GRANULAR-ACTIVATED CARBON FROM MUKAH COAL USING CARBON DIOXIDE ACTIVATION
DOI:
https://doi.org/10.11113/jt.v75.5340Keywords:
Mukah coal, one-step activation, burn off analysis, BET surface area, micropore area, average pore diameterAbstract
A study was conducted on Mukah coal using fixed bed reactor and one step activation with varying resident time and temperatures. CO2 gas was used for the activation process. The one-step continuous process comprised of carbonization and activation processes. The burn off analysis for 80 grams of Mukah coal was done to obtain volatiles removal at various carbonization temperatures. The results obtained showed that at 900oC, the percentages of burn off and the remaining weight were 42.2% and 57.8% respectively. Micrometrics ASAP2010 was used to analyze Mukah coal activated carbon in obtaining the BET surface area, the micropore area, and the average pore diameter. The results obtained indicated that activation at 900oC gave the highest BET surface area with 675m2/g, while the highest micropore area with 427 m2/g was obtained at 800oC. In addition, the average pore diameter range was within 18.5 to 26.4 A.Â
References
Jun’ichi H, Toshihide H, Isao T, Katsuhiko M, Ani F N. 2002. Preparing activated carbon from various nutshells by chemical activation with K2CO3. Carbon. 40: 2381-2386.
Wan Mohd Ashri WD, Wan Shabuddin WA, Mohd Zaki S. 2000. The Effects of Carbonization Temperature on Pore Development in Palm-Shell-Based Activated Carbon. Carbon. 38: 1925-1932.
Jon A, Gartzen L, Maider A, Javier B, Martin O. 2014. Upgrading the rice husk char obtained by flash pyrolysis for the production of amorphous silica and high quality activated carbon. Bioresource Technology. 170: 132–137.
Jinbei Y, Meiqiong Y, Wentao C. 2015. Adsorption of hexavalent chromium from aqueous solution by activated carbon prepared from longan seed: Kinetics, equilibrium and thermodynamics. Journal of Industrial and Engineering Chemistry. 21: 414–422.
Irem O, Selhan K, Turgay T, Murat E. 2014. Activated Carbons from Grape Seeds by Chemical Activation with Potassium Carbonate and Potassium Hydroxide. Applied Surface Science.93: 138–142.
Ahmadpour A, Do DD. 1996. The Preparation of Active Carbons from Coal by Chemical and Pysical Activation. Carbon. 34: 471-479.
Junbo Z,Shan Hao, Liping Gao,Youchen Zhang, 2014. Study on adsorption performance of coal based activated carbon to radioactive iodine and stable iodine. Annals of Nuclear Energy. 72: 237-241.
Duan X H, C. Srinivasakannan, Liang J S, 2014. Process optimization of thermal regeneration of spent coal based activated carbon using steam and application to methylene blue dye adsorption, Journal of the Taiwan Institute of Chemical Engineers. 45: 1618-1627.
Wei G L, Xu J G, Ke W, Xin R Z, Wen B F. 2014. Adsorption characteristics of arsenic from micro-polluted water by an innovative coal-based mesoporous activated carbon. Bioresource Technology. 165: 166-173.
Hwang H I, Matsuto T, Tanaka N, Sasaki Y, Tanaami K. 2006. Characterization of char derived from various types of solid wastes from the standpoint of fuel recovery and pretreatment before landfilling. Waste Management. 27: 1155-1166.
Turkan K, Atakan T. 2007. Preparation of activated carbons from Zonguldak region coals by physical and chemical activations for hydrogen sorption. International Journal of Hydrogen Energy. 32: 5005 – 5014.
Ku H, K. H, Abdul R. 2004. Effects of Activating Agents on the Yield and Porosity of Chemically Produced Activated Carbon From Oil Palm Shell, Faculty of Chemical Engineering, Universiti Teknologi MARA, Shah Alam. Journal of Industrial Technology. 13: 65-74.
[13]Wan Mohd Ashri WD, Wan Shabuddin WA, Mohd Zaki S. 2000. The Effects of Carbonization Temperature on Pore Development in Palm-Shell-Based Activated Carbon. Carbon. 38: 1925-1932.
Jia G, Aik CL. 2000. Preparation of Activated Carbons from Oil-Palm-Stone Chars by Microwave Induced Carbon Dioxide Activation. Carbon. 38: 1985–1993.
Jian S, Hippo E J, Marsh H O, W S, Crelling J C. 1996. Activated Carbon Produced from an Illinois Basin Coal. Carbon. 35: 341-352.
Marcilla A, Asensio M, MartÃn-GullónI. 1995. Influence of the carbonization-heating rate on the pysical properties of activated carbon from a sub-bituminous coal. Carbon. 34: 449-456.
Jun’ichi H, Atsuo K, Katsuhiko M, Paul WA. 2000. Preparation of activated carbon from lignin by chemical activation.. Carbon. 38: 1873–1878.
Teng H, Ho J A, Hsu Y F. 1996. Preparation of Activated Carbons from Bituminous Coals with CO2 Activation-Influence of Coal Oxidation. Carbon. 35: 275-283.
Downloads
Published
Issue
Section
License
Copyright of articles that appear in Jurnal Teknologi belongs exclusively to Penerbit Universiti Teknologi Malaysia (Penerbit UTM Press). This copyright covers the rights to reproduce the article, including reprints, electronic reproductions, or any other reproductions of similar nature.