SORPTION OF ZINC USING MICROWAVE INCINERATED SUGARCANE BAGASSE ASH (MISCBA) AND RAW BAGASSE

Authors

  • Ibrahim Umar Salihi Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS (UTP), 32610, Bandar Seri Iskandar, Perak Darul Ridzuan, Malaysia
  • Shamsul Rahman Mohamed Kutty Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS (UTP), 32610, Bandar Seri Iskandar, Perak Darul Ridzuan, Malaysia
  • Mohamed Hasnain Isa Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS (UTP), 32610, Bandar Seri Iskandar, Perak Darul Ridzuan, Malaysia
  • Amirhossein Malakahmad Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS (UTP), 32610, Bandar Seri Iskandar, Perak Darul Ridzuan, Malaysia
  • Usman Aminu Umar Department of Civil and Environmental Engineering, Universiti Teknologi PETRONAS (UTP), 32610, Bandar Seri Iskandar, Perak Darul Ridzuan, Malaysia

DOI:

https://doi.org/10.11113/jt.v78.8510

Keywords:

Microwave, zinc, adsorption, bagasse ash, heavy metals

Abstract

Release of contaminated wastewater containing toxic pollutants has adverse negative effects to the receiving water environment. Heavy metals are non-biodegradable, with longer half –life and overtime, and can accumulate in living organism. Therefore, it is important to remove heavy metals from wastewater for its safe disposal. In this study, activated carbon prepared from thermal incineration of sugarcane bagasse was used in removing zinc from synthetic solution.  The prepared carbon is termed as microwave incinerated sugarcane bagasse ash (MISCBA). Raw non-incinerated bagasse was also employed to compare the removal capacities of the two adsorbents (MISCBA and raw bagasse). Parameters including pH, contact time, initial metal concentrations and adsorbents dosages were examined. The results showed that pH of 6.0, contact time 3 hours and adsorbents dosage of 12 g/L were found to be optimum for zinc removal. Removal capacities of 21.05 mg/g and 13.4 mg/g were determined for MISCBA and raw bagasse, respectively. Freundlich correlation coefficients for MISCBA and raw bagasse were found to be 0.7508 and 0.9233, respectively. Langmuir correlation coefficients were 0.9231 and 0.6423, for MISCBA and bagasse respectively.

References

Fu, F. and Wang, Q. 2011. Removal Of Heavy Metal Ions From Wastewaters: A Review. Journal of Environmental Management. 92: 407-418.

Chasapis, C. T., Loutsidou, A. C., Spiliopoulou, C. A., and Stefanidou, M. E., 2012. Zinc And Human Health: An Update. Archives Of Toxicology. 86: 521-534.

Vašák, M. and Hasler, D. W. 2000. Metallothioneins: New Functional And Structural Insights. Current Opinion In Chemical Biology. 4: 177-183.

Beyersmann, D. 2002. Homeostasis And Cellular Functions Of Zinc. Materialwissenschaft Und Werkstofftechnik. 33: 764-769.

Amuda, O., Giwa, A., and Bello, I. 2007. Removal Of Heavy Metal From Industrial Wastewater Using Modified Activated Coconut Shell Carbon. Biochemical Engineering Journal. 36: 174-181.

Umar, S. I., Kutty, S. R. M., Isa, M. H., Aminu, N., Henry, E., and Rahim, A. F. B. A. 2015. Biomass As Low-Cost Adsorbents For Removal Of Heavy Metals From Aqueous Solution: A Review Of Some Selected Biomass. InCIEC 2014. ed: Springer. 973-987.

Huang, C. and Blankenship, D. 1984. The Removal Of Mercury (II) From Dilute Aqueous Solution By Activated Carbon. Water Research. 18: 37-46.

Annadurai, G., Juang, R., and Lee, D. 2003. Adsorption Of Heavy Metals From Water Using Banana And Orange Peels. Water Science & Technology. 47: 185-190.

Kumar, P., Rao, R., Chand, S., Kumar, S., Wasewar, K., and Yoo, C. K. 2013. Adsorption Of Lead From Aqueous Solution Onto Coir-Pith Activated Carbon. Desalination and Water Treatment. 51: 2529-2535.

Salihi, I., Kutty, S., Isa, M., Aminu, N., and Ezerie, H. 2014. Microwave Incinerated Sugarcane Bagasse Ash (MISCBA) As A Low Cost Adsorbent For The Removal Of Zinc In Aqueous Solution. Energy and Sustainability V. 186: 281.

Ferrero, F. and Gaglia, Prati M. 1996. Coal Fly Ash And Alginate For The Removal Of Heavy Metals From Aqueous Solutions. Annali Di Chimica. 86: 125-132

Kutty, S. R. M., Khaw, S. G., Lai, C. L., Isa, M. H. 2012. Removal of Copper Using Microwave Incinerated Rice Husk Ash (MIRHA) in Continuous Flow Activated Sludge System. 2012 International Conference on Civil, Offshore & Environmental Engineering (ICCOEE2012).

Rafatullah, M., Sulaiman, O., Hashim, R., and Ahmad, A. 2009. Adsorption Of Copper (II), Chromium (III), Nickel (II) And Lead (II) Ions From Aqueous Solutions By Meranti Sawdust. J Hazard Mater. 170: 969-77.

Salihi, I. U., Kutty, S. R. M., Isa, M. H., Olisa, E., and Aminu, N. 2015. Adsorption Of Copper Using Modified And Unmodified Sugarcane Bagasse. International Journal of Applied Engineering Research. 10: 40434-40438.

Krishni, R., Foo, K., and Hameed, B. 2013. Adsorptive Removal Of Methylene Blue Using The Natural Adsorbent-Banana Leaves. Desalination And Water Treatment. 1-9.

Gönen, F. and Serin, D. S. 2014. Adsorption Study On Orange Peel: Removal Of Ni (II) Ions From Aqueous Solution. African Journal of Biotechnology. 11: 1250-1258,

Ahmad, M., Lee, S. S., Oh S.-E., Mohan, D., Moon, D. H., Lee, Y. H., et al. 2013. Modeling Adsorption Kinetics Of Trichloroethylene Onto Biochars Derived From Soybean Stover And Peanut Shell Wastes. Environmental Science and Pollution Research. 1-10.

Rosmi, M., Azhari, S., and Ahmad, R. 2014. Adsorption of Cadmium from Aqueous Solution by Biomass: Comparison of Solid Pineapple Waste, Sugarcane Bagasse and Activated Carbon. Advanced Materials Research. 832: 810-815.

Febrianto, J., Kosasih, A. N., Sunarso, J., Ju, Y.-H., Indraswati, N., and Ismadji, S. 2009. Equilibrium And Kinetic Studies In Adsorption Of Heavy Metals Using Biosorbent: A Summary Of Recent Studies. Journal of Hazardous Materials. 162: 616-645.

Badmus, M., Audu, T., and Anyata, B. 2007. Removal of Lead Ion From Industrial Wastewaters By Activated Carbon Prepared From Periwinkle Shells (Typanotonus fuscatus). Turkish J. Eng. Env. Sci. 31: 251-263.

Hashem, M. A. 2007. Adsorption Of Lead Ions From Aqueous Solution By Okra Wastes. International Journal of Physical Sciences. 2: 178-184.

Matheickal, J. T. and Yu, Q. 1999. Biosorption Of Lead (II) And Copper (II) From Aqueous Solutions By Pre-Treated Biomass Of Australian Marine Algae. Bioresource Technology. 69: 223-229.

Marzal, P., Seco, A., Gabaldon, C., and Ferrer, J. 1996. Cadmium And Zinc Adsorption Onto Activated Carbon: Influence Of Temperature, Ph And Metal/Carbon Ratio. Journal Of Chemical Technology And Biotechnology. 66: 279-285.

Isa, M. H., Ibrahim, N., Aziz, H. A., Adlan, M. N., Sabiani, N. H. M., Zinatizadeh, A. A. L., et al. 2008. Removal Of Chromium (VI) From Aqueous Solution Using Treated Oil Palm Fibre. Journal of Hazardous Materials. 152: 662-668.

Pereira, F. V., Gurgel, L. V. A, and Gil, L. F. 2010. Removal Of Zn2+ From Aqueous Single Metal Solutions And Electroplating Wastewater With Wood Sawdust And Sugarcane Bagasse Modified With EDTA Dianhydride (EDTAD). Journal of Hazardous Materials. 176: 856-863.

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Published

2016-05-08

How to Cite

SORPTION OF ZINC USING MICROWAVE INCINERATED SUGARCANE BAGASSE ASH (MISCBA) AND RAW BAGASSE. (2016). Jurnal Teknologi (Sciences & Engineering), 78(5-3). https://doi.org/10.11113/jt.v78.8510