CFD MODELING OF SO2 CAPTURE USING LIMESTONE IN INDUSTRIAL SCALE CIRCULATING FLUIDIZED BED BOILER

Authors

  • Rattapong Tritippayanon Center of Excellence on Petrochemical and Materials Technology, Chulalongkorn University, 254, Phayathai Road, Patumwan, Bangkok 10330, Thailand
  • Veeraya Jiradilok D.A. Research Center Co., Ltd., 122 Moo 2, Thatoom, Srimahaphote, Prachinburi 25140, Thailand
  • Pornpote Piumsomboon Department of Chemical Technology, Faculty of Science, Chulalongkorn University, 254 Phayathai Road, Patumwan, Bangkok 10330, Thailand
  • Benjapon Chalermsinsuwan Department of Chemical Technology, Faculty of Science, Chulalongkorn University, 254 Phayathai Road, Patumwan, Bangkok 10330, Thailand

DOI:

https://doi.org/10.11113/jt.v78.8986

Keywords:

CFD modeling, circulating fluidized bed boiler, combustion, desulfurization, sulfur dioxide capture

Abstract

The unsteady state computational fluid dynamics model for gas-solid particle flow in industrial scale circulating fluidized bed boiler combining with combustion and desulfurization (using limestone solid sorbent) chemical reactions, both homogeneous and heterogeneous, was developed in this study. The effects of solid sorbent feeding position and solid sorbent particle size on sulfur dioxide concentration were investigated. The results showed that both the solid sorbent feeding position and solid sorbent particle size had an effect on the sulfur dioxide capture. Entering solid sorbent at the upper secondary air position gave lower sulfur dioxide concentration than the one at the lower secondary air position and fuel feed position, respectively. This can be explained by the influence of suitable temperature at the upper secondary air position for desulfurization chemical reaction. About the solid sorbent particle size, the sulfur dioxide capture was the lowest when using the largest solid sorbent particle size due to the system hydrodynamics. 

References

Staudt, J. E. 2011. Control Technologies To Reduce Conventional And Hazardous Air Pollutants From Coal-Fired Power Plants. M.J. Bradley & Associates LLC. United states of America

Ryu, H., Grace, J. and Lim, C. 2006. Simultaneous CO2/SO2 Capture Characteristics of Three Limestones in a Fluidized-Bed Reactor. Energy Fuels. 1621-1628.

Ma, L., Cao, L. and He, R. 2015. Numerical Study Of Pore Structure Effect On SO2–CaO Reactions. Chinese Journal of Chemical Engineering. 23: 652-658.

Arias, B., Cordero, J. M., Alonso, M., Diego, M. E. and Abanades, J. C. 2013. Investigation Of SO2 Capture In A Circulating Fluidized Bed Carbonator Of A Ca Looping Cycle. Industrial & Engineering Chemistry Research. 52(7): 2700-2706.

Shuai, W., Juhui, C., Guodong, L., Huilin, L., Feixiang, Z. and Yanan, Z. 2014. Predictions Of Coal Combustion And Desulfurization In A CFB Riser Reactor By Kinetic Theory Of Granular Mixture With Unequal Granular Temperature. Fuel Processing Technology. 126: 163-172.

Chinsuwan, A., Dutta, A. and Janlasad, N. 2014. Prediction Of The Heat Flux Profile On The Furnace Wall Of Circulating Fluidized Bed Boilers. Journal of the Energy Institute. 87: 314-320.

Qiu, G., Ye, J. and Wang, H. 2015. Investigation Of Gas–Solids Flow Characteristics In A Circulating Fluidized Bed With Annular Combustion Chamber By Pressure Measurement Sand CPFD Simulation. Chemical Engineering Science. 134: 433-447.

Patankar, S. V. 1980. Numerical Heat Transfer And Fluid Flow. Hemisphere Publishing Corporation. New York

Verstreeg, H. K. and Malalasekera, W. 2007. An Introduction to Computational Fluid Dynamics: The Finite Volume Method. 2nd ed. Longman Group Limited. England.

Balakin, B. V., Hoffmann, A. C., Kosinski, P., and Rhyne, L. D. 2010. Eulerrian - Eulerian CFD Model For The Sedimentation Of Spherical Particles In Suspension With High Particle Concentrations. Engineering Applications of Computational Fluid Mechanics. 4(1): 116-126.

Halwachs, M., Hofbauer, H. and Kampichler, G. 2009. Low Temperature Pyrolysis Of Agricultural Residues-First Results Of A Pilot Plant. International Conference on Polygeneration Strategies.

Shuai, W., Juhui, C., Guodong, L., Huilin, L., Feixiang, Z. and Yanan, Z. 2014. Predictions Of Coal Combustion And Desulfurization In A CFB Riser Reactor By Kinetic Theory Of Granular Mixture With Unequal Granular Temperature. Fuel Processing Technology. 126: 163-172.

Busciglio, A., Vella, G., Micale, G. and Rizzuti, L. 2009. Analysis Of The Bubbling Behaviour Of 2D Gas Solid Fluidized Beds Part II. Comparison Between Experiments And Numerical Simulations Via Digital Image Analysis Technique. Chemical Engineering Journal. 148: 145-163.

Gungor, A. and Eskin, N. 2008. Two-Dimensional Coal Combustion Modeling Of CFB. International Journal of Thermal Sciences. 47: 157-174.

Gungor, A. 2008. Two-Dimensional Biomass Combustion Modeling Of CFB. Fuel. 87: 1453-1468.

Zhou, W., Zhao, C., Duan, L., Liu, D. and Chen, X. 2011. CFD Modeling Of Oxy-Coal Combustion In Circulating Fluidized Bed. International Journal of Greenhouse Gas Control. 5(6): 1489-1497.

Ross, I. B. and Davidson, J. F. 1982. The Combustion Of Carbon Particles In A Fluidized Bed. Transactions of the institution of Chemical Engineers. 60: 109-114.

Rajan, R. R. and Wen, C. Y. 1980. A Comprehensive Model For Fluidized Bed Coal Combustors. AIChE Journal. 26: 642-655.

Mattisson, T. and Lyngfelt, A. 1998. A Sulphur Capture Model For Circulating Fluidized-Bed Boilers. Chemical Engineering Science. 53: 1163-1173.

Borgwardt, R. H. 1970. Kinetics Of Reaction Of SO2 With Calcined Limestone. Environmental Science & Technology. 4: 59-63.

Mattisson, T. and Lyngfelt, A. 1998. A Sulfur Capture Model For Circulating Fluidized-Bed Boilers. Chemical Engineering Science. 53: 1163-1173.

Field, M. A., Gill, D. M., Morgan, B. B. and Hawskley, P. G. W. 1987. Combustion of Pulverized Coal. BCURA. Leatherhead. England.

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Published

2016-06-12

How to Cite

CFD MODELING OF SO2 CAPTURE USING LIMESTONE IN INDUSTRIAL SCALE CIRCULATING FLUIDIZED BED BOILER. (2016). Jurnal Teknologi, 78(6-4). https://doi.org/10.11113/jt.v78.8986