Harruddin Centre of Lipid Engineering and Applied Research (CLEAR), Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bharu, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v67.2736

Keywords:

Reactive dye, textile wastewater, liquid-liquid extraction, dye removal

Abstract

Dyes caused serious environmental pollution and health problem in many ways. Many dyes have toxic effects on aquatic life and also on humans. Liquid-liquid extraction process is one of the alternatives for dye removal from wastewater. Removal of remazol red 3BS from simulated textile wastewater using tetrabutyl ammonium bromide has been studied at room temperature with total operation time of 18 hours. Several parameters have been studied such as pH, diluents, initial dye concentration, extractant concentration and stripping agents toward the extraction process of the dye. The results show only small effects of pH on the extraction percentage. The best diluent for the extraction is dichloromethane with the percentage of 98%. The percentage of extraction is maximum (97%) at 0.07M of TBAB concentration with the distribution ratio of D= 34.65. Salicylic acid in Na2CO3 with the ratio of 1:2 gives the highest percentage of stripping process. It shows a good performance for liquid-liquid extraction of remazol red 3BS for both removal and recovery processes.

References

McKay, G., M. El-Guendi, M.M. Nassar. 1987. Equilibrium Studies During the Removal of Dyestuffs from Aqueous Solution Using Bagass Pith. Water Research. 21: 1513–1520.

Amin, N.K. 2008. Removal of Reactive Dye from Aqueous Solutions by Adsorption onto Activated Carbons Prepared from Sugarcane Bagasse Pith. Desalination. 223: 152–161.

Othman, N., N. Mili, S.N. Zailani. 2010. Emulsion Liquid Membrane Extraction of Turquoise Blue Reactive – Study on Membrane Breakage and Swelling. Journal of Applied Membrane Science and Technology. 11: 43–48

Othman, N., R. Djamal, N. Mili, S.N. Zailani. 2011. Removal of Red 3BS Dye from Wastewater Using Emulsion Liquid Membrane Process. Journal of Applied Science. 11(7): 1406–1410

Daneshvar, N., H.A. Sorkhabi, M.B. Kasiri. 2004. Decolourisation of Dye Containing Acid Red 14 by Electrocoagulation with Comparative Investigation of Different Electrode Connections. Journal of Hazardous Material. 112: 55–62.

Pandit, P., S.J. Basu. 2002. Removal of Organic Dyes from Water by Liquid-Liquid Extraction Using Reverse Micelles. Colloid Interface Science. 245: 208–214.

Woo, L. D., H. W. Hi, H. K. Yup. 2000. Removal of an Organic Dye from Water Using a Predispersed Solvent Extraction. Separation Science Technology. 25: 1951–1962.

Nerud, F., P. Baldrian, J. Gabriel, D. Ogbeifun. 2001. Decolorization of Synthetic Dyes by The Fenton Reagent and The Cu/Pyridine/H2O2 System. Chemosphere. 44: 957–961

Bali, U., B. Karagozoglu. 2007. Decolorization of Remazol-Turquoise Blue G and Other Dyes by Cu/Pyridine/H2O2 System. Dyes and Pigments. 73: 133–140.

Rydberg, J., C. Musikas, G.R. Choppin. 1992. Principles and Practice of Solvent Extraction. New York: Marcel Dekler, Inc.

Wade, L.G. 2006. Organic Chemistry. 6th Ed. United States: Pearson Education International.

Downloads

Published

2014-02-28

How to Cite

Reactive Dye Removal from Simulated Wastewater using Tetrabutyl Ammonium Bromide as an Extractant. (2014). Jurnal Teknologi, 67(2). https://doi.org/10.11113/jt.v67.2736