Alkali Pretreatment and Acid Hydrolysis of Coconut Pulp and Empty Fruit Bunch to Produce Glucose

Authors

  • Noorhalieza Ali Centre of Lipid Engineering and Applied Research (CLEAR), Ibnu Sina Institute for Scientific and Industrial Research, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Che Afifi Che Aziz Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia
  • Onn Hassan Department of Chemical Engineering, Faculty of Chemical Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia

DOI:

https://doi.org/10.11113/jt.v74.4687

Keywords:

Lignocellulose, alkaline pretreatment, acid hydrolysis, glucose

Abstract

Lignocellulose waste has great potential to be converted into value added products sustainably as it is readily available at low cost. The aim of this study is to examine the amount of glucose produced from coconut pulp and coconut empty fruit bunch using acid hydrolysis. Sodium hydroxide pretreatment is carried out at 70oC using different concentrations of sodium hydroxide which are 5%, 10%, 15% and 20% v/v for a duration time of 2 hours. Optimum pretreatment is evaluated using Fourier Transform Infra-Red (FTIR) analysis. It is observed that optimum pretreatment is at 20% v/v sodium hydroxide. The optimum samples are then hydrolysed using concentrations of 5%, 10%, 15% and 20% v/v of sulphuric acid at different temperatures of 30, 50, 70 and 90oC for 2 hours. Glucose concentration is analysed using an ultraviolet (UV) Spectrophotometer. The highest glucose concentrations obtained are 0.895 g/L and 0.550g/L for coconut pulp and coconut empty fruit bunch, respectively at 20% v/v acid concentration and a temperature of 90oC. 

References

Pu, Y. Q., Zhang, D., Singh, P. M. and Ragauskas, A. J. J. 2008. The New Forestry Biofuels Sector. Biofuels, Bioproducts and Biorefining. 2(1): 58–73.

Meine, N., J. Hilgert, M., Kadstrom, R., Rinaldi, and F., Schüth. 2013. Catalytic Milling: A New Entry Point for Lignocellulose Biorefineries. Research Report. Germany. Max Planck Institute for Coal Research.

Sorek. N., Yeats, T. H., Szemenyei, H., Youngs, H. and Somerville, C. R. 2014. The Implications of Lignocellulosic Biomass Chemical Composition for the Production of Advanced Biofuels. BioScience 63(3): 192–201.

Ritter, S. K. 2008. Lignocellulose: A Complex Biomaterial. C&EN. 86(49): 15 [Online] http://cen.gext.acs.org/articles/86/i49/Lignocellulose-Complex-Biomaterial.html [Acessed on 24 Febuary, 2015].

He, Y., Pang, Y., Liu, Y., Li, X., and Wang, K. 2008. Physicochemical Characterization of Rice Straw Pretreated with Sodium Hydroxide in the Solid State for Enhancing Biogas Production. Energy and Fuels. 22: 2775–2781.

Parveen K., Diane M. B., Michael J. D., and Pieter S. 2009. Methods for Pretreatment of Lignocellulosic Biomass for Efficient Hydrolysis and Biofuel Production. Ind. Eng. Chem. Res. 48(8): 1–18.

Bensah, E. C. and Mensah, M. 2013. Chemical Pretreatment Methods for the Production of Cellulosic Ethanol: Technologies and Innovations. International Jurnal of Chemical Engineering. 2013 Article ID719607:21 pages.

Mosier, N., Wyman, C., Dale, B., Elander, R., Lee, Y.Y., Holtzapple, M., Ladisch, M. 2005. Features of Promising Technologies for Pretreatment of lignocellulosic Biomass. Bioresource Technology. 96(6): 673–686.

Karimi K., M., Shafiel, and R.,Kumar. 2013. Progress in Physical and Chemical: Pretreatment of Lignocellulosic Biomass. Gupta, V. K. and M. G. Tuohy (ed.). Biofuel Technologies: Recent Developments. Berlin. Springer-Verlag .

Hsu, T. C., Guo, G. L., Chen, W. H., and Hwang, W. S. 2010. Effect of Acid Pretreatment of Rice Straw on Structural Properties and Enzymatic Hydrolysis. Bioresource Technology. 101(13): 4907–4913.

Kubo S., and Kadla J. F. 2005. Hydrogen Bonding in Lignin: A Fourier Transform Infrared Model Compound Study. Biomacromolecules. 6(5): 2815–2821.

Sun, R. C., Tomkinson, J., Ma, P. L., Liang, S. F. 2000. Comparative Study of Hemicelluloses from Rice Straw by Alkali and Hydrogen Peroxide Treatments. Carbohydrate Polymers. 42(2): 111–122.

Sekiguchi, Y., Kamagata. Y., and Harada, H. 2001. Recent Advances in Methane Fermentation Technology. Biotechnology. 12(3): 277–282.

Huang, D. L., Zeng, G. M., Huang, G. H., and Hu, T. J. 2005. Optimum Conditions of Solid-state Fermentation for White-rot Fungi and for Its' Degrading Straw. Acta Sci. Circumstantiae. 25(2): 232–237.

Yoon, S. Y., San, S. H., and Shin, S. J. 2014. The Effect of Hemicelluloses and Lignin on Acid Hydrolysis of Cellulose. Energy. 77: 19–24.

Botha T. and Blottnitz H. 2006. A Comparison of the Environmental Benefits of Bagasse-derived Electricity and Fuel Ethanol on a Life-cycle Basis. Energy Policy. 34(17): 2654–2661.

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Published

2015-06-02

Issue

Section

Science and Engineering

How to Cite

Alkali Pretreatment and Acid Hydrolysis of Coconut Pulp and Empty Fruit Bunch to Produce Glucose. (2015). Jurnal Teknologi, 74(7). https://doi.org/10.11113/jt.v74.4687